Investigation of the state of local thermodynamic equilibrium of a laser-produced aluminum plasma

In this work, the assumption of local thermodynamic equilibrium (LTE) for a laser-induced plasma in ambient air is examined experimentally using two different laser systems, namely an infrared short-pulse Ti : Sapphire laser and an ultraviolet long-pulse XeCl excimer laser. The LTE assumption is investigated by examining the plasma produced at a laser fluence of 10 J/cm(2) from aluminum targets containing iron and magnesium impurities. The excitation temperature is deduced from Boltzmann diagrams built from a large number of spatially integrated neutral iron lines distributed from 3.21 to 6.56 eV. It is shown that at any time after the end of the laser pulse, the neutral excited states are in excellent Boltzmann equilibrium. Detailed investigation of Boltzmann equilibrium further validates previous temperature measurements using less accurate diagrams. However, observations of ion lines provide some evidence that the ionized species do not obey Saha equilibrium, thereby indicating departure from LTE. This could be explained by the fact that the plasma cannot be considered as stationary for these species.     

Laser-ablated volume and depth as a function of pulse duration in aluminum targets

The ablated depth and volume per laser pulse from an aluminum target were measured for pulse durations that ranged from 80 fs to 270 ps at an average fluence of approximately 100 J/cm2 and a wavelength of 0.8 microm. The ablated volume showed a flat maximum for subpicosecond pulses and a minimum for approximately 6 ps. The crater diameters were rather constant up to pulse durations of approximately 6 ps and increased for larger pulse durations. As a result, the ablated depth also showed a plateau for subpicosecond pulses but decreased monotonically with pulse duration. A physical interpretation of these results and their consequences for laser applications are discussed.     

Ice‐Assisted Synthesis of Black Phosphorus Nanosheets as a Metal‐Free Photocatalyst: 2D/2D Heterostructure for Broadband H2 Evolution

A 2D/2D heterojunction of black phosphorous (BP)/graphitic carbon nitride (g‐C₃N₄) is designed and synthesized for photocatalytic H₂ evolution. The ice‐assisted exfoliation method developed herein for preparing BP nanosheets from bulk BP, leads to high yield of few‐layer BP nanosheets (≈6 layers on average) with large lateral size at reduced duration and power for liquid exfoliation. The combination of BP with g‐C₃N₄ protects BP from oxidation and contributes to enhanced activity both under λ > 420 nm and λ > 475 nm light irradiation and to long‐term stability. The H₂ production rate of BP/g‐C₃N₄ (384.17 µmol g^?1 h^?1) is comparable to, and even surpasses that of the previously reported, precious metal‐loaded photocatalyst under λ > 420 nm light. The efficient charge transfer between BP and g‐C₃N₄ (likely due to formed N? P bonds) and broadened photon absorption (supported both experimentally and theoretically) contribute to the excellent photocatalytic performance. The possible mechanisms of H₂ evolution under various forms of light irradiation is unveiled. This work presents a novel, facile method to prepare 2D nanomaterials and provides a successful paradigm for the design of metal‐free photocatalysts with improved charge‐carrier dynamics for renewable energy conversion.     

Visual Attention for Rendered 3D Shapes

Understanding the attentional behavior of the human visual system when visualizing a rendered 3D shape is of great importance for many computer graphics applications. Eye tracking remains the only solution to explore this complex cognitive mechanism. Unfortunately, despite the large number of studies dedicated to images and videos, only a few eye tracking experiments have been conducted using 3D shapes. Thus, potential factors that may influence the human gaze in the specific setting of 3D rendering, are still to be understood. In this work, we conduct two eye‐tracking experiments involving 3D shapes, with both static and time‐varying camera positions. We propose a method for mapping eye fixations (i.e., where humans gaze) onto the 3D shapes with the aim to produce a benchmark of 3D meshes with fixation density maps, which is publicly available. First, the collected data is used to study the influence of shape, camera position, material and illumination on visual attention. We find that material and lighting have a significant influence on attention, as well as the camera path in the case of dynamic scenes. Then, we compare the performance of four representative state‐of‐the‐art mesh saliency models in predicting ground‐truth fixations using two different metrics. We show that, even combined with a center‐bias model, the performance of 3D saliency algorithms remains poor at predicting human fixations. To explain their weaknesses, we provide a qualitative analysis of the main factors that attract human attention. We finally provide a comparison of human‐eye fixations and Schelling points and show that their correlation is weak.     

Layered Simple Hydroxides Functionalized by Fluorene‐Phosphonic Acids: Synthesis,Interface Theoretical Insights,and Magnetoelectric Effect

Copper‐ and cobalt‐based layered simple hydroxides (LSH) are successfully functionalized by a series of fluorene mono‐ and diphosphonic acids, using anionic exchange reactions and a preintercalation strategy. The lateral functionalization of the fluorene moieties has only little impact on the overall structure of the obtained layered hybrid materials but it influences the organization of the molecules within the interlamellar spacing. For bulky fluorene (9,9‐dioctyl derivative), luminescence is preserved when inserted into copper and cobalt hydroxydes, whereas it is completely quenched for the other fluorenes. Detailed characterization of the internal structure and chemical bonding properties for copper‐ and cobalt‐based hybrids is performed via ancillary experimental techniques. For the copper‐based LSH class, for which more elusive findings are found, first‐principles molecular dynamics simulations unravel the fundamental stabilizing role of the H‐bonding network promoted within the local environments of the fluorene mono‐ and diphosphonic acids. The cobalt series of compounds constitute a new class of hybrid magnets, with ordering temperatures ranging from 11.8 to 17.8 K and show a clear magnetoelectric effect. This effect appears above a threshold magnetic field, which is null below the magnetic ordering temperature, and it persists in the paramagnetic regime till about 110 K.     

Instrument recognition in polyphonic music based on automatic taxonomies

We propose a new approach to instrument recognition in the context of real music orchestrations ranging from solos to quartets. The strength of our approach is that it does not require prior musical source separation. Thanks to a hierarchical clustering algorithm exploiting robust probabilistic distances, we obtain a taxonomy of musical ensembles which is used to efficiently classify possible combinations of instruments played simultaneously. Moreover, a wide set of acoustic features is studied including some new proposals. In particular, signal to mask ratios are found to be useful features for audio classification. This study focuses on a single music genre (i.e., jazz) but combines a variety of instruments among which are percussion and singing voice. Using a varied database of sound excerpts from commercial recordings, we show that the segmentation of music with respect to the instruments played can be achieved with an average accuracy of 53%.     

Survey of Ti-, B-, and Y-based soft x-ray-extreme ultraviolet multilayer mirrors for the 2- to 12-nm wavelength region

We have performed an experimental investigation of Ti-, B(4)C-, B-, and Y-based multilayer mirrors for the soft x-ray?extreme ultraviolet (XUV) wavelength region between 2.0 and 12.0 nm. Eleven different material pairs were studied: Ti/Ni, Ti/Co, Ti/Cu, Ti/W, B(4)C/Pd, B/Mo, Y/Pd, Y/Ag, Y/Mo, Y/Nb, and Y/C. The multilayers were sputter deposited and were characterized with a number of techniques, including low-angle x-ray diffraction and normal incidence XUV reflectometry. Among the Ti-based multilayers the best results were obtained with Ti/W, with peak reflectances up to 5.2% at 2.79 nm at 61° from normal incidence. The B(4)C/Pd and B/Mo multilayer mirrors had near-normal incidence (5°) peak reflectances of 11.5% at 8.46 nm and 9.4% at 6.67 nm, respectively, whereas a Y/Mo multilayer mirror had a maximum peak reflectance of 25.6% at 11.30 nm at the same angle. The factors limiting the peak reflectance of these different multilayer mirrors are discussed.     

High temperature phase stability and chemical analysis of the highly doped yttria stabilized zirconia with alumina

Short and long term thermal stability of YSZ was studied considering the equilibrium and non-equilibrium phase transformation of YSZ. To improve the long term thermal stability of YSZ, electrical treatment was introduced. Electrical treatment consists of applying electric field into YSZ at high temperatures under a reducing atmosphere. By optimizing the conditions of treatment, electrical resistivity reduced around 40% and thermal stability improved dramatically. These improvements are due to the generation of tetragonal metastable phases. Arguments are put forth to show that electrical treatment induces a relaxation in the lattice. This relaxation is associated with a reduction in lattice tetragonality and replaces the tetragonal grains of YSZ with domain of metastable phases. High resistance of metastable phase to creep deformation and lower electrical resistivity of domains of metastable phases in comparison with tetragonal grains brings about these improvements.     

Optimal Selective Arbitrary-Spaced Filters Optimization Using GA Synthesis in One-Dimensional Silicon Photonic Crystal

Silicon - The optimization process is a necessary step in the design of optimal optical devices with high performances. In this paper, optimization of unidirectional photonic crystal selective...     

Dependence of gold nanoparticle production on pulse duration by laser ablation in liquid media

The dependence on laser fluence and laser pulse duration of size, size distribution and concentration of gold nanoparticles synthesized by laser ablation in liquid media was investigated. It was demonstrated that increasing laser energy from 1 to 5 mJ/pulse enhances the ablation rate by a factor of 100. The behavior of the ablation rate, hence of the nanoparticle concentration, as a function of pulse duration (varied from 40 fs to 200 ps) was found to strongly differ from that in air, which can be explained by photoionization and important losses of laser energy in the femtosecond regime. The optimal pulse duration for maximum ablation rate in liquid media was found to be equal to 2 ps.