热压烧结Ti3AlC2材料的制备、结构与性能研究

采用热压工艺研究了不同工艺制度和原料中不同的Si含量对Ti3AlC2合成的影响.研究表明在1 300℃～1 500℃,30MPa压力和Ar气氛中热压摩尔比为n(TiC)n(Ti)n(Al)n(Si)=2110.2的混合粉末,可以得到纯度达98%(质量分数)以上的致密块体Ti3AlC2材料;添加的Si均匀分布在基体中,形成固溶体,当添加Si的摩尔比为0.2时,固溶体的化学式为Ti2 76Al0 78Si0.22C2.烧结试样的晶体为层片状结构,1 300℃和1 400℃时,烧结试样的晶粒尺寸分别为10μm～15μm和20μm～30μm.材料的维氏硬度为3.3 GPa～5.0 GPa,弹性模量为289 GPa,抗压强度为785 MPa,抗弯强度为375 MPa,断裂韧性为7.0 MPa·m1/2;25℃时,电导率为3.1×106 S·m-1,热容为125.4 J/mol·K,热导率为27.5 W/m·K;热膨胀系数为8.8×10-6 K-1.     

含硼金刚石的金属包膜成分及其物相的研究

本文采用铁基触媒加入硼铁的方法，在高温高压条件下合成了含硼金刚石，利用电子探针（EPMA），透射电子显微镜（TEM）两种检测手段，分析了含硼金刚石金属包膜的微观组织结构，化学组成成分，各组成成分的物相及其可能形成的原因。研究结果表明：金属包膜的成分及其物相由正交立方结构的（Fe,Ni）3C，面心立方的γ-（Fe,Ni），面心立方的Fe23（C，B）。及少量的FeB,Ni3B组成，这些成份主要来源于原材料，其含量在高温压过程中是瞬间变化的。     

Microstructure of Titanium after Hydrogenation

ＭｉｃｒｏｓｔｒｕｃｔｕｒｅｏｆＴｉｔａｎｉｕｍａｆｔｅｒＨｙｄｒｏｇｅｎａｔｉｏｎＷａｎｇＹｕ；ＷａｎｇＰｅｉｘｕａｎ；ＺｈａｎｇＪｉａｎｗｅｉ（王宇）（王佩璇）（张建伟）ＵｎｉｖｅｒｓｉｔｙｏｆＳｃｉｅｎｃｅａｎｄＴｅｃｈｎｏｌｏｇｙＢｅｉｊｉｎ...     

工作流技术在ASP公共服务平台中的应用研究*

根据项目特点,建立了适合ASP平台的基于协调理论和反馈机制的扩展活动网络模型,采用XML模式的XPDL规范实现过程定义;然后通过DOM解析XML数据文档和J2EE的技术支持实现了系统的轻量级工作流引擎.详细介绍了系统实现中解决的两个关键问题:事务型操作的处理和并发控制,并提出了基于优先级的锁绑定机制.     

Coordinated Recovery of Middleware Services:A Framework and Experiments

Being the most popular runtime infrastructure for distributed systems, middleware can be viewed as a collection of common services. Since the development, deployment and maintenance of distributed systems rely largely on middleware services, the failure of middleware services puts a significant impact on the reliability and availability of the whole system. Though recovery-based fault tolerance is an effective way to improve the reliability of middleware services, it is far away from practice mainly because of the high complexity and cost of the recovery of correlated failures between interdependent services. In this paper,a framework for detecting and recovering the correlated failures of middleware services in an automated way is presented. First, the problem is investigated from two perspectives, i.e.,analyzing the role and impact of middleware services and illustrating a set of correlated failures in J2EE standard services as motivating examples. Then, a general coordinated recovery model is constructed with the elements necessary and su±cient for detecting and recovering correlated failures in middleware services. The supporting framework is demonstrated on three J2EE application servers, i.e., PKUAS, JBoss and JOnAS, one by one without fundamental modifications. Finally, based on the three enhanced application servers, many cases on J2EE common services, including the transaction service, database service, naming and directory service, security service and messaging service, are studied. The experiment results show the effectiveness and applicability of the framework presented in this paper.     

Simulation study on the gasification process of Ningdong coal with iron-based oxygen carrier

Chemical looping gasification (CLG) of Ningdong coal by using Fe₂O₃ as the oxygen carriers (OCs) was studied, and the gasification characteristics were obtained. A computation fluid dynamics (CFD) model based on Eulerian‐-Lagrangian multiphase framework was established, and a numerical simulation the coal chemical looping gasification processes in fuel reactor (FR) was investigated. In addition, the heterogeneous reactions, homogeneous reactions and Fe₂O₃ oxygen carriers' reduction reactions were considered in the gasification process. The characteristics of gas flow and gasification in the FR were analyzed and it was found that the experiment results were consistent with the simulation values. The results show that when the O/C mole rate was 0.5:1, the gasification temperature was 900 ℃ and the water vapor volume flow rate was 2.2 ml·min^-1, the mole fraction of syngas reached a maximum value of the experimental result and simulation value were 71.5% and 70.2%, respectively. When the O/C mole rate was 0.5:1, the gasification temperature was 900 ℃, and the water vapor volume flow was 1.8 ml·min^-1; the gasification efficiency reached the maximum value was 62.2%, and the maximum carbon conversion rate was 84.0%.     

500kV输电线路运行稳定性评价模型研究

针对目前500 kV输电线路运维工作任务分配不合理,导致巡检效率低以及线路大修技改采取"差异化"改造方案如何选择规划的问题,建立一种输电线路多维度评价模型.该模型采用模糊综合评价方法,选择与输电线路巡检与大修技改密切相关的多个指标,通过层次分析法与熵权法确定各指标权重,计算各指标对应评语集的隶属度,最终得出评估结果.通过具体案例分析,该模型符合实际情况,能较好地对500 kV输电线路运行稳定性进行评估.     

Genome-Wide Analysis of the Late Embryogenesis Abundant (LEA) and Abscisic Acid-, Stress-, and Ripening-Induced (ASR) Gene Superfamily from Canavalia rosea and Their Roles in Salinity/Alkaline and Drought Tolerance

Canavalia rosea (bay bean), distributing in coastal areas or islands in tropical and subtropical regions, is an extremophile halophyte with good adaptability to seawater and drought. Late embryogenesis abundant (LEA) proteins typically accumulate in response to various abiotic stresses, including dehydration, salinity, high temperature, and cold, or during the late stage of seed development. Abscisic acid-, stress-, and ripening-induced (ASR) genes are stress and developmentally regulated plant-specific genes. In this study, we reported the first comprehensive survey of the LEA and ASR gene superfamily in C. rosea. A total of 84 CrLEAs and three CrASRs were identified in C. rosea and classified into nine groups. All CrLEAs and CrASRs harbored the conserved motif for their family proteins. Our results revealed that the CrLEA genes were widely distributed in different chromosomes, and all of the CrLEA/CrASR genes showed wide expression features in different tissues in C. rosea plants. Additionally, we introduced 10 genes from different groups into yeast to assess the functions of the CrLEAs/CrASRs. These results contribute to our understanding of LEA/ASR genes from halophytes and provide robust candidate genes for functional investigations in plant species adapted to extreme environments.     

The effect of heat treatment on tensile properties of 2D C/SiC composites

Two-dimensional (2D) carbon fiber reinforced silicon carbide (C/SiC) composites with different initial strength were prepared by chemical vapor infiltration (CVI). After tensile property testing, results exhibited that as the heat-treatment temperature (HTT) increases to 1900°C, the tensile strength and toughness of the low strength specimen (LSS) increased by 110% and 530%, while the high strength specimen (HSS) increased by 5.4% and 550%, respectively. As observed from morphologies, the heat treatment increases the graphitization of the amorphous PyC interphase, which leads to the weakening of interfacial bonding strength (IBS). Meanwhile, the defects arising from heat treatment cause thermal residual stress relaxation. Therefore, the tensile strength and toughness of LSS with relatively high initial IBS increase significantly as HTT increases. For HSS with moderate initial IBS, the heat treatment slightly improves the tensile strength, but significantly improves the toughness. Consequently, the post-heat-treatment tensile properties of 2D C/SiC composites can be regulated by varying HTTs and different initial strength.     

伊索昔康的合成方法研究

研究并合成一种昔康类非甾体抗炎药——4-羟基-2-甲基-N-(5-甲基-3-异噁唑基)-2H-1,2-苯并噻嗪-3-羧酰胺-1,1-二氧化物(伊索昔康).以糖精钠(1)和氯乙酸甲酯为原料,经取代、重排扩环、甲基化反应生成4-羟基-2-甲基-2H-1,2-苯并噻嗪-3-羧酸甲酯1,1-二氧化物(4)中间体,化合物(4)与5-甲基-3-异噁唑胺发生酰胺化反应生成伊索昔康(5).目标产物总收率为64.6％,纯度达100％,其结构由1H-NMR和MS表征.