Reaction mechanism and microstructure evolution of reaction sintered <Emphasis Type="Italic">h</Emphasis>-BN

Hexagonal boron nitride ceramic (h-BN) based on the nitridation of B powders was obtained by reaction sintering method. The effects of sintering temperature on the mechanical properties and microstructure of the resultant products were investigated and the reaction mechanism was discussed. Results showed that the reaction between B and N₂ occurred vigorously at temperatures ranging from 1 000 °C to 1 300 °C, which resulted in the generation of t-BN. When the temperature exceeded 1 450 °C, transformation from t-BN to h-BN began to occur. As the sintering temperature increased, the spherical particles of t-BN gradually transformed into fine sheet particles of h-BN. These particles subsequently displayed a compact arrangement to achieve a more uniform microstructure, thereby increasing the strength.     

基于不完全信道信息的D2D功率分配算法

针对蜂窝与终端直通(Device-to-device,D2D)混合网络中的不完全信道状态信息(Channel state information,CSI),提出了一种基于不完全CSI的最优功率分配算法。利用拉格朗日乘数法推导出了最优功率分配解的闭式表达式。相对于传统的最大发送功率分配方案,该最优解受信道信息误差的影响较小,具有较好的鲁棒性。仿真结果表明,本文算法可以节约发送功率,并得到更大的接收信噪比。     

Simple Preparation of Crystal Co3（BTC）2·12H2O and Its Catalytic Activity in CO Oxidation Reaction

Crystalline metal-organic framework cobalt(Ⅱ) benzenetricarboxylate Co3(BTC)2?12H2O(MOF-Co) has been prepared using solvothermal method. The reaction of cobalt(Ⅱ) nitrate and 1,3,5-benzenetricarboxylic(BTC) acid in a mixed solution of N,N-dimethylformamide(DMF)/C2H5OH/H2O(1:1:1, ν/ν) at low temperature for short reaction times produced this crystalline compound. Compared with traditional hydrothermal method, a mixed solution method for the synthesis of crystalline metal complex was found to be highly efficient. After water molecules were removed from this metal complex, its exposed nodes served as active sites. When this MOF-Co was employed in the oxidation of CO, it showed good catalytic properties causing 100% conversion of CO to CO2 at low temperature of 160 ℃.     

Influence of static pre-loading on the dynamic bending strength of concrete with particle element modeling

Experimental tests show that static pre-loading has a significant effect on the dynamic strength of concrete.Based on meso-scale particle element model,numerical simulations of dynamic bending tests with pre-loading are performed.Complete stress–strain relationships are then obtained.Significant increase in dynamic strength is found when the pre-loadings are imposed within the elastic limit of concrete.However,when the imposition of pre-loadings reaches the plastic or softening range,dynamic strengths may gradually decrease along with the increase in pre-loadings.The distribution of energy components and the failure modes are discussed to explain the mechanisms of the phenomena.     

Non-Fourier heat conduction in a thin gold film heated by an ultra-fast-laser

Based on the dual-phase-lagging(DPL)heat conduction model,the Cattaneo-Vernotte(CV)model and the improved CV model we investigate the one-dimensional heat conduction in gold films with nano-scale thickness exposed to an ultra-fast laser heating.The influence of system parameters on the temperature field is explored.We find that for all the non-Fourier heat conduction models considered in this work,a larger Knudsen number normally leads to a higher temperature.For the DPL model,the large ratio of the phase lag of temperature gradient to the phase lag of heat flux reduces the maximum temperature and shortens the time for the system to reach its steady state.The CV model and the improved CV model lead to the similar thermal wave behavior of the temperature field,but the thermal wave speeds for these two models are different,especially for large Knudsen numbers.When the phase lag of temperature gradient is smaller,the difference between the DPL model and the improved CV model is not significant,but for the large phase lag of temperature gradient the difference becomes quite significant,especially for the large Knudsen number.In addition,the effect of the surface accommodation coefficient,which is a parameter in the slip boundary condition,on the temperature field of the gold film heated by ultra-fast laser pulses is investigated based on the DPL model.     

Effects of coagulation bath temperature on structure and performance of poly （vinyl butyral） hollow fiber membranes via thermally induced phase separation

Poly （vinyl butyral） （PVB） hollow fiber membranes were fabricated via thermally induced phase separation （TIPS）. The effects of coagulation bath temperature （CBT） on the structure and performance of membranes were investigated in detail. The morphologies of the membranes were studied by scanning electron microscopy （SEM）, the performances of water permeability, rejection, breaking strength and elongation were measured, respectively. The results indicate that all the membranes have the asymmetric morphology and the thickness of the skin layer decreases and the pore size of the outer layer increases with the increase of CBT. The permeability of membranes prepared at air gap 1.0 cm and take-up speed 0.253 m/s increases from 1.047×10-7 to 5.909×10-7 m3/（m2·s-kPa） with the CBT increasing from 20 ℃ to 40℃, and sharply increases to 35.226×10 7 m3/（m2.s.kPa）once the CBT arrives at 50 ℃. While the carbonic ink rejections have no significant decrease, totally exceed 98%, but that of acid-maleic acid copolymer greatly decreases with the increase of CBT. Both the breaking strength and elongation decrease with the increase of CBT.     

微创业:大学生创业实践教育的思考

大学生创业实践是高校创业教育的一个难题。当前国内高校创业教育普遍存在实践教育环节薄弱、效果不显著等问题,本研究同步社会经济发展,尝试以微创业视角思考高校创业实践教育,通过梳理微创业的概念及应用,从契合大学生需求角度分析微创业具有的时代性、低门槛、大众化、创新性等特点。并根据高校实际情况,从完善微创业环境、开设微创业课程、建立微创业实践基地、提供微创业网络平台服务等方面提出推动高校大学生微创业的路径建议。     

超细Al（OH）3的粒度控制研究

采用铝酸钠种子分解法制备超细Al（OH）3.用X射线衍射仪（XRD）表征了样品的晶相组成,用扫描电子显微镜（SEM）观察了样品的形貌,用激光粒度分析仪测定样品的粒度分布.研究了NaOH浓度、NaOH/Al（OH）3摩尔比,分解温度,分解时间、晶种率和搅拌速率等因素对Al（OH）3的粒度的影响.结果表明：NaOH浓度越高,分解温度越低,NaOH/Al（OH）3摩尔比越小,得到的Al（OH）3颗粒的粒度越小.试验条件为：NaOH浓度180 g/L,NaOH/Al（OH）3摩尔比1.15,分解温度40℃,分解时间26 h,晶种率8％,搅拌速率200 rpm时,氢氧化铝颗粒的平均粒度为2.89 μm.     

铜离子印迹改性壳聚糖海绵的制备及应用研究

以醋酸铜为模板,甲醇、氯仿为溶剂,2-乙烯吡啶、丙烯酰胺为功能单体,乙二醇二甲基丙烯酸酯为交联剂,采用本体聚合法制备铜离子印迹聚合物;然后掺入到壳聚糖海绵的制备中,使壳聚糖海绵对铜离子的吸附率由27．1％提高到72．3％。制备的铜离子印迹改性壳聚糖海绵需要2d达到吸附平衡,吸附-解吸5次后,性能稳定。     

Electrochemical investigation of La0.4Sr0.6TiO3 synthesized in air for SOFC application

Journal of Applied Electrochemistry - La-doped titanate materials have been widely investigated as alternative Ni-free anodes for solid oxide fuel cells (SOFCs). In this study, La0.4Sr0.6TiO3 (LST)...