基体温度对磁控溅射沉积ZAO薄膜性能的影响

利用中频交流磁控溅射方法 ,采用氧化锌铝陶瓷靶材 [w(ZnO) =98%、w(Al2 O3 ) =2 % ]制备了ZAO(ZnO∶Al)薄膜 ,观察了基体温度对ZAO薄膜的晶体结构、电学和光学性能的影响 ,采用X射线衍射仪对薄膜的结构进行了分析 ,采用光学分度计和电阻测试仪测量了薄膜的光学、电学特性 ,采用霍尔测试仪测量了薄膜的载流子浓度和霍尔迁移率。结果表明 :沉积薄膜时的基体温度对薄膜的结构、结晶状况、可见光透射率以及导电性有较大的影响。当基体温度为 2 5 0℃ ,Ar分压为 0 8Pa时 ,薄膜的最低电阻率为 4 6× 10 -4Ω·cm ,方块电阻为 35Ω时 ,可见光 (λ =5 5 0nm)透射率高达 92 0 %。     

Ring‐opening polymerization of D,L‐lactide by rare earth 2,6‐dimethylaryloxide

Ring‐opening polymerization of D,L ‐lactide (LA) has been successfully carried out by using rare earth 2,6‐dimethylaryloxide (Ln(ODMP)₃) as single component catalyst or initiator for the first time. The effects of different rare earth elements, solvents, monomers and catalyst concentration as well as polymerization temperature and time on the polymerization were investigated. The results show that La(ODMP)₃ exhibits higher activity to prepare poly(D,L ‐lactide) (PLA) with a viscosity molecular weight of 4.5 × 10⁴ g mol^?1 and the conversion of 97 % at 100 °C in 45 min. The catalytic activity of Ln(ODMP)₃ has following sequence: La > Nd > Sm > Gd > Er > Y. A kinetic study has indicated that the polymerization is first order with respect to both monomer and catalyst concentration. The apparent activation energy of the polymerization of LA with La(ODMP)₃ is 69.6 kJ mol^?1. The analyses of polymer ends indicate that the LA polymerization proceeds according to ‘coordination–insertion’ mechanism with selective cleavage of the acyl–oxygen bond of the monomer. Copyright © 2004 Society of Chemical Industry     

Al2O3对镁铬耐火材料致密化的影响

为了提高镁铬耐火材料的烧结性能,通过考察气孔率、体积密度和常温耐压强度与Al2O3加入量之间的关系,讨论了Al2O3添加剂对两种不同镁铬耐火材料致密化的影响.结果表明,镁铬耐火材料的骨料不同,Al2O3对其烧结性能和致密化的影响也不一样.     

负温度系数传感器特性检测系统设计

负温度系数(NTC)传感器是一种阻值随温度升高而降低的热敏电阻,广泛应用于家用电器的测控系统中.鉴于不同NTC元件的温度-电阻特性一致性较差,给批量家用电器产品的调试带来不便.因此,NTC特性的自动测量和筛选是十分重要的.文中介绍了一种新型的NTC热敏电阻特性检测系统,阐述了该系统的检测原理和硬件组成,给出了系统的硬件框图和软件流程.该系统实现了NTC传感器温度特性的自动测量和筛选,方便了整机装配前对使用的NTC传感器温度特性的检测,降低了后道工序的调整难度,节省了工时.     

基于LCoS芯片的微型电视系统设计与实现

介绍了LCoS芯片在电视接收系统中的应用，重点讨论了LCoS芯片的结构与特点。自主开发的LCoS模块采用模拟视频接口、兼容隔行和逐行扫描方式，可以简化系统电路设计，降低系统功耗。同时论述了LCoS微型电视机在信号接收、模拟视频处理、时序控制和音频电路等方面的特点，并给出了相关电路的设计方案。     

TCP/IP网络的动态模型描述

拥塞现象成为TCP/IP网络发展面临的一个重要问题。因此，拥塞控制对TCP/IP网络的鲁棒性和稳定性具有重要作用。目前，网络拥塞控制策略主要包括两类：端到端的控制机制，如TCP拥塞控制算法；网络内部的主动队列管理(AQM)策略。但由于缺乏对网络系统动态特性的了解，这些拥塞控制策略大都基于专家经验，并没有建立完整的理论分析框架。为此，本文从数据流的角度出发，通过建立网络基本单元状态方程模型来实现IP网络系统的数学解析模型，然后用混杂系统来描述TCP带有拥塞控制策略的数据传输过程，建立了TCP/IP网络的动态模型，为网络系统中动态性能的分析、拥塞控制策略的设计奠定了基础。实验结果表明，该数学模型与NS仿真实验的结果相一致。     

环境友好水基润滑添加剂的研究

在脂肪酸分子中引入硼和氮，合成了一种环境友好水基润滑添加剂BNR，并利用红外光谱对其主要官能团进行了表征。通过四球试验机考察了BNR添加剂在水中的抗磨性能与极压性能，用X射线光电子能谱仪对磨痕表面元素进行了分析，探讨了该类添加剂的极压抗磨作用机理。结果表明：硼氮化水基润滑添加剂BNR在水中具有优良的抗磨和减摩性能；其润滑作用机理是由于长链脂肪酸分子的载体作用、硼的缺电子性、氮的高反应活性以及三者的协同作用与摩擦金属表面形成了一层高强度的吸附膜和／或摩擦化学反应膜。     

开流形的曲率与拓扑

应用比较几何的方法研究了完备非紧且具有特定曲率条件的黎曼流形，证明了在一定Pinching条件限制下，流形具有有限拓扑型或者微分同胚于R^n。     

含V、N无缝钢管表面外折缺陷产生原因的分析

通过对鞍钢生产的部分批号V、N微合金强化无缝钢管及生产该钢管的原料连铸坯和连轧管坯的表面缺陷进行研究，分析了含V、N钢管表面外折缺陷的成因，提出了改善钢管表面质量的方法。采用改进后工艺生产的无缝管，其表面外折废品量大幅度降低。     

Ozonation of CI Reactive Black 5 using rotating packed bed and stirred tank reactor

This study investigates the ozonation of CI Reactive Black 5 (RB5) by using the rotating packed bed (RPB) and completely stirred tank reactor (CSTR) as ozone contactors. The RPB, which provides high gravitational force by adjusting the rotational speed, was employed as a novel ozone contactor. The same ozone dosage was separately introduced into either the RPB or the CSTR for the investigation, while the experimental solution was continuously circulated within the apparatus consisting of the RPB and CSTR. The decolorization and mineralization efficiencies of RB5 in the course of ozonation are compared for these two methods. Moreover, the dissolved and off‐gas ozone concentrations were simultaneously monitored for the further analysis. As a result, the ozone mass transfer rate per unit volume of the RPB was significantly higher because of its higher mass transfer coefficient and gas–liquid concentration driving force. Furthermore, ozonation kinetics was found to be independent of the gravitational magnitude of an ozone gas–liquid contactor. Therefore, the results suggest employing RPBs as ozone‐contacting devices with the advantage of volume reduction. The experimental results, which can be used for further modeling of the ozonation process in the RPB, also show the requirement of correct design for the RPB. Consequently, the present study is useful for the understanding of practical application of RPBs. Copyright © 2004 Society of Chemical Industry