全文获取类型
收费全文 | 1036篇 |
免费 | 59篇 |
国内免费 | 6篇 |
专业分类
电工技术 | 59篇 |
综合类 | 3篇 |
化学工业 | 269篇 |
金属工艺 | 28篇 |
机械仪表 | 24篇 |
建筑科学 | 37篇 |
能源动力 | 51篇 |
轻工业 | 130篇 |
水利工程 | 7篇 |
石油天然气 | 3篇 |
无线电 | 86篇 |
一般工业技术 | 244篇 |
冶金工业 | 9篇 |
原子能技术 | 33篇 |
自动化技术 | 118篇 |
出版年
2024年 | 1篇 |
2023年 | 6篇 |
2022年 | 30篇 |
2021年 | 47篇 |
2020年 | 21篇 |
2019年 | 38篇 |
2018年 | 27篇 |
2017年 | 24篇 |
2016年 | 41篇 |
2015年 | 39篇 |
2014年 | 57篇 |
2013年 | 72篇 |
2012年 | 80篇 |
2011年 | 117篇 |
2010年 | 75篇 |
2009年 | 71篇 |
2008年 | 82篇 |
2007年 | 61篇 |
2006年 | 34篇 |
2005年 | 38篇 |
2004年 | 35篇 |
2003年 | 29篇 |
2002年 | 17篇 |
2001年 | 14篇 |
2000年 | 8篇 |
1999年 | 3篇 |
1998年 | 9篇 |
1997年 | 2篇 |
1996年 | 5篇 |
1995年 | 2篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1983年 | 2篇 |
排序方式: 共有1101条查询结果,搜索用时 17 毫秒
61.
The effects of accelerating voltage and collection angle on the mean free path for all inelastic electron scattering (lambdap), which is an important parameter for determining specimen thickness by using electron energy-loss spectroscopy, were investigated with crystalline Si and amorphous SiO2. First, thickness of Si film was measured with the convergent-beam electron diffraction method, while thickness of SiO2 particles was estimated from their spherical shape. Then from electron energy-loss spectra, lambdap was evaluated for Si film and SiO2 particles by changing the accelerating voltage (100 to approximately 300 kV) and the collection angle for the scattered electrons. Under the condition of no objective aperture, lambdap for Si film and SiO2 particles was found to increase with the increase of accelerating voltage and to take values of 180+/-6 nm (Si) and 247+/-8 nm (SiO2) at 300 kV. Also, it was found that lambdap in both cases decreases drastically with the increase of collection angle in the range smaller than 25 mrad, while it tends to take a constant value at the collection angle larger than 25 mrad at 200 kV. 相似文献
62.
Determining surface orientations of transparent objects based on polarization degrees in visible and infrared wavelengths 总被引:1,自引:0,他引:1
Miyazaki D Saito M Sato Y Ikeuchi K 《Journal of the Optical Society of America. A, Optics, image science, and vision》2002,19(4):687-694
Techniques for modeling an object through observation are very important in object recognition and virtual reality. A wide variety of techniques have been developed for modeling objects with opaque surfaces, whereas less attention has been paid to objects with transparent surfaces. A transparent surface has only surface reflection; it has little body reflection. We present a new method for obtaining surface orientations of transparent surfaces through analysis of the degree of polarization in surface reflection and emission in visible and far-infrared wavelengths, respectively. This parameter, the polarization degree of reflected light at the visible wavelengths, is used for determining the surface orientation at a surface point. The polarization degree at visible wavelengths provides two possible solutions, and the proposed method uses the polarization degree at far-infrared wavelengths to resolve this ambiguity. 相似文献
63.
Steroid cyclophanes, each having a macrocyclic ring attached to four bile acid moieties via chiral lysine connectors, were synthesized, and the binding of the 2-naphthylphenylketone (guest) to the steroid cyclophanes in water was investigated. The circular dichroism spectra of the steroid cyclophane with cholic acid and L-lysine were significantly affected by the binding of the guest, and the induced circular dichroism based on the absorption of the achiral guest was also observed. The binding of the guest to the steroid cyclophane with cholic acids and D-lysines induced changes in the circular dichroism spectra with the opposite sign of the molecular ellipticities. An induced circular dichroism spectral change was not observed upon binding of the guest to the analogous host without OH sites. These results strongly suggest that the guest is conformationally fixed through hydrogen bonding between the carbonyl group of the guest and the steroidal hydroxyl group of the host. The assembly of only four steroid residues on the macrocyclic ring probably provided a hydrophobic nanocavity for hydrogen bonding. 相似文献
64.
Tadashi Kitamura Daisuke Nishino 《IEEE transactions on systems, man, and cybernetics. Part B, Cybernetics》2006,36(2):353-365
The design clue for the remote control of a mobile robot is inspired by the Talwar's brain-machine interface technology for remotely training and controlling rats. Our biologically inspired autonomous robot control consciousness-based architecture (CBA) is used for the remote control of a robot as a substitute for a rat. CBA is a developmental hierarchy model of the relationship between consciousness and behavior, including a training algorithm. This training algorithm computes a shortcut path to a goal using a cognitive map created based on behavior obstructions during a single successful trial. However, failures in reaching the goal due to errors of the vision and dead reckoning sensors require human intervention to improve autonomous navigation. A human operator remotely intervenes in autonomous behaviors in two ways: low-level intervention in reflexive actions and high-level ones in the cognitive map. Experiments are conducted to test CBA functions for intervention with a joystick for a Khepera robot navigating from the center of a square obstacle with an open side toward a goal. Their statistical results show that both human interventions, especially high-level ones, are effective in drastically improving the success rate of autonomous detours. 相似文献
65.
Daisuke Nagamatsu Masanori Maeda Keisuke Hashimoto Kenji Okumoto Hiroshi Kageyama Yasuhiko Shirota 《Journal of the Society for Information Display》2005,13(5):399-404
Abstract— A novel emitting vinyl polymer, poly[4‐(7‐{4‐[N,N‐bis(9,9‐dimethylfluoren‐2‐yl)amino]phenyl}‐2,1,3‐benzothiadiazol‐4‐yl)phenylethylene] (PVFABT), was designed and synthesized. The new vinyl polymer was found to form smooth amorphous films with a high glass‐transition temperature of 199°C. The polymer possesses bipolar character with both electron‐donating and accepting properties. It undergoes reversible anodic oxidation and cathodic reduction to give stable cation and anion radicals. It exhibits intense orange fluorescence in solution and as film. A multilayer organic electroluminescent device using PVFABT as an emitting material emitted orange light, exhibiting high performance. 相似文献
66.
Toshinori Kawabata Hoe I. Ling Yoshiyuki Mohri Daisuke Shoda 《Canadian Metallurgical Quarterly》2006,132(10):1354-1359
The existing design guidelines for buried flexible pipes are limited to depth up to 10?m. The increasing use of difficult terrains for infrastructure, landfills, and residential and industrial developments has prompted installation of drainage pipelines under 20–30?m high fills. This paper presents the behavior of an instrumented flexible pipe buried under a 47.1?m deep fill. For filling above 20?m, the measured vertical stress above the pipe exhibited a concave distribution, corresponding to 90 and 110% of the average vertical pressure at the center and edges of the pipe, respectively. The measured results suggest that a triangular lateral pressure distribution can lead to overly conservative and uneconomical results for high fills while Spangler’s analysis is unconservative. Based on the measured results, a revised vertical and lateral earth pressure diagram was proposed for the design of flexible pipe under high fills >20?m. This paper proposes closed-form analyses for estimating the moments and displacements of the pipe subjected to high fill earth pressures. These closed-form solutions agree well with the measured pipe displacements and strains. 相似文献
67.
A current measurement method through magnetic field detection by magnetic force microscopy was proposed and demonstrated. We observed the magnetic field induced by an AC below 2.2 μA around a GaAs/AlGaAs mesa stripe. To achieve high sensitivity in magnetic field detection, we tuned the AC bias frequency to the torsional resonant frequency of the cantilever. As a result, the sensitivity of the magnetic field detection was much improved and specific features of the magnetic field around the mesa stripe were clearly observed at a current in sub-μA range. 相似文献
68.
Microstructures and magnetic domain structures of precipitation-hardened Sm-Co permanent magnets were systematically investigated by analytical electron microscopy and electron holography. By an elemental mapping method with energy-dispersive X-ray spectroscopy, the change in the local distribution of additive elements, i.e. Cu, Fe and Zr, in Sm-Co magnets with various heat treatments was visualized and the enrichment of Zr in the Z-phase with a width of approximately 1 nm was clarified directly. Detailed analysis with electron holography revealed that considerable fluctuation in the distribution of lines of magnetic flux in the step-aged magnet was due to the chemical partitioning of additives and resulted in magnetic hardening during the magnetization process. 相似文献
69.
Matsui J Akamatsu K Nishiguchi S Miyoshi D Nawafune H Tamaki K Sugimoto N 《Analytical chemistry》2004,76(5):1310-1315
A molecularly imprinted polymer with immobilized Au nanoparticles (Au-MIP) is reported as a novel type of sensing material. The sensing mechanism is based upon the variable proximity of the Au nanoparticles immobilized in the imprinted polymer, which exhibits selective binding of a given analyte accompanied by swelling that causes a blue-shift in the plasmon absorption band of the immobilized Au nanoparticles. Using adrenaline as the model analyte, it was shown that molecular imprinting effectively enhanced the sensitivity and selectivity, and accordingly, Au-MIP selectively detects the analyte at 5 microM. The combination of molecular imprinting and the Au nanoparticle-based sensing system was shown to be a general strategy for constructing sensing materials in a tailor-made fashion due to wide applicability of the imprinting technique and the independence of the sensing mechanism from the analyte recognition system. 相似文献
70.
Tanaka N Kimura H Tokuda D Hosoya K Ikegami T Ishizuka N Minakuchi H Nakanishi K Shintani Y Furuno M Cabrera K 《Analytical chemistry》2004,76(5):1273-1281
Simple and comprehensive two-dimensional (2D)-HPLC was studied in a reversed-phase mode using monolithic silica columns for second-dimension (2nd-D) separation. Every fraction from the first column, 15 cm long (4.6-mm i.d.), packed with fluoroalkylsilyl-bonded (FR) silica particles, was subjected to the separation in the 2nd-D using one or two octadecylsilylated (C(18)) monolithic silica columns (4.6-mm i.d., 3 cm). Monolithic silica columns in the 2nd-D were eluted at a flow rate of up to 10 mL/min with separation time of 30 s that meets the fractionation every 15-30 s at the first dimension (1st-D) operated at a flow rate of 0.4-0.8 mL/min. Three cases were studied. (1) In the simplest scheme of 2D-HPLC, effluent of the 1st-D was directly loaded into an injector loop of 2nd-D HPLC for 28 s, and 2 s was allowed for injection. (2) Two six-port valves each having a sample loop were used to hold the effluent of the 1st-D alternately for 30 s for one 2nd-D column to effect comprehensive 2D-HPLC without the loss of 1st-D effluent. (3) Two monolithic silica columns were used for 2nd-D by using a switching valve and two sets of 2nd-D chromatographs separating each fraction of the 1st-D effluent with the two 2nd-D columns alternately. In this case, two columns of the same stationary phase (C(18)) or different phases, C(18) and (pentabromobenzyloxy)propylsilyl-bonded (PBB), could be employed at the 2nd-D, although the latter needed two complementary runs. The systems produced peak capacity of approximately 1000 in approximately 60 min in cases 1 and 2 and in approximately 30 min in case 3. The three stationary phases, FR, C(18), and PBB, showed widely different selectivity from each other, making 2D separations possible. The simple and comprehensive 2D-HPLC utilizes the stability and high efficiency at high linear velocities of monolithic silica columns. 相似文献