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31.
Despite significant advances in water based surface coating technology, the presence of surfactants in emulsion polymer binders leads to loss of performance after prolonged immersion in water, relative to solvent based coatings that are free of surfactant impurities. This study begins with water uptake evaluation of a range of emulsion polymer binders. A carboxylated styrene butadiene rubber latex (c-SBR) performed best in the latter evaluations and was selected for the formulation of an exterior grade paint and construction of a mathematical model to predict water uptake of the dry film. The c-SBR was then compounded with a range of inorganic fillers and water uptake and tensile properties were evaluated. Talc was found to be the best performing filler, and was used in a three factorial central composite design study where the simultaneous effects of talc, titanium dioxide and phenolic stabiliser on water up take were evaluated and fitted to response equations. A quadratic model was found to provide the most accurate prediction of effects associated with interactions between talc and TiO2. Certain combinations of talc and titanium dioxide were found to be synergistic in reducing the water uptake. This was considered to be associated with a packing effect stemming from the vast difference in particle size between talc and titanium dioxide particles. An optimised formulation was finally prepared to meet one of the final formulation objectives; i.e., minimised water uptake. Preparation of such a formulation showed that the predicted and measured water uptake responses were in excellent agreement. This study illustrates the effectiveness of statistical experimental design methods in predicting the water uptake characteristics of water-based coatings. 相似文献
32.
Michail V. Kozlov Junwei Zhu Peter Philipp Wittko Francke Elena L. Zvereva Bill S. Hansson Christer Löfstedt 《Journal of chemical ecology》1996,22(3):431-454
The fifth abdominal segment of femaleEriocrania semipurpurella (Stephens) andE. sangii (Wood) contains a pair of exocrine glands. Hexane extracts of this segment were prepared from both species and analyzed by gas chromatography with simultaneous flame ionization and electroantennographic detection (EAD). For both species, the EAD active peaks were identified as nonan-2-one, (Z)-6-nonen-2-one, and (Z)-6-nonen-2-ol by means of mass spectrometry and comparison of retention indices with those of synthetic standards. Enantiomeric separation of chiral alcohols from the female extracts was achieved by gas chromatographic analysis on a cyclodextrin column. InE. semipurpurella, a mixture of (2S,6Z)-nonen-2-ol and (2R,6Z)-nonen-2-ol (2: I) was found, whereas inE. sangii (2S,6Z)-nonen-2-ol was the predominant enantiomer and only traces of theR enantiomer were indicated by the antennal response. In field tests, a blend of the three compounds was not attractive to conspecific males. A subtractive assay showed that the alcohol in various enantiomeric mixtures was the only attractive compound, whereas addition of (Z)-6-nonen-2-one to the alcohol completely inhibited the attraction of both species. A trapping experiment including a wide range of ratios between theR andS enantiomers showed that baits containing 95–100% of theS enantiomer were attractive to maleE. sangii, whereas males ofE. semipurpurella were attracted to all tested ratios of the enantiomers. However, the response profiles of maleE. semipurpurella differed between populations from southern Sweden, south Finland, and the Kola Peninsula in Russia. In south Sweden males were maximally attracted to a racemic mixture of the alcohols. At the Kola PeninsulaE. semipurpurella was attracted to baits containing 95–100% of theR enantiomer. In south Finland all tested ratios between 0 and 100%R enantiomer trappedE. semipurpurella, but the trap catches appeared to be bimodally distributed with peaks around 15 and 70%R enantiomer. The trapping results suggest the existence of pheromone races or sibling species among the specimens identified asE. semipurpurella.Dedicated to Prof. H. J. Bestmann on the occasion of his 70th birthday. 相似文献
33.
Amanda Baker Michael Lanagan Clive Randall Elena Semouchkina George Semouchkin Khalid Z. Rajab Richard Eitel Khalid Z. Rajab Raj Mittra Sorah Rhee Peter Geggier Claus Duschl Günter Fuhr 《International Journal of Applied Ceramic Technology》2005,2(6):514-520
At the Keck Smart Materials Integration Laboratory at Penn State University, low-temperature co-fired ceramic (LTCC) material systems have been used to fabricate a number of devices for a variety of applications. This article presents an overview of the integration of the concepts and materials that we have used to achieve miniaturization and unique device function. Examples of microwave filters, metamaterial antennas, and a dielectrophoretic cell sorter will be presented, with emphasis on device modeling and design, prototype construction methods, and test results. 相似文献
34.
Alberto Doretto Francesca Bona Elisa Falasco Daniele Morandini Elena Piano Stefano Fenoglio 《河流研究与利用》2020,36(1):91-101
Droughts are affecting an increasing number of lotic ecosystems worldwide due to the combined effects of climatic and anthropogenic pressures. Unlike naturally intermittent rivers, where the drying phase is a part of the annual flow regime, water scarcity in Alpine rivers represents a relatively recent phenomenon and, therefore, a major threat for the biodiversity of these lotic ecosystems. However, Alpine stream community response to drought is still poorly investigated. Here, we assess the recovery of macroinvertebrates in two Alpine streams after a supraseasonal drought. As water returned, a total of 10 sampling sessions were carried out, and temporal patterns in diversity, density, and taxonomic composition of benthic communities, as well as in the percentage of functional feeding groups, were investigated. We found that the resistance of invertebrate communities in Alpine streams is generally low: drought markedly reduced the diversity and density of macroinvertebrates. Conversely, our results suggest that the passive dispersal by drift from the upstream river sections seems the most probable mechanism promoting the post‐drought recovery. Nevertheless, this resilience ability appears to be stream specific and influenced by intrinsic stream characteristics, including the flow permanence and distance from the nearest upstream perennial reach. This work sheds light on the ecological consequences of droughts on macroinvertebrate communities. As flow intermittency in Alpine areas is expected to intensify under current global change scenarios, results of this study provide important information to predict changes in the taxonomic composition and diversity of macroinvertebrate communities. 相似文献
35.
Adel Al Rai Elena Stojanovska Yasin Akgul Mohammad Mansoob Khan Ali Kilic Safak Yilmaz 《应用聚合物科学杂志》2021,138(7):49835
Highly porous free-standing co-poly(vinylidene fluoride)/modacrylic/SiO2 nanofibrous membrane was developed using electrically-assisted solution blow spinning method. The performance and the potential of the membrane as a lithium-ion battery separator were investigated. The addition of modacrylic enhanced the solution spinnability that resulted in defect-free membranes. Moreover, the presence of modacrylic enhanced the dimensional and thermal stabilities, while the addition of hydrophilic SiO2 nanoparticle enhanced both mechanical property and ionic conductivity. Combustion test results illustrated that the presence of modacrylic provide flame retarding property over a set of different polymeric-based membranes. Electrochemical performance results showed that the developed membrane can increase the battery capacity compared with the commercial separator. 相似文献
36.
Robustness of ISS systems to inputs with limited moving average: Application to spacecraft formations 下载免费PDF全文
Esten Ingar Grøtli Elena Panteley Antoine Chaillet Jan Tommy Gravdahl 《国际强度与非线性控制杂志
》2016,26(4):816-833
》2016,26(4):816-833
We provide a theoretical framework that fits realistic challenges related to spacecraft formation with disturbances. We show that the input‐to‐state stability of such systems guarantees some robustness with respect to a class of signals with bounded average‐energy, which encompasses the typical disturbances acting on spacecraft formations. Solutions are shown to converge to the desired formation, up to an offset, which is somewhat proportional to the considered moving average of disturbances. In the presence of fast peaking perturbations, the approach provides a tighter evaluation of the disturbances' influence, which allows for the use of more parsimonious control gains. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
37.
38.
A basic goal in property testing is to identify a minimal set of features that make a property testable. For the case when the property to be tested is membership in a binary linear error-correcting code, Alon et al. (Trans Inf Theory, 51(11):4032–4039, 2005) had conjectured that the presence of a single low-weight codeword in the dual, and “2-transitivity” of the code (i.e., the code being invariant under a 2-transitive group of permutations on the coordinates of the code) suffice to get local testability. We refute this conjecture by giving a family of error-correcting codes where the coordinates of the codewords form a large field of characteristic two, and the code is invariant under affine transformations of the domain. This class of properties was introduced by Kaufman & Sudan (STOC, 2008) as a setting where many results in algebraic property testing generalize. Our result shows a complementary virtue: This family also can be useful in producing counterexamples to natural conjectures. 相似文献
39.
Elena Baralis Andrea Bianco Tania Cerquitelli Luca Chiaraviglio Marco Mellia 《Computer Networks》2013,57(17):3300-3315
Internet measured data collected via passive measurement are analyzed to obtain localization information on nodes by clustering (i.e., grouping together) nodes that exhibit similar network path properties. Since traditional clustering algorithms fail to correctly identify clusters of homogeneous nodes, we propose the NetCluster novel framework, suited to analyze Internet measurement datasets. We show that the proposed framework correctly analyzes synthetically generated traces. Finally, we apply it to real traces collected at the access link of Politecnico di Torino campus LAN and discuss the network characteristics as seen at the vantage point. 相似文献
40.
Elena Molina Mercedes Ramos Pedro J. Martin-álvarez 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1995,201(4):331-335
Stepwise multiple linear regression (SMLR) and principal components regression (PCR) have been used to predict the percentages of cows', goats' and ewes' milk in Iberico cheese, using the results obtained by electrophoretic analysis (PAGE and IEF) of whey proteins, using standard cheeses. Similar predictions of the percentages of milks from the three species were obtained when either SMLR or PCR were applied to the electrophoretic data, i.e. the optical intensity of the electrophoretic bands (PAGE or IEF) of the whey proteins. The root mean square error of prediction in cross-validation (RMSEPCV) was lower than 4% in all cases. 相似文献