厚向异性板应力应变强度表述方法讨论

从希尔 (Hill)正交各向异性体二次屈服函数出发 ,可以导出厚向异性板应力强度 (等效应力 )与应变强度 (等效应变 )的两组表达式 ;本文讨论了采用两组不同表述方法的选择 ,并利用单向拉伸与双向等拉两种实验作了可比性的分析比较     

Preparation and properties of PAn/ATTP/PE conductive composites

Polyaniline/Attapugite/PE（PAn-ATTP/PE）composites containing particles with core-shell structure were obtained via the two-step blending processs. The experimental condition is as follows： Organo-attapulgite and PAn was obtained by modifying attapulgite with laury benzenesulfonic acid sodium salt and, then added to PE. The electrical conductivity, structure and properties of the composites were studied. Under the function of shear stress, core-shell structure particles with ATTP as the core and PAn as the shell were formed in the composites. The structure of PAn-ATTP/PE composites were characterized by FTIR,XRD,SEM, etc, respectively. The effects of concentration of doping agent on the conductivity and mechanical property of the composites were investigated. The mechanical properties and impact fracture surface of the ternary composites were studied by means of the tensile tester, SEM, etc. The results show that polyaniline encapsulated ATTP enhances the strength of the PE. And the conductivity of PAn-ATTP/PE composites of is improved effectively when polyaniline encapsulated ATTP is added. The composite have good conductivity when 10% polyaniline encapsulated ATTP is added.     

铸件内析出性气孔形成及演化的直接观察与分析

采用透明模型合金实时观察了铸件析出性气孔的形成发展,结果发现,纯物质凝固时,析出性气孔的产生发生于凝固型壳形成之后,随着凝固自型壁向中心凝固,呈现自周边向中心的气条生长。对于合金凝固,析出性气孔在凝固基本完成之后伴随着热裂及缩松的发生开始产生,呈现一定的偏聚现象。浇注前熔体过热度的提高将使析出性气孔更加密集,铸型和环境温度的降低有利于降低气孔的数量及分布范围,采用真空除气,可有效地抑制析出性气孔的产生和热裂缩松缺陷的形成。     

高频感应钎焊中电源频率的优化选择

在高频感应钎焊的过程中，要获得良好的钎焊接头，必须要根据接头材料的物理性能选择合适频率的高频电源，采用计算机数值分析手段建立了感应加热电源及其频率范围的选择数值分析模型。研究表明，数值解析法可以作为高频感应钎焊感应加热设备设计的重要方法。在对高频电源电流频率等参数的选择时，利用数值解析模型所得到的解析近似解进行频率选择比传统经验公式更精确。因为后者由平面电磁波在导电媒质中的传播特性导出，更适合于板状结构感应加热时频率的选择。而对于管状或其它复杂形状，利用数值解析解可以较好地对高频电源的频率进行优化选择。     

混合盐法制备TiB2/Al复合材料的研究现状

由于TiB2/Al复合材料优良的性能,使其在航空航天和汽车制造等行业中具有广阔的应用前景。本文从混合盐法的原理、有效形核相等方面进行了阐述与分析,对材料的组织、性能和热处理进行了简要介绍,对材料的主要问题和现有解决方法作了分析。     

金属板料成形数值模拟的研究现状

本文对板料成形数值模拟的几个主要研究方向 :有限元算法、接触与摩擦、成形极限图、缺陷等的研究现状进行了介绍 ,并且讨论了板料成形数值模拟今后的研究方向     

Theoretical prediction and experimental realization of transition metal doped rutiles as diluted magnetic semiconductors

1. Introduction The new research area of ‘spintronics’ seeks to extend the properties and applications of electronic devices by making use of the spin of electrons in ad- dition to their charge. The development of magnetic semiconductors would be compatible with standard semiconductor technology and open new opportuni- ties. The so-called diluted magnetic semiconductor (DMS) is used to denote the no magnetic semicon- ductor doped with magnetic ions, and there have been considerable progress…     

SiCp/Al复合材料热处理及统计分析

采用四因素多水平组合热处理试验与统计分析相结合的方法研究了粉末冶金制备的12%SiCp/6066Al(体积分数)复合材料的热处理工艺参数与硬度间的关系.结果表明,复合材料与基体合金相比具有峰值提前效应;热处理工艺参数主效应由强到弱依次为时效时间、固溶温度、时效温度、固溶时间;时效时间与时效温度一级交互作用也较重要,其他一级、二级和三级交互作用较小.12%SiCp/6066Al复合材料的优化热处理工艺参数为530℃固溶90min,水淬170℃时效6h.     

4-methoxy-2,6-bis(3,5-dimethylpyrazoyl)-1,3,5-triazine modified carbon paste electrode for trace Cu(Ⅱ) determination by differential pulse volt-ammetry

A differential pulse voltammetric method was developed for the sensitive and selective determination of Cu(Ⅱ) at 4-methoxy-2,6-bis(3,5-dimethylpyrazoyl)-l,3,5-triazine modified carbon paste electrode in 0.05 mol/L KHC8H4O4 solution (pH = 4.02). The oxidation peak of Cu(Ⅱ) was observed at 0.065 V(vs Ag/AgCl) by scanning the potential in positive direc-tion. The analysis procedure consisted of an open circuit accumulation step in stirred sample solution. It was followed by medium exchange to a clean solution and subsequently an anodic potential scan was affected to obtain the voltammetric peak. The current was proportional to the concentration of the Cu(Ⅱ) ion in a range of 1× 10-7-1×10-4 mol/L for 6 min accumulation; the most of metal ions did not interfere with the determination. The developed method was applied to Cu(Ⅱ) determination in coal-ash sample, the results agreed with that of atomic adsorption spectroscopy(AAS).     

DZG-10焦化汽油加氢精制催化剂的开发和工业应用

介绍了DZG-10焦化汽油加氢精制催化剂的开发过程和工业应用。通过对载体的改性，提高了大孔所占比例,将催化剂外形改为齿球形，增大了催化剂的外表面积，提高了催化剂的活性和机械强度。从连续平稳运转26个月情况来看，催化剂床层压差较低，说明催化剂床层结垢、结焦和催化剂破损情况不明显。开发的DZG-10催化剂是一种优良的纯焦化汽油加氢精制催化剂，具有较好的应用前景。