溶胶－凝胶二氧化硅驻极体薄膜的物理化学改性

实验研究了由溶胶－凝胶法制备二氧化硅驻极体薄膜的工艺。用红外透射谱、扫描电子显微镜以及驻极体等温表面电位测量和热刺激放电等实验考察了热处理和化学表面修正两个关键工艺对溶胶－凝胶二氧化硅样品驻极体性能的影响。结果表明经过高温条件下一定时间的热处理和化学表面修正，可以制备出性能优良的驻极体薄膜     

An infrared spectroscopic study of the mechanism of chloromethane conversion to higher hydrocarbons on HZSM5 catalyst

Investigation of the reaction mechanism of chloromethane on ZSM5 is a new topic. In this work an in situ FTIR technique was employed to study the conversion processes of chloromethane, the active sites on HZSM5, and the desorption state of surface species. The catalytic conversion of chloromethane to higher hydrocarbons was also studied. It is demonstrated that chloromethane can be reversibly adsorbed on acidic sites of HZSM5 at room temperature. At 100°C chloromethane is irreversibly and dissociatively adsorbed on the strong acidic sites of HZSM5, on which surface methoxyl is formed as proved by infrared characteristic C-H stretchings of-CH₃ at 2960 and 2870 cm^–1. Alkoxyls are produced and adsorbed on the catalyst surface as characterized by the infrared absorption bands of -CH₂-groups at 1460 and 2930 cm^–1. At 100°C the adsorbed methoxyl and alkoxyls are the main surface species, and a small amount of aromatics might exist as detected by a characteristic absorption band at 1510 cm^–1. Between 100 and 200°C the adsorbed surface methoxyl and alkoxyls are converted to aromatics, and the occupied OH groups partially appear. At temperature higher than 300°C the adsorbed aromatics are thermally desorbed into the gas phase. Aromatics and alkanes are the main products in catalytic conversion. These results reveal that the formation of aromatics from methoxyl and alkoxyls is easier than the desorption of aromatics from HZSM5 catalyst. An alkoxyl mechanism is proposed for the conversion of chloromethane on HZSM5 based upon the experimental results and the three assumptions: (a) The primary C-C bond is formed from surface methoxyl groups via the methoxyl group polarization and C-H bond weakening, (b) The adsorbed alkoxyls are converted to aromatics via hydrogen transfer and bond rearrangement similar to the conventional carbenium ion mechanism for the aromatization of olefins and alkanes on HZSM5. The hydrogen atoms from the aromatization stimulate the desorption of alkoxyls to alkanes. (c) At temperature higher than 300°C surface reactions and desorption of adsorbed species take place simultaneously, determining the product distribution in the catalytic conversion.     

Reengineering the Internet for Better Security

The growing proliferation of malware is raising doubts about the Internet's future. Security measures primarily target inbound traffic, but service providers have no incentive to stop attacks and spam at the source. A proposed certification scheme motivates providers to control outgoing traffic, efficiently increasing overall security while preserving the Internet's open, decentralized structure     

美国的灭火与救援机器人研发综述

设想某一个城镇生产木材调色板的流水线车间里 ,由于电器原因引发了一场火灾 ,致使建筑物坍塌。没有人能够确切地说出有多少工人被埋压在里面 ,更糟的是 ,当毗邻墙体坍塌时 ,隔壁的旧轮胎储藏室也被埋压在下面。于是市消防局派遣一批机器人去现场救援。第一个到达的机器人进入现场调查情况 ,该机器人能忍耐80 0℃的高温炙烤 ,身上安装了摄像机 ,可以给 90 m外的控制室发送图片 ,控制室的指挥人员就可以根据图片决定是否派消防队员冒险进入现场。第二个机器人是无人驾驶卡车 ,进入后便从 75 m远的地方以2 6 gal/ s的速度往火场喷水 ,并用它所…     

复杂形体目标激光散射特征测量系统的研制

复杂形体目标激光散射特征的测量系统中，利用反射式离轴光路满足了可见到远红外波段的测量需要，通过大孔径（250mm）物方远心接收光路实现了对实际远场的模拟测量，以光滑镀金球体作为标准器，可直接获得任意目标散射截面的绝对值。在0．6328、1．06和10．6μm三个波段针对标准器的实测结果表明，平均误差小于4．95％。     

中置式与后置式副产蒸汽氨合成塔的研究

带中置锅炉的氨合成塔和带后置式锅炉的氨合成塔，在结构和节能方面有许多异同之处．本文经过计算，定量地对这两种塔进行比较．     

ε－拟可微规划的Fritz John型条件和Knhn－Tucker型条件

讨论了不等式约束下的ε－拟可微规划的局部最优解问题，给出了这一问题的ＦｒｉｔｚＪｏｈｎ型条件和Ｋｕｈｎ－Ｔｕｃｋｅｒ型条件，本文也是对Ｇｏｒｏｋｈｏｖｉｋ结果的推广     

论企业有效培训

企业培训是企业最有价值的投资,是一种双赢投资。开展有效的企业培训应建立保证措施,做好需求分析,选择适当的培训方式与内容,加强对培训的管理。     

语音提示电缆断点测试仪的研制与应用

查找电缆断点是电缆维修中的难题,为此,我们对原来的电缆断点测试仪进行了改进,研制出了可以测试各种电缆并有语音提示功能的电缆断点测试仪,本文详细地介绍了这种语音提示电缆断点测试仪的工作原理、使用方法及其技术指标.