Effects of Process Conditions on Desalting and Demetalization of Crude Oil

The efficiency of desalting for six crude oils was studied with a SY-1 dynamic simulation experimental installation. The demulsifier DC2 was examined for 1#, 2#, and 4# crude oil and DC4 was used for 3#, 5#, and 6# crude oil. The effects of temperature, electric field gradient, dosage of demulsifier, and washing water on the desalting efficiency of six crude oils were investigated. The results showed that at the optimization process condition after desalting, the desalting efficiency and the salt content of 1# crude oil reached 89.17% and 1.92 mg/L; that of 2# crude oil reached 85.08% and 1.04 mg/L; that of 3# crude oil reached 91.06% and 1.35 mg/L; that of 4# crude oil reached 81.67% and 1.51 mg/L; that of 5# crude oil reached 81.03% and 2.32 mg/L; and that of 6# crude oil reached 86.64% and 2.67 mg/L. Different crude oils have different metal contents. Three assistants, ammonium nitrate (TJ1), nitric acid (TJ3), and polyamine carboxylate (TJ4), were used to improve the efficiencies of desalting and demetalization of six crude oils. TJ4 was more efficient in removing calcium and iron for 1# and 2# crude oil. TJ1 was more efficient in desalting and demetalizing 5# crude oil. The efficiencies for removal of calcium, iron, nickel, and vanadium respectively reached 99.89%, 98.33%, 20.58%, and 43.02%. TJ3 has better efficiency desalting and demetalizing for 6# crude oil. With the concentration of TJ3 increasing from 0 to 80 mg/L, the desalting efficiency increases from 31.22% to 73.54%, and the iron removal efficiency increases from 56.0% to 74.05%.     

Preparation and adsorption behavior of a cellulose‐based,mixed‐mode adsorbent with a benzylamine ligand for expanded bed applications

A novel mixed‐mode expanded bed adsorbent with anion‐exchange properties was explored with benzylamine as the functional ligand. The cellulose composite matrix, densified with stainless steel powder, was prepared with the method of water‐in‐oil suspension thermal regeneration. High activation levels of the cellulose matrix were obtained with allyl bromide because of the relative inertness of the allyl group under the conditions of the activation reaction. After the formation of the bromohydrin with N‐bromosuccinimide and coupling with benzylamine, the activated matrix was derived to function as a mixed‐mode adsorbent containing both hydrophobic and ionic groups. The protein adsorption capacity was investigated with bovine serum albumin as a model protein. The results indicated that the prepared adsorbent could bind bovine serum albumin with a high adsorption capacity, and it showed salt tolerance. Effective desorption was achieved by a pH adjustment across the isoelectric point of the protein. The interactions between the cell and adsorbent were studied, and the bioadhesion was shielded by the adjustment of the salt concentration above 0.1M. Stable fluidization in the expanded bed was obtained even in a 2% (dry weight) yeast suspension. The direct capture of target proteins from a biomass‐containing feedstock without extra dilution steps could be expected with the mixed‐mode adsorbent prepared in this work, and this would be especially appropriate for expanded bed adsorption applications. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

二次电池电极基板用复合多孔金属材料的研究

介绍了一种复合金属多孔体的制备及其方法，首先以泡沫塑料为芯膜，经过导电化处理使其具有导电性，其次进行电沉积金属铁，再进行电沉积金属镍，经过热处理后可制备出复合金属多孔体。该复合金属多孔体用铁取代金属镍，其抗拉性能优于单质泡沫镍，同时可以降低制造成本，主要用于载体如电池电极。     

自适应相干噪声衰减技术

去除噪声是必需的地震数据处理过程。由于地表条件和地震波激发、传播以及接收条件等诸多方面的原因，时常引起地震记录上出现各种相干干扰波。本文主要针对地震数据处理中地震剖面上存在的各种相干噪声，提出了时问一空间域自适应相干噪声衰减技术，以进行信噪分离。这种方法把噪声在整个处理平面上的视速度近似看作常量(正值或负值)，可以有效地消除地震剖面上的线性噪声、面波以及多次波等，并且对信号的保真度高。本文方法是复杂地区低信噪比地震数据处理的一种理想的噪声去除方法，具有运算速度快、压制噪声效果好等优点。     

200m3液氨球罐裂纹成因分析

通过检验,从球罐的应力状态、球罐的金属材料和腐蚀介质等方面对200m3液氨球罐表面裂纹的形貌及产生裂纹的原因进行了分析,确定了球罐的裂纹是应力腐蚀裂纹,并对球罐进行了强度计算及安全评估。     

在备件招标采购中运用"定质比价法"初探

针对公司在备件采购中存在的质量、价格等问题，探讨了如何使用“定质比价法”这一新的招标采购方法来提高备件质量、降低成本。     

A globally convergent algorithm for transportation continuous network design problem

The continuous network design problem (CNDP) is characterized by a bilevel programming model, in which the upper level problem is generally to minimize the total system cost under limited expenditure, while at the lower level the network users make choices with regard to route conditions following the user equilibrium principle. In this paper, the bilevel programming model for CNDP is transformed into a single level convex programming problem by virtue of an optimal-value function tool and the relationship between System Optimum (SO) and User Equilibrium (UE). By exploring the inherent nature of the CNDP, the optimal-value function for the lower level user equilibrium problem is proved to be continuously differentiable and its derivative in link capacity enhancement can be obtained efficiently by implementing user equilibrium assignment subroutine. However, the reaction (or response) function between the upper and lower level problem is implicit and its gradient is difficult to obtain. Although, here we approximately express the gradient with the difference concept at each iteration, based on the method of successive averages (MSA), we propose a globally convergent algorithm to solve the single level convex programming problem. Comparing with widely used heuristic algorithms, such as sensitivity analysis based (SAB) method, the proposed algorithm needs not strong hypothesis conditions and complex computation for the inverse matrix. Finally, a numerical example is presented to compare the proposed method with some existing algorithms.     

重油催化裂化沉降器结焦原因分析

分析了重油催化裂化沉降器结焦的原因，认为反应油气中含有催化剂颗粒以及油气中重组分的冷凝是沉降器结焦的物理原因，而重芳烃、胶质、沥青质的高温缩合则是沉降器结焦的化学因素。因此，防止沉降器结焦的关键是抑制油气重组分的冷凝和减少油气在沉降器内的停留时间。     

Piezoelectric Nanogenerators for Self-Powered Nanodevices

A novel approach converts nanoscale mechanical energy into electric energy for self-powering nanodevices.In our own work, we've used piezoelectric zinc-oxide nanowire (ZnO NW) arrays to demonstrate a novel approach for converting nanoscale mechanical energy into electric energy. Here, we review the fundamental principle behind the nanogenerator, present an approach for improving its performance, and discuss some of the challenges we face in pushing this technology to reach its potential.