Enhanced electrocatalytic performance of cyano groups containing conducting polymer supported catalyst for oxidation of formic acid

A new palladium (Pd) based catalyst was developed using poly(diphenylamine-co-3-aminobenzonitrile) (P(DPA-co-3ABN)) as the new catalyst support. The sizes, distribution and stability of Pd nanoparticles (Pd NPs) are strongly influenced by the cyano group (–CN) present in P(DPA-co-3ABN). Field emission scanning electron microscopy image and energy dispersive x-ray analysis revealed good dispersion of Pd NP onto P(DPA-co-3ABN) matrix. The electrocatalytic activity of P(DPA-co-3ABN)/Pd catalyst electrode (CE) was investigated in terms of formic acid (FA) electro oxidation. The onset potential and catalytic current for the electro oxidation of FA are higher at P(DPA-co-3ABN)/Pd-CE as compared to PdNPs loaded pristine PDPA catalyst electrode (PDPA/Pd-CE). P(DPA-co-3ABN)/Pd-CE exhibited 18 time higher electrocatalytic current than PDPA/Pd-CE for oxidation of FA.     

Integrated electro-optic lens/scanner in a LiTaO3 single crystal

We report what we believe to be the first stand-alone integrated electro-optic lens and scanner fabricated on a single crystal of Z-cut LiTaO(3). The independently controlled lens and scanner components consist of lithographically defined domain-inverted regions extending through the thickness of the crystal. A lens power of 0.233 cm(-1) kV(-1) and a deflection angle of 12.68 mrad kV(-1) were observed at the output of the device.     

Analyses of Two Different 1-Server Systems

In this paper, the availability and the reliability of two 1-server systems with redundancy have been obtained. System 1 consists of n subsystems in series; each subsystem consists of two redundant i.i.d. components in `parallel' (cold standby) and one server. The times to failure of the components are exponentially distributed; their repair time distributions are arbitrary and different. System 2 consists of n dissimilar units and one server. The times to failure of the units are arbitrarily distributed; the repair rates are constant but all different. Explicit expressions for the Laplace transform of the mean down-time of the system in (0, t) and for the mean time to system failure have been obtained. A few particular cases are discussed.     

Changes in the glaciers of Chandra–Bhaga basin,Himachal Himalaya,India, between 1980 and 2010 measured using remote sensing

This study reports the glacier changes of Chandra–Bhaga basin, northwest Himalaya, India, from 1980 to 2010. Satellite remote-sensing data from the Landsat Multispectral Scanner (MSS) and Thematic Mapper (TM), the Linear Imaging Self Scanning Sensor (LISS) and Advanced Wide Field Sensor (AWiFS) of the Indian Remote Sensing (IRS) series, and the Shuttle Radar Topography Mission (SRTM) digital elevation model (DEM) were used to study the changes in glacier parameters such as glacier area, length, snout elevation, and the impact of glacier topographical parameters (glacier slope, aspect, and altitude range) on the glacier changes. It was found that the total glaciated area had shrunk to 368.2 km² in 2010 from 377.6 km² in 1980, a loss of 2.5%. The average position of glacier terminuses retreated by 465.5 ± 169.1 m from 1980 to 2010 with an average rate of 15.5 ± 5.6 m year^?1. The decadal scale analysis showed that the average rate of retreat had increased the most in the recent decade. A moraine-dammed lake located in the study region was found to have expanded in area from (0.65 ± 0.01) km² in 1980 to (1.26 ± 0.03) km² in 2010. Glaciers with steep slope and less altitude range have lost more area than the glaciers having gentle slope and greater altitude range.     

Semitransparent poly(styrene‐r‐maleic anhydride)/alumina nanocomposites for optical applications

This article presents the development and characterization of transparent poly(styrene‐r‐maleic anhydride) (SMA)/alumina nanocomposites for potential use in optical applications. Chemically treated spherical alumina nanoparticles were dispersed in an SMA matrix polymer via the solution and melt‐compounding methods to produce 2 wt % nanocomposites. Field emission scanning electron microscopy was used to examine the nanoparticle dispersion. When the solution method was used, nanoparticle reagglomeration occurred, despite the fairly good polymer wetting. However, through the coating of the alumina nanoparticles with a thin layer (ca. 20 nm) of low‐molecular‐weight SMA, reagglomeration was absent in the melt‐compounded samples, and this resulted in excellent nanoparticle dispersion. The resultant nanocomposites were semitransparent to visible light at a 2‐mm thickness with improved UV‐barrier properties. Their impact strengths, tensile strengths, and strains at break were slightly reduced compared with those of their neat resin counterpart, whereas a small enhancement in their moduli was achieved. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Cost-benefit analysis of a one-server two-unit cold standby system with repair and preventive maintenance

This paper deals with the cost-benefit analysis of a one-server two-identical-unit cold standby system with repair and preventive maintenance (PM). The PM is of the type where the operating unit is taken up for PM whenever the other unit is available for operation. Initially, one unit is placed in operation and the other unit is kept as a cold standby. When the operating unit fails while the other unit is under service (repair or PM), the system breaks down. The busy period of the server in a time interval (O, t] is divided into time spent for repair and time spent for PM. By identifying regenerative epochs, suitable expressions for the expected values of these times are obtained. The pointwise availability is also derived. With the assumptions that a revenue is earned linearly with up-time, and repair and PM costs are incurred linearly with repair and PM times, respectively, the net expected revenue for a period (O, t] is derived. A particular case where the time to failure of the operating unit is 2-Erlang and the times for repair and PM are exponential has been analysed.     

Higher moments in cost-benefit analysis

This paper deals with the cost-benefit analysis of one-server two-unit hot standby system with imperfect switch where the repair densities depend upon the type of items (unit/standby/switch) waiting for repair. Initially one unit is put to operation (switch is working at t = 0) and the other unit is kept as a hot standby. The revenue as well as the cost of repair are arbitrary functions of time. Explicit expressions are obtained for expected net gain in [0,t] from which other characteristics like expected busy period due to repair of unit/standby/switch, expected up-time, expected number of repairs completed of unit/standby/switch etc. can be obtained.     

Hydrogen generation and separation using Gd0.2Ce0.8O1.9−δ–Gd0.08Sr0.88Ti0.95Al0.05O3±δ mixed ionic and electronic conducting membranes

Decomposition of steam under a chemical driving force at moderate temperatures offers a simple and economical way to generate hydrogen. A significant amount of hydrogen can be generated and separated by splitting steam and removing the oxygen using Gd_0.2Ce_0.8O_1.9−δ (GDC)–Gd_0.08Sr_0.88Ti_0.95Al_0.05O_3±δ (GSTA) mixed oxygen ionic and electronic conducting membranes. Hydrogen generation experiments for the self-supported thick membranes and porous supported thin membranes were conducted at different oxygen partial pressure gradients across the membrane established using H₂–H₂O mixture gas. Experimental results indicate that the hydrogen generation from steam using GDC–GSTA MIEC membranes at elevated temperatures is mainly controlled by the bulk diffusion of oxygen for the self-supported thick membranes, while the permeation process for the porous supported thin membranes is mixed controlled, i.e. the hydrogen generation/oxygen permeation process is controlled by the surface exchange reactions and bulk diffusion of oxygen through the MIEC membrane. A mathematical model for the calculation of the area specific hydrogen generation rate is proposed in this paper based on the measured oxygen partial pressures, gas compositions, and gas flow rates of the inlet and outlet gases on feed side of the membrane, as well as the permeation area of the membrane.     

Studies on structural transformation and magnetic properties in Sm2Co17 type alloys

Structural transformations and microstructural characterisation of Sm₂Co₁₇ alloys containing Fe, Cu and Zr at different stages of thermal processing have been investigated by X-ray diffraction, optical, scanning electron and transmission electron microscopes. Solution treated samples consist of a mixture of hexagonal TbCu₇ (1:7 H) and rhombohedral Th₂Zn₁₇ (2:17 R) structure types of 2:17 phase. After isothermal aging, TbCu₇ + Th₂Zn₁₇ structures transform into Th₂Zn₁₇ type structure with precipitation of Cu-rich hexagonal SmCo₅ (1:5 H) and Zr-rich platelet phases. In addition to the main phases, a soft magnetic phase of composition Zr₆(FeCo)₂₃ is formed in alloys containing higher Zr composition. Isothermal aging studies reveal that magnetic properties show a peak value when aged at 1108–1123 K for 10 h. TEM studies show cellular precipitate structure with cell interiors having 2:17 R structure, while the fully coherent cell boundaries have the 1:5 H structure. Zr-rich platelets which run across many cells and cell boundaries were found to have 1:7 H structure.     

Deposition of poly(diphenylamine‐co‐o‐chloroaniline) by pulse potentiostatic method: Growth equation and characterization

Electrochemical copolymerization of diphenylamine (DPA) with o‐chloroaniline (OCA) was performed in aqueous 4M sulfuric acid using the pulse potentiostatic method (PPSM). By employing the tunable parameters in PPSM, polymeric films were deposited under different conditions. Cyclic voltammetry was used for evaluating the characteristics of the deposited polymeric films. A suitable growth equation for the deposition of polymer, relating the charge associated for the film deposition and the pulse parameters in PPSM, was deduced. Various surface parameters are evaluated. The formation of copolymer during PPSM deposition was revealed through critical analysis of the results. The characteristic differences between the individual homopolymers, poly(diphenylamine) and poly(o‐chloroaniline) and the copolymer, poly(diphenylamine‐co‐o‐chloroaniline), were brought out. The copolymer was also synthesized through a chemical method and characterized through infrared and ultraviolet‐visible spectroscopic analysis. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 389–397, 2003