载锰氮化碳催化臭氧法降解水中草酸研究

草酸是废水中多种有机物氧化降解的中间产物,与臭氧反应速率很低,难以直接氧化去除。本研究通过热解法煅烧不同摩尔比例的三聚氰胺与醋酸锰(Ⅲ)二水合物,制备出不同负载量的载锰氮化碳催化剂,并研究了不同条件下载锰氮化碳催化臭氧法对草酸的降解效果,考察三聚氰胺与醋酸锰摩尔比、催化剂投加量、p H值、臭氧浓度等因素以及叔丁醇对草酸去除效果的影响。实验结果表明:相对于单独臭氧氧化而言,载锰氮化碳催化臭氧法可以极大的提高草酸的去除率,在投加0.15 g/L三聚氰胺与醋酸锰20∶1的催化剂后,草酸在60 min的TOC去除率可达到89.1%。叔丁醇加入对草酸的去除率影响较小,表明·OH在载锰氮化碳催化氧化草酸的过程中起作用但不是唯一因素。     

物联网技术在密云水库大坝变形监测系统中的应用

密云水库是首都北京唯一地表饮用水源地。水库大坝已安全运行50余年,大坝变形趋于稳定,2015年密云水库承担了南水北调中线工程调蓄任务,水库大坝将逐步进入高水位运行状态,对于变形以及稳定性的监测需求日益增加,在此背景下,基于物联网技术,采用智能传感器及移动通信技术建立了大坝变形监测自动化系统,本系统利用GPS作为水平位移的监测手段,利用静力水准仪作为垂直位移监测手段,充分发挥了各自的优势,通过数据应用平台集成采集的数据,使变形监测实现实时采集、传输、存储、计算及分析等功能,为及时准确地对大坝安全状况进行评估提供了数据基础,也适应了新工况下对水工监测管理的新要求。     

A THEORETICAL STUDY OF MASS AND HEAT TRANSFER IN FILM FLOW OF NONNEWTONIAN POWER LAW FLUIDS

The exact expressions of concentration and local or average Sherwood number,Sh or Sh for non-Newtonian fluids which obey the famous power law:τ={K|1/2(1/2)~(1/2)|~(n=1)}in which the flow index n takes any positive rational value,have been obtained by solving the differen-tial equation of diffusion together with the velocity distribution in the falling film flow.The use of Fourth-order Runge-Kutta method and Wegstien's iteration method by means of thecomputer yields results which are a series of values of dimensionless concentration O,local and averageSherwood number for n equal to 1/4,1/3,1/2,1/1.4,1/1.2,1,1.25,2.5,and ∞.When the flow indexn=1,i.e.for Newtonian fluids,the result agrees well with the data from the literature.     

聚1-丁烯热塑性弹性体的老化与防护

以拉伸性能为主要检测指标，考察了聚1-丁烯[P(1-Bt)]热塑性弹性体的热氧老化、紫外光老化和耐酸碱老化性能，制备了P(1-Bt)和三元乙丙胶(EPDM)防水卷材试样并进行对比：结果表明：单独使用抗氧剂1010，其用量在0．1～0．2质量份时具有较好的防热氧效果；1010与DLTP配合使用效果更佳，最佳配比为m(1010)：n(DLTP)=1：3(1010为0．2份)。热氧防老剂与紫外光吸收剂并用明显优于热氧防老剂或紫外光吸收剂单用时的防紫外光效果；ZnO对热氧老化和紫外光老化也具有很好的防护作用。P(1-Bt)制备的防水卷材的耐紫外光老化性能接近EPDM防水卷材，耐酸碱性能优于后者。     

纳米氧化锌在全钢载重子午线轮胎胎面胶和胎侧胶中的应用

研究纳米氧化锌作为活性剂替代普通氧化锌在全钢载重子午线轮胎胎面胶和胎侧胶中的应用效果.结果表明,纳米氧化锌替代普通氧化锌可以提高胶料的加工安全性和弹性,改善胎面胶的耐磨性能;纳米氧化锌减量约30%替代普通氧化锌,胎面胶和胎侧胶的综合性能较好,原材料成本降低,成品轮胎的高速性能提高.     

CONDENSING HEAT TRANSFER IN AN ADVANCED TWO-PHASE CLOSED THERMOSYPHON

1 INTRODUCTIONClosed thermosyphon has been developed to enhance heat transfer and recover wasteheat in various process industries [1,2].Stimulated by this success,a new type oftwo-phase closed thermosyphon was designed by inserting respectively two inner tubesinto the thermosyphon,one in the boiling section and the other in the condensing sec-tion.The two-phase flow boiling heat transfer coefficient was calculated successfully onthe basis of Chen's dual-mechanism [3].A boiling heat transfer model for thetwo-phase closed thermosyphon with an inner tube in the boiling section was pro-     

3D Shape Segmentation and Labeling via Extreme Learning Machine

We propose a fast method for 3D shape segmentation and labeling via Extreme Learning Machine (ELM). Given a set of example shapes with labeled segmentation, we train an ELM classifier and use it to produce initial segmentation for test shapes. Based on the initial segmentation, we compute the final smooth segmentation through a graph‐cut optimization constrained by the super‐face boundaries obtained by over‐segmentation and the active contours computed from ELM segmentation. Experimental results show that our method achieves comparable results against the state‐of‐the‐arts, but reduces the training time by approximately two orders of magnitude, both for face‐level and super‐face‐level, making it scale well for large datasets. Based on such notable improvement, we demonstrate the application of our method for fast online sequential learning for 3D shape segmentation at face level, as well as realtime sequential learning at super‐face level.     

碳纳米管在催化中的应用进展

简要介绍了碳纳米管的基本结构、特点以及制备方法,概述了碳纳米管在国内用作催化剂或催化剂载体的应用进展情况。     

扫描隧道显微镜技术在腐蚀防护研究中的应用

简述了扫描隧道显微镜技术的发展概况，着重介绍了扫描隧道显微镜在局部腐蚀、点蚀、钝化膜形成等方面的应用。     

挡水结构水下爆炸作用的离心模型试验

水下爆炸包括冲击波和气泡脉动,两者能量相当,均会对结构产生毁伤作用。水下爆炸载荷试验唯有在离心机内才满足相似关系,设计试验时宜在离心机负载范围内尽可能增加模型尺寸以减小边界效应。针对挡水结构,在离心机内布置压力传感器、高速摄像机、加速度计及应变片测试了冲击波、气泡脉动载荷及结构产生的动力响应。通过试验对比了水下爆炸和空爆产生的载荷,分析其引起结构动力响应的差异。对于水下爆炸,重力加速度的增加引起气泡脉动冲量的减小,而气泡脉动产生的峰值应变基本与气泡冲量呈线性关系,因而模拟气泡脉动对结构作用时应考虑重力效应。