230 kt/a烟气制酸系统的运行及改造情况

介绍230kt／a诺兰达炉铜冶炼烟气制酸装置的运行及技术改造。装置采用稀酸洗净化、ⅣⅠ-Ⅲ Ⅱ“3 1”两转两吸工艺流程，运行中发现板式酸冷却器堵塞、电除雾器腐蚀、气体换热器积酸和漏气等现象，通过更换为阳极保护管壳式酸冷却器、在电除雾器前增设湍冲洗涤器、调整换热管的喷铝成分等措施，收到良好的效果。     

色谱顶空法测活度系数及对三元极性体系液液平衡预测

用气相色谱顶空分析法测定 18组部分互溶三元极性体系在完全互溶区的 3个组分活度系数 ,由此拟合出 U NIQU AC过量自由焓模型参数 ,再用 U NIQUAC方程预测液液平衡。这一方法曾很好地用在水-正烷烃 -醇体系。将此法拓展到含醇、酮、酯 ,醚、卤烷烃和水等多种极性组分的三元体系液液平衡的预测 ,其结果与文献的液液平衡数据比较 ,平均均方根误差 1.4 1% ,表明本法对含极性组分的体系仍然可行     

高抗冲聚苯乙烯的阻燃研究

利用锥形量热仪(CONE)研究了阻燃高抗冲聚苯乙烯(HIPS)的燃烧性能,同时也采用垂直燃烧、氧指数等方法进行了对比测试。含十溴二苯乙烷的试样不仅保持了原有的物理机械性能,而且阻燃效果明显。相对于使用十溴二苯醚阻燃的HIPS,十溴二苯乙烷的使用不会产生多溴代二问题,产品符合一定的环保要求。     

混炼硅橡胶的配合技术(八)

介绍了2种汽车部件（密封图、汽车挡风玻璃刮片）装配用混炼硅橡胶的配制，以及硫化过程中能与接触基材粘接的混炼硅橡胶（通过添加各种增粘剂如含乙烯烃碳酸酯基或巯基乙酸酯基化合物、烷氧基硅烷、含乙烯基硅官能基过氧化物为硫化剂）的配制。     

卫生瓷坯体配方的改进

利用本地瓷石和厂内废料代替河北邢台碱、长石和部分石英生产卫生瓷，可降低产品烧成温度，提高产品质量。     

Thermal analysis of montmorillonites modified with quaternary phosphonium and ammonium surfactants

The thermal stability of seven organically modified montmorillonites (‘organoclays’) has been investigated using differential thermal analysis, differential scanning calorimetry, and thermogravimetry in conjunction with X-ray diffractometry. Six organoclays were synthesised by replacing the interlayer inorganic cations, initially present, with quaternary phosphonium and ammonium surfactant cations. The samples modified with tetrabutylphosphonium (TBP), and butyltriphenylphosphonium (BTPP) ions have an appreciably higher thermal stability than the octadecyltrimethylammonium (ODTMA)-modified clays. Thus, in the case of TBP- and BTPP-modified montmorillonites, the onset temperature of decomposition is close to 300 °C. Samples modified with hexadecyltributylphosphonium (HDTBP) ions have a lower onset temperature of decomposition of 225 °C. In comparison, the onset temperature for ODTMA-montmorillonites (obtained at different concentrations of ODTMA-bromide) ranges from 158 to 222 °C, being highest where the concentration of intercalated surfactant is lowest. The onset temperature for a commercial alkylsilane-treated quaternary ammonium-modified organoclay (S-BEN N-400FP) is 207 °C. The basal spacing of the TBP- and BTPP-modified clays is 1.7–1.8 nm, indicating a monolayer arrangement of quaternary phosphonium ions in the interlayer space, while the value of 2.5 nm for HDTBP-montmorillonite indicates a more open structure. The ODTMA-modified samples have basal spacings ranging from 1.9 to 2.1 nm, indicative of a bilayer to pseudo-trilayer arrangement. The exceptionally high basal spacing of 3.4 nm for the S-BEN N-400FP organoclay might be due to interlayer penetration of organosilane hydrolysis products during synthesis. The thermal properties of organoclays are apparently related to the nature of the surfactants and their arrangement in the interlayer space of montmorillonite.     

Finite Time Synchronization of Delayed Quaternion Valued Neural Networks with Fractional Order

Neural Processing Letters - In this article, the finite time (FT) synchronization problem of fractional order quaternion valued neural networks with time delay is investigated. Without separating...     

轧制力传感器模态与瞬态仿真分析

为满足轧机振动测试的需求,对自行设计的小型轧机的轧制力传感器进行模态和瞬态仿真分析.将轧制力传感器的分析简化为对敏感元件的分析,建立仿真分析的模型,为接近轧机的实际工作受力情况,模态分析施加定载荷,而瞬态分析施加随时间变化的载荷.仿真结果表明,轧制力传感器的各阶振动频率均远高于轧机设备的固有频率,轧制力传感器的结构不会与轧机产生共振;敏感元件关键点的位移响应与轧制力函数载荷的变化基本一致,均没有激振现象的发生,说明敏感元件的设计符合轧机振动测试的要求.