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91.
Toshiyuki Momma Hiroki Nara Shinpei YamagamiChika Tatsumi Tetsuya Osaka 《Journal of power sources》2011,196(15):6483-6487
Many efforts have been paid to realize the superior anodes for future Li batteries in either the dry Ar atmosphere or the dry air atmosphere. In this work, in order to clarify the effects of such atmospheres, the most reactive anodes of Li were freshly electrodeposited under the dry Ar or under the dry air condition. The Solid Electrolyte Interface (SEI) formed during the electrodeposition of Li anodes is revealed to have a different chemical composition and protective feature. The Li deposited under the dry air was revealed to have longer cycle life in the electrolyte than that deposited in Ar, even in the electrolyte containing ionic liquid. From the XPS results, the SEI formed in dry air is proved to be different from that formed in Ar gas atmospheres, that is, the SEI formed in dry air consists of Li2CO3 and Li nitride. In order to improve the performance of the anodes, the atmosphere for the initial preparation of the anode/electrolyte interface should be tuned. 相似文献
92.
Methylcyclohexane dehydrogenation for hydrogen production via a bimodal catalytic membrane reactor 下载免费PDF全文
Lie Meng Xin Yu Takuya Niimi Hiroki Nagasawa Masakoto Kanezashi Tomohisa Yoshioka Toshinori Tsuru 《American Institute of Chemical Engineers》2015,61(5):1628-1638
The dehydrogenation of methylcyclohexane (MCH) to toluene (TOL) for hydrogen production was theoretically and experimentally investigated in a bimodal catalytic membrane reactor (CMR), that combined Pt/Al2O3 catalysts with a hydrogen‐selective organosilica membrane prepared via sol‐gel processing using bis(triethoxysilyl) ethane (BTESE). Effects of operating conditions on the membrane reactor performance were systematically investigated, and the experimental results were in good agreement with those calculated by a simulation model with a fitted catalyst loading. With H2 extraction from the reaction stream to the permeate stream, MCH conversion at 250°C was significantly increased beyond the equilibrium conversion of 0.44–0.86. Because of the high H2 selectivity and permeance of BTESE‐derived membranes, a H2 flow with purity higher than 99.8% was obtained in the permeate stream, and the H2 recovery ratio reached 0.99 in a pressurized reactor. A system that combined the CMR with a fixed‐bed prereactor was proposed for MCH dehydrogenation. © 2015 American Institute of Chemical Engineers AIChE J, 61: 1628–1638, 2015 相似文献
93.
A novel saccharide sensor that displays a distinct color change resembling a “traffic signal” was developed. By copolymerizing boronic acid and amine monomers on a glass plate, a boronic acid‐containing thin film was obtained. Anionic blue and yellow dyes were adsorbed on the thin film, and the film was immersed in aqueous saccharide solutions containing a cationic red dye. With increase in the saccharide concentration in the solution, the thin film changes color from green to red via yellow. The observed distinct changes in color were attributed to a stepwise release and binding of dyes. The sensitivity of the saccharide sensor was dependent on the monomer composition of the thin film and increased with increasing the boronic acid content. The pH of the saccharide solution was another key factor affecting the sensing behavior, and glucose‐responsive color changes were significantly enhanced at pH 7.8. By optimizing these conditions, significant color changes in response to glucose were achieved. Saccharide selectivity was found to be in the following order: fructose > glucose > galactose = mannose > sucrose. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42679. 相似文献
94.
Kiyoyuki Yambe Hiroki Saito Kazuo Ogura 《IEEJ Transactions on Electrical and Electronic Engineering》2015,10(6):614-618
We present a measurement method of the plasma current and density in an atmospheric‐pressure plasma generated using a quartz tube, helium gas, and copper foil electrode by applying a high RF voltage. The plasma in the form of a bullet is released as a plume or jet into the atmosphere. To study the characteristics of the atmospheric‐pressure plasma, the plasma current is measured using a current probe, and the drift velocity of plasma plume is measured using a photodetector. The current of the plasma plume is estimated by subtracting the ground line current from the power line current in the circuit. The density of plasma plume n is estimated from the plasma plume current I and the drift velocity v as I = envS, where S is the cross section of plasma plume. The density of the released plasma into the atmosphere is estimated as ∼1018 m−3 by the method. © 2015 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc. 相似文献
95.
Development of biobased microwave absorbing composites with various magnetic metals and carbons 下载免费PDF全文
Shinji Kanehashi Hiroki Oyagi Toraki Iwamaru Shota Ando Kazukiyo Nagai Shinichiro Uekusa Tetsuo Miyakoshi 《应用聚合物科学杂志》2016,133(44)
The preparation and characterization of a biobased electromagnetic absorbing composites derived from natural lacquer as a renewable resource with microwave‐absorption fillers, including Ni–Zn ferrite and carbonyl iron (CI) as magnetic metals and soot and carbon nanotube (CNT) as carbon materials, were investigated in terms of the gel content, hardness, drying properties, and electromagnetic absorption properties. Interestingly, composites with ferrite and CI contained up to 320 and 550 wt %, respectively, of these compounds. This quite high loading capacity of the metal fillers in a natural‐lacquer base could have been due to the high compatibility between the filler and the natural lacquer; this indicated that the natural lacquer worked as a binder for these metals. The morphology of the biobased composite was characterized by scanning electron microscopy. The electromagnetic absorption properties of composites were characterized in the frequency range from 0.05 and 20 GHz by the reflection loss (RL) measurement method in terms of the kind of fillers and filler loading. The natural lacquer did not affect the absorption properties of the fillers. Biobased composites showed over 99% electromagnetic absorption in the frequency range 3.0–4.0 GHz for 280 wt % ferrite and 8.9–9.7 GHz for 200 wt % CI. Conversely, 10 and 20 wt % soot exhibited good performance (RL < ?20 dB) between 16.5 and 17.3 and between 8.8 and 9.2 GHz, respectively. The areas with RL values of less than ?20 dB of the CNT composites were 10.4–11.0 GHz for 5 wt % and 14.6–15.2 GHz for 10 wt %. Hence, natural lacquer can be used as a binder material for electromagnetic absorption composites. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44131. 相似文献
96.
Chikara Tsutsumi Ryouji Watanabe Ayaka Tokumaru Nao Kuwaoka Yuushou Nakayama Takeshi Shiono 《应用聚合物科学杂志》2016,133(39)
Synthetic l ‐lactide random copolymers can be employed as controlled release materials when prepared using supercritical carbon dioxide (scCO2), since they are biodegradable via hydrolysis. To determine the effects of thermal properties on polymer performance following scCO2 processing, three types of poly(l ‐lactide) having different properties were assessed. The Tm of one poly(l ‐lactide) sample (H‐100) was found to be approximately 170 °C over the processing pressure range from 8 to 18 MPa, while a second sample (H‐440) also showed a constant value of approximately 152 °C. In contrast, the poly(l ‐lactide) REVODE exhibited a Tm of 146 °C prior to processing but a higher value of 147 °C following treatment at 8 MPa. Unlike the H‐100 and H‐440, the Tm value of the REVODE tended to decrease with increasing pressure. The Tg values increased greatly under mild conditions of 8 MPa pressure and a temperature of 40 °C. In particular, the Tg values for the H‐440 and REVODE increased by 4 °C and 5 °C, respectively. All Tg values were lowest at 12 MPa and increased with increasing processing pressure, although the effect of processing temperature was minimal. The Χc DSC of the H‐100 was 18% initially but increased to 20% upon scCO2 processing at 40 °C and 14 MPa, and showed further increases at higher processing temperatures. Although the relationship between processing temperature and Χc DSC values for the H‐440 showed the same trend as observed with the H‐100, a different trend was seen for the REVODE. The Χc XRD values obtained from the XRD analyses differed from the values generated by DSC analysis, and showed a maximum degree of crystallinity following processing at 80 °C both with and without scCO2 treatment. ATR FT‐IR analyses identified peaks due to semicrystalline regions in poly(l ‐lactide) samples treated with scCO2, even when applying low temperatures. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44006. 相似文献
97.
Ryuta Shigefuku Hideaki Takahashi Hiroyasu Nakano Tsunamasa Watanabe Kotaro Matsunaga Nobuyuki Matsumoto Masaki Kato Ryo Morita Yousuke Michikawa Tomohiro Tamura Tetsuya Hiraishi Nobuhiro Hattori Yohei Noguchi Kazunari Nakahara Hiroki Ikeda Toshiya Ishii Chiaki Okuse Shigeru Sase Fumio Itoh Michihiro Suzuki 《International journal of molecular sciences》2016,17(9)
The progression of chronic liver disease differs by etiology. The aim of this study was to elucidate the difference in disease progression between chronic hepatitis C (CHC) and nonalcoholic fatty liver disease (NAFLD) by means of fibrosis markers, liver function, and hepatic tissue blood flow (TBF). Xenon computed tomography (Xe-CT) was performed in 139 patients with NAFLD and 152 patients with CHC (including liver cirrhosis (LC)). The cutoff values for fibrosis markers were compared between NAFLD and CHC, and correlations between hepatic TBF and liver function tests were examined at each fibrosis stage. The cutoff values for detection of the advanced fibrosis stage were lower in NAFLD than in CHC. Although portal venous TBF (PVTBF) correlated with liver function tests, PVTBF in initial LC caused by nonalcoholic steatohepatitis (NASH-LC) was significantly lower than that in hepatitis C virus (C-LC) (p = 0.014). Conversely, the liver function tests in NASH-LC were higher than those in C-LC (p < 0.05). It is important to recognize the difference between NAFLD and CHC. We concluded that changes in hepatic blood flow occurred during the earliest stage of hepatic fibrosis in patients with NAFLD; therefore, patients with NAFLD need to be followed carefully. 相似文献
98.
99.
Hiroki Noguchi Atsuhiko TeradaKaoru Onuki Ryutaro Hino 《Chemical Engineering Research and Design》2014
The Japan Atomic Energy Agency has been conducting research and development on the thermo-chemical iodine–sulfur (IS) process, which is one of the most attractive water-splitting hydrogen production methods that uses nuclear thermal energy. The sulfuric acid decomposer is one of the key components of the IS process. The boiling heat transfer coefficients of sulfuric acid solutions are required to design the sulfuric acid decomposer. These coefficients were measured in aqueous solutions where the mole fraction of H2O ranged from 0.17 to 0.37 (heat flux range from 16.9 kW/m2 to 5.6 kW/m2) and compared with the empirical correlations formulated for binary mixtures. A combination of the Stephan–Körner correlation, using the empirical constant A0 = 2.00, and the Nishikawa–Fujita correlation was used to predict the experimental results with an accuracy of ±10%. 相似文献
100.
Hiroki Iwamoto Alexey Stankovskiy Luca Fiorito Gert Van den Eynde 《Journal of Nuclear Science and Technology》2018,55(5):539-547
The applicability of Monte Carlo techniques, namely the Monte Carlo sensitivity method and the random-sampling method, for uncertainty quantification of the effective delayed neutron fraction βeff is investigated using the continuous-energy Monte Carlo transport code, MCNP, from the perspective of statistical convergence issues. This study focuses on the nuclear data as one of the major sources of βeff uncertainty. For validation of the calculated βeff, a critical configuration of the VENUS-F zero-power reactor was used. It is demonstrated that Chiba's modified k-ratio method is superior to Bretscher's prompt k-ratio method in terms of reducing the statistical uncertainty in calculating not only βeff but also its sensitivities and the uncertainty due to nuclear data. From this result and a comparison of uncertainties obtained by the Monte Carlo sensitivity method and the random-sampling method, it is shown that the Monte Carlo sensitivity method using Chiba's modified k-ratio method is the most practical for uncertainty quantification of βeff. Finally, total βeff uncertainty due to nuclear data for the VENUS-F critical configuration is determined to be approximately 2.7% with JENDL-4.0u, which is dominated by the delayed neutron yield of 235U. 相似文献