Effects of polyglycerol esters of fatty acids and ethylene‐vinyl acetate co‐polymer on crystallization behavior of biodiesel

Biodiesel fuels (BDF) have many problems in the cold due to their crystallization properties. In particular, precipitation of large crystals of high‐melting fractions in BDF at low temperatures remarkably changes cold flow property of BDF and, thereby, it increases the values of cold filter plugging point. In this study, we evaluated polyglycerol esters of fatty acids (PGE) and ethylene‐vinyl acetate co‐polymer (EVA) as chemical additives to improve the cold flow property of palm oil‐based FAME (PFME). The results of solid fat content measurement indicate that the simultaneous addition of PGE and EVA showed synergistic effects on suppression of crystallization of PFME, however such effect was not observed when EVA was used alone. DSC thermograms indicated that the PGE additives not only decreased the crystallization temperature but also kinetically suppressed the crystal growth. Polarized light microscopy showed that the simultaneous addition of PGE and EVA led to the formation of considerably small and fine‐dispersed crystals of PFME. These results indicate that combined effects of PGE and EVA caused the formation of fine‐dispersed PFME crystals, which could improve the viscous properties of palm oil‐based BDF at relatively cold temperatures.     

Coil design optimization for an induction evaporation process: Simulation and experiment

For the purpose of utilizing induction heating in the evaporation process, the effects of induction coil design and droplet size on induction heating efficiency are investigated. Electro-magnetic simulations with various induction coil designs were conducted to predict the electro-magnetic field distribution. The induction coils were fabricated in order to verify the simulation results under atmospheric evaporation test conditions. The electro-magnetic simulation results indicated that the magnetic field became widened around the Zn droplet when the size of the Zn droplet increased. This in turn attributed to the increase in induction heating energy efficiency. The energy efficiency of the induction coil with 4-windings was the highest among the 3-, 4-, and 5-windings induction coils. Energy efficiency tendencies derived by the atmospheric evaporation tests corresponded well to the simulation results, and maximum energy efficiency was measured to be 42% under the atmospheric evaporation tests.     

Physical property and electrical conductivity of electroless Ag-plated carbon fiber-reinforced paper

The addition of a large amount of conductive filler to paper in order to increase electrical conductivity adversely affects some physical properties of the paper. Hence, it is desirable that conductive paper can be manufactured by adding only a small amount of conductive filler. Reinforced paper was manufactured by adding (1) electroless Ag-plated carbon fiber or (2) activated carbon fiber to the pulp. We investigated the effects of adding Ag-plated carbon fiber on the microstructure, physical properties, electrical conductivity, etc., of the paper. We found that the addition of a small amount of Ag-plated carbon fiber to the pulp made it possible to manufacture conductive paper with a high level of electrical conductivity and great physical strength.     

Magnesium interlayered diamond coating on silicon

Diamond thin films have been deposited using hot filament chemical vapour deposition technique on manually scratched p-Si(1 0 0) substrate, with and without magnesium interlayer. In spite of magnesium melting point being lower (T_m = 649 °C) than the growth temperature of the substrate (T_s  750 °C) used in these experiments, it was found that high quality diamond films could be grown on Mg covered substrate. A liquid substrate is probably generated during the diamond film growth. Raman spectroscopy analysis exhibited only the triply degenerate, zone centre optical phonon peak at 1333 cm⁻¹ indicating that nearly stress free crystallites were present. Broadening of the Raman peak (11.76 cm⁻¹) indicates that some small crystallites also are present. Scanning electron and atomic force microscopy accompanied by X-ray diffraction analysis where used to compare the details of diamond film growth directly on scratched Si(1 0 0) and Mg interlayered scratched Si(1 0 0) substrates.     

The structure of the core polyol of the ether lipids fromSulfolobus acidocaldarius

The major ether-type lipid structures ofSulfolobus acidocaldarius (ATCC33909) were composed of caldarchaeol and calditoglycerocaldarchaeol. However, the characterization by nuclear magnetic resonance spectroscopy and mass spectrometry showed that the structure of calditol in calditoglycerocaldarchaeol is not nonitol, 2-(1′,2′,3′-trihydroxypropyl)1,2,3,4,5,6-hexahydroxyhexane, but 2-hydroxymethyl-1-(2,3-dihydroxypropoxy),2,3,4,5-cyclopentanetetraol with an ether linkage in the molecule. Such an intermolecular ether linkage was resistant, to BCl₃ treatment, but nonresistant to 57% HI degradation treatment conducted at 100°C for 60 h, producting 2-hydroxymethyl-1,2,3,4,5-cyclopentanepentaol from calditol as reaction product. Further, it was confirmed that the structure of calditol is essentially a derivative of glycerol, and hydrocarbon chains were conjugated to the glycerol-like site in the structure. The calditol with an ether linkage in the molecule suggested an important role regarding the properties of heat-resistance and acid-resistance observed inSulfolobales. Presented at the international workshop on “Molecular Biology and Biotechnology of Extremophiles and Archaebacteria,” Wako, Japan, August 1993.     

Spray jet penetration and distribution of modulated liquid jets in subsonic cross-flows

Modulated liquid jets injected into subsonic cross-flows are empirically studied by using a mechanical liquid jet modulation apparatus. Experimental investigations were conducted using water over a range of cross-flow velocities from 5 m/s to 143 m/s and with modulated liquid jet frequencies from 35.7 Hz to 166.2 Hz and so on. PDPA(phase Doppler particle anemometry) was employed to measure droplet diameter and velocity with various spray cross-sections from Z/d=20 to Z/d=60. The spray structure, penetration depth, SMD(Sauter mean diameter), volume flux and velocity characteristics of modulated liquid jets injected into cross-flows were examined. As oscillation of the periodic pressure that could make liquid jet moved up and down in cross-flow field, the mixing process was facilitated. This phenomenon has the advantage of mixing the spray concentration from the center area to the outer area. Also, a bulk liquid jet puff was detected in the upper field of the liquid jet surface. The modulation effect appears significant in the extent of the spray oscillation. The correlation equations for the liquid jet boundary of the upper and lower regions which related to the Strouhal number have been presented to predict the spray structure under modulation conditions. Because of the modulation frequency, an inclination of averaged SMD for the structured layer was evanescent which contributed to the promotion of the macroscopic spray mixing process. Cross-sectional characteristics of SMD had the same tendency over a range of various modulation frequencies. As the modulation frequency increased, the region of volume flux distribution also increased.     

Influence of the substrate temperature and annealing on the 1.54-µm erbium photoluminescence of a-Si:H films obtained using a glow discharge

Effective Er photoluminescence is observed at room temperature in a-Si:H films doped with Er atoms through a gas phase using powdered Er(TMND)₃ as a source of Er ions. It is shown that the conditions for deposition of the films and their subsequent annealing influence the photoluminescence intensity and its temperature dependence. The observed behavior is attributed to restructuring of the amorphous silicon matrix within an Auger excitation mechanism involving defects. Fiz. Tekh. Poluprovodn. 33, 208–210 (February 1999)     

Lymphocyte subpopulations in the mammary gland of the goat

Mammary glands of pregnant, lactating and resting goats were studied by immunohistochemistry for lymphocyte subpopulations using a panel of monoclonal antibodies. All T lymphocyte subpopulations that may have a role in the immune response, CD2+, CD4+, CD8+ and gamma delta T cells and subsets, were present in the mammary gland and were noted to increase in number progressively during pregnancy, decrease significantly during lactation, and then moderately increase during the resting period. CD4+ cells, the predominant cell type in the mammary gland, were located mainly in the connective tissue, whereas CD2+, CD8+ and TcR1-N24+ cells were predominant in the intraepithelial areas. TcR1-N6+ cells were detected almost exclusively during pregnancy, being localized mainly in the connective tissue. Their proportion decreased markedly following parturition. Very few WC1-N3+ and -N4+ cells were detected in the mammary gland. It is suggested that the majority of gamma delta T lymphocytes in the mammary gland of the goat are CD2+ CD8+ WCl-, a distinctive subset from that of the WCl+ subset in peripheral blood.     

ASMD with duty cycle correction scheme for high-speed DRAM

An analogue synchronous mirror delay with duty cycle-correction scheme (ASMDCC), to improve the data transmission performance between DRAM and system, is proposed. The ASMDCC achieves duty cycle correction and clock synchronisation at once within two clock cycles, by using a half value current source. The simulation results show the duty cycle of the internal clock is stabilised with less than ±100 ps deviation from 50% for the wide duty cycle range