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31.
The oxidation of Fe(II) with dissolved molecular oxygen was studied in sulfuric acid solutions containing 0.2 mol . dm-3 FeSO4 at temperatures ranging from 343 to 363 K. In solutions of sulfuric acid above 0.4 mol . dm-3, the oxidation of Fe (II) was found to proceed through two parallel paths. In one path the reaction rate was proportional
to both [Fe2+]2 and po2, exhibiting an activation energy of 51.6 . kJ mol-1. In another path the reaction rate was proportional to [Fe2+]2, [SO4-], and po2 with an activation energy of 144.6 kJ . mol-1. A reaction mechanism in which the SO4- ions play an important role was proposed for the oxidation of Fe(II). In dilute solutions of sulfuric acid below 0.4 mol
. dm-3, the rate of the oxidation reaction was found to be proportional to both [Fe(II)]2 and Po2, and was also affected by [H+] and [SO2-
4]. The decrease in [H+] resulted in the increase of reaction rate. The discussion was further extended to the effect of Fe (III) on the oxidation
reaction of Fe (II). 相似文献
32.
New integrated optical devices combining an InGaAsP/InP HPT and an inner-stripe LED are proposed and their fabrication processes are described. The device functions of light amplification, optical bistability, and optical switching are demonstrated in the 1-μm wavelength region. 相似文献
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35.
N Sugimoto T Ohmichi A Tanaka A Matsumura M Sasaki 《Canadian Metallurgical Quarterly》1993,(29):167-168
Most stable secondary structures and their stabilization energies of the TAR RNA with +1 to +104 nucleotide-sequence region were calculated at different temperatures by using thermodynamic parameters for RNA structure prediction. The most stable secondary structure has one bulge and one loop within the region of +20 to +40 nucleotide sequence, and its stabilization energy at 37 degrees C was -46.3 kcal mol-1. The interaction of a TAR bulge oligomer (TARBO) with arginine (Arg) which was in the binding site of a Tat protein was also investigated by CD measurements. The addition of Arg did not affect the CD spectrum of TARBO. The result was different from that of the RNA oligomer with both bulge and loop. 相似文献
36.
Tomoko Akai Hiroshi Yamanaka Hajimu Wakabayashi 《Journal of the American Ceramic Society》1996,79(4):859-864
Copper-ruby glasses were prepared by the sputtering method and the effect of reducing treatment was examined. The reducing was carried out either during sputtering or heat treatment. Optical absorption was related to the growth of copper particles. The results are summarized as follows: (i) the volume fraction of copper particles in the glasses which are heat-treated in air increases with the addition of hydrogen in the sputtering gas. (ii) The copper particles do not grow larger than 8 nm by heat treatment in reducing atmosphere, whereas they grow as large as 12 nm in air. (iii) Reducing during heat treatment gives a pronounced effect only when sputtering was not carried out under reducing conditions. The origin of these phenomena was also discussed, considering the mechanism of nucleation and growth of copper particles. 相似文献
37.
A molecular orbital approach to materials design has recently made great progress. This approach is based on the electronic structure calculations by the DV-Xα cluster method. In this paper recent progress in this approachis reviewed. In particular 相似文献
38.
Highly transparent cellulose hydrogels with physical crosslinkage were prepared from nonaqueous organic cellulose solutions and viscose by coagulating and regenerating cellulose in an aqueous solution containing a water‐miscible organic solvent. Nonaqueous organic cellulose solutions used were LiCl/dimethylacetamide, paraformaldehyde/dimethyl sulfoxide, and triethylammonium chloride/dimethyl sulfoxide. Preparation conditions and physical properties of the transparent cellulose hydrogels were studied. The transparency of the cellulose hydrogels depended on the composition of the aqueous solution containing the organic solvent. Furthermore, transparent cellulose hydrogels from viscose showed high tensile strength. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3020–3025, 2003 相似文献
39.
Characterization of C-S-H from Highly Reactive β-Dicalcium Silicate Prepared from Hillebrandite 总被引:1,自引:1,他引:0
Yoshihiko Okada Hideki Ishida Kaori Sasaki J. Francis Young Takeshi Mitsuda 《Journal of the American Ceramic Society》1994,77(5):1313-1318
β-dicalcium silicate synthesized by thermal dissociation of hydrothermally prepared hillebrandite (Ca2 (SiO3 )(OH)2 ) exhibits extremely high hydration activity. Characterization of the hydrates obtained and investigation of the hydration mechanism was carried out with the aid of trimethylsilylation analysis, 29 Si magic angle spinning nuclear magnetic resonance, transmission electron microscopy selected area electron diffraction, and XRD. The silicate anion structure of C-S-H consisted mainly of a dimer and a single-chain polymer. Polymerization advances with increasing curing temperature and curing time. The C-S-H has an oriented fibrous structure and exhibits a 0.73-nm dreierketten in the longitudinal direction. On heating, the C-S-H dissociates to form β-C2 S. The temperature at which βC2 S begins to form decreases with increasing chain length of the C-S-H or as the Ca/Si ratio becomes higher. The high activity of β-C2 S is due to its large specific surface area and the fact that the hydration is chemical-reaction-rate-controlled until its completion. As a result, the hydration progresses in situ and C-S-H with a high Ca/Si ratio is formed. 相似文献
40.