Low‐temperature fabrication of 5‐in. QVGA flexible AMOLED display driven by OTFTs using olefin polymer as the gate insulator

Abstract— A 5‐in. QVGA flexible AMOLED display driven by OTFTs has been fabricated at a low temperature of 130°C. A polyethylene naphthalate film was used as the flexible substrate and an olefin polymer was used as the gate insulator for the OTFT. This layer was formed by spin‐coating and baking at 130°C. Pentacene was used as the organic semiconductor layer. The OTFT performance to drive the flexible display with QVGA pixels in terms of current on/off ratio, carrier mobility, and spatial uniformity on the backplane have been obtained. Phosphorescent and fluorescent OLEDs were used as light‐emitting devices on a flexible display. Those layers were formed by vacuum deposition. After the flexible display was fabricated, a clear and uniform moving image was obtained on the display. The display also showed a stable moving image even when it was bent.     

Improvement in image quality of a 5.8‐in. OTFT‐driven flexible AMOLED display

Abstract— The image quality of an OTFT‐driven flexible AMOLED display has been improved by enhancing the performance of OTFTs and OLEDs. To reduce the operating voltage of OTFTs on a plastic film, Ta²O⁵ with a high dielectric constant was used as a gate insulator. The organic semiconductor layer of the OTFT was successfully patterned by a polymer separator, which is an isolating wall structure using an organic material. The OTFT performance, such as its current on/off ratio, carrier mobility, and spatial uniformity on the backplane, was enhanced. A highly efficient phosphorescent OLED was used as a light‐emission device. A very thin molybdenum oxide film was introduced as a carrier‐injection layer on a pixel electrode to reduce the operating voltage of the OLED. After an OTFT‐driven flexible AMOLED display was fabricated, the luminance and uniformity on the display was improved. The fabricated display also showed clear moving images, even when it was bent at a low operating voltage.     

gBoost: a mathematical programming approach to graph classification and regression

Graph mining methods enumerate frequently appearing subgraph patterns, which can be used as features for subsequent classification or regression. However, frequent patterns are not necessarily informative for the given learning problem. We propose a mathematical programming boosting method (gBoost) that progressively collects informative patterns. Compared to AdaBoost, gBoost can build the prediction rule with fewer iterations. To apply the boosting method to graph data, a branch-and-bound pattern search algorithm is developed based on the DFS code tree. The constructed search space is reused in later iterations to minimize the computation time. Our method can learn more efficiently than the simpler method based on frequent substructure mining, because the output labels are used as an extra information source for pruning the search space. Furthermore, by engineering the mathematical program, a wide range of machine learning problems can be solved without modifying the pattern search algorithm.     

Power oscillation damping by superconducting magnetic energy (SMES) storage unit

With the increase in the size and capacity of electric power systems and the growth of widespread interconnections, the problem of power oscillations due to the reduced system damping has become increasingly serious. Since a Superconducting Magnetic Energy Storage (SMES) unit with a self-commutated converter is capable of controlling both the active (P) and reactive (Q) power simultaneously and quickly, increasing attention has been focused recently on power system stabilization by SMES control. This paper describes the effects of SMES control on the damping of power oscillations. By examining the case of a single generator connected to an infinite bus through both theoretical analyses and experimental tests (performed with a SMES unit with maximum stored energy of 16 kJ and an artificial model system), the difference in the effects between P and Q control of SMES is clarified as follows:

• 1 In the case of P control, as the SMES unit is placed closer to the terminal of the generator, the power oscillations will decay more rapidly.
• 2 In the case of Q control, it is most effective to install the SMES unit near the midpoint of the system.
• 3 By comparing the P control with Q control, the former is more effective than the latter based on the conditions that the SMES unit location and the control gain are the same.

     

Lipase made active in hydrophobic media by coupling with polyethylene glycol

Lipases from various microorganisms were chemically modified with polyethylene glycol derivatives: 2,4-bis[O-methoxypoly(ethylene glycol)]-6-chloro-s-triazine (activated PEG₂, a chain-shaped polymer) and copolymer of polyoxyethylene allyl methyl diether and maleic anhydride (activated PM, a comb-shaped polymer). Because each polymer is amphipathic, the modified lipases become soluble not only in aqueous solution but also in hydrophobic media. They exhibit potent catalytic actions for ester synthesis and ester exchange reactions, the reverse reaction of hydrolysis, in transparent organic solvents and also in oily substrates without organic solvents. With PEG₂-lipases, macrocyclic lactone and gefarnate (geranyl farnesylacetate) were synthesized in high yields from 16-hydroxy-hexadecanoic acid ethyl ester and from farnesylacetic acid and geraniol in organic solvents, respectively. The modified lipase catalyzed the esterification preferentially with the (R)-isomer of secondary alcohols. Because the ester synthesis reactions with modified lipase proceeded in the transparent benzene system, the kinetic parameters (Michaelis constant and maximum velocity) were obtained by reciprocal plotting according to the Michaelis equation. With comb-shaped polymer as modifier, PM-lipase catalyzed effectively the reverse reaction of hydrolysis in organic solvents. The properties of each modified lipase are discussed in relation to those of the nonmodified lipase. Presented at the 84th Annual Meeting of the American Oil Chemists' Society held on April 25–29, 1993, in Anaheim, CA.     

Remarks on the assignments of temperature programmed desorption peaks for the surface species formed on Cu/ZnO and ZnO in the methanol synthesis from CO

Temperature programmed desorption (TPD), IR spectroscopy and chemical trapping of the surface species with H₂O revealed that the TPD peak of CO frequently assigned to zinc formate species, which were formed in the course of the methanol synthesis from CO-H₂, arose from zinc methoxide species.     

Pressure effect on CHF enhancement in pool boiling of nanofluids

This paper investigates critical heat flux (CHF) in saturated pool boiling for water and TiO₂ nanofluid on a 7-mm-diameter vertical copper surface at pressures of 0.1–0.8 MPa. The nanofluid was prepared by dispersing 0.002 wt% TiO₂ nanoparticles in deionized water. The CHF of the nanofluid was enhanced about two times over that of water boiling at atmospheric pressure. With the increasing pressure, however, the CHF enhancement with the nanofluid decreases, and almost disappears at 0.8 MPa.     

A4‐sized flexible ferroelectric liquid‐crystal displays with micro color filters

Abstract— We demonstrated an A4‐paper‐sized flexible ferroelectric liquid‐crystal (FLC) color displays fabricated by using a new plastic‐substrate‐based process which was developed for large‐sized devices. Finely patterned color filters and ITO electrodes were formed on a plastic substrate by a transfer method to avoid surface roughness and thermal distortion of the substrate, which induce disordering of the FLC molecular alignment. The thickness of an FLC/monomer solution sandwiched by two plastic‐film substrates was well controlled over a large area by using flexographic printing and lamination techniques. Molecular‐aligned polymer walls and fibers were formed in the FLC by a two‐step photopolymerization‐induced phase‐separation method using UV‐light irradiation. A fabricated A4‐sized flexible‐sheet display for color‐segment driving was able to exhibit color images even when it was bent.     

Therapeutic Effects of an Anti-sialyl Lewis X Antibody in a Murine Model of Allergic Asthma

Asthma is an allergic disease that causes severe infiltration of leukocytes into the lungs. Leukocyte infiltration is mediated by the binding of sialyl Lewis X (sLe^x) glycans present on the leukocytes to E-and P-selectins present on the endothelial cells at the sites of inflammation. Here, we found that mouse eosinophils express sLe^x glycans, and their infiltration into the lungs and proliferation in the bone marrow were significantly suppressed by an anti-sLe^x monoclonal antibody (mAb) F2 in a murine model of ovalbumin-induced asthma. The percentage of eosinophils in the bronchoalveolar lavage fluid and bone marrow and serum IgE levels decreased significantly in the F2-administered mice. Levels of T helper type 2 (Th2) cytokines and chemokines, involved in IgE class switching and eosinophil proliferation and recruitment, were also decreased in the F2-administered mice. An ex vivo cell rolling assay revealed that sLe^x glycans mediate the rolling of mouse eosinophils on P-selectin-expressing cells. These results indicate that the mAb F2 exerts therapeutic effects in a murine model of allergen-induced asthma, suggesting that sLe^x carbohydrate antigen could serve as a novel therapeutic target for allergic asthma.     

Production of Trehalose from Starch by Thermostable Enzymes from Sulfolobus acidocaldarius

The optimum conditions for the production of trehalose from starch were investigated using two thermostable enzymes, maltooligosyl trehalose synthase (MTSase) and maltooligosyl trehalose trehalohydrolase (MTHase), from Sulfolobus acidocaldarius ATCC 33909. The optimum pH was 5.5 and the optimum temperature was 55—57°C using isoamylase from Pseudomonas amyloderamosa as a debranching enzyme. The addition of CGTase to the reaction mixture during the saccharification process caused an increase in trehalose and a decrease in maltose and maltotriose. Isoamylase was better than pullulanase as a debranching enzyme. The yield of trehalose was independent of the type of starch used. Under optimum conditions, the yield of trehalose from corn starch at 30% concentration was more than 82%.