Analysis of Cs-adsorption behavior using a column filled with microcapsule beads of potassium copper hexacyanoferrate

Ash-washing technology is a crucially important technology for removing radioactive Cs from contaminated ash. For that technology, Cs⁺ removal from the ash-washing solution by the adsorbent is necessary. This study was conducted to establish rapid preparation of appropriate adsorption columns for Cs⁺ uptake. A one-site model was not used for analysis because the model cannot accommodate sites with different adsorption speed. Results demonstrated that the adsorption behavior of the column filled with the granules of potassium copper hexacyanoferrate was well reproduced by a two-site adsorption model with parameters chosen through analysis of batch adsorption test results.     

Analysis of capacitance ratio of a rectangular X-cut length-extensional mode quartz crystal resonator by stresses

The electrical properties of an X-cut, length-extensional mode quartz crystal resonator of a cut angle theta around the X-axis were calculated by a variational method using stresses as trial functions. Analytical expressions of stresses were estimated by a linear regression on a cut angle best-fit to the results of finite-element method. The calculated dependence of the capacitance ratio on the cut angle was consistent with the measured results.     

Thermal ratcheting of solder-bonded layered plates: cyclic recovery and growth of deflection

This paper describes computational analysis of the thermal ratcheting of solder-bonded layered plates subjected to cyclic thermal loading following solder-bonding. Finite element computations of Si/solder/Cu layered plates are performed by taking into account mechanical ratcheting of the copper as well as temperature-dependent creep of the solder. A sophisticated non-linear kinematic hardening model is used for appropriately representing mechanical ratcheting of the copper; a temperature-dependent power-law creep model is assumed for the solder. It is shown that the layered plates can exhibit either the cyclic recovery or the cyclic growth of deflection depending on the extent of plastic yielding in the copper layer, and that the cyclic recovery always occurs if the copper layer is elastic. It is also demonstrated that the cyclic recovery of deflection can be much greater than the static recovery of deflection at a constant temperature.     

The development of simplified ultrasonic CT system and its application to the evaluation of weld metal

In this paper, as a new measurement method to estimate the change of material condition, the simplified ultrasonic CT system, which uses the information of three directions, that is, 90°, + 45° and −45° about inspection plane is proposed. Use of simplified CT system has two merits: Firstly, the measurement time is very short compared with general CT. Secondly, it can detect sensitively small defect in vertical or slant direction about inspection plane because the obtained image is CT image calculated from three directions. From these merits, this method can be considered as an effective method to evaluate material conditions. The basic performance of the proposed method was confirmed through several specimens with several simple defects. In order to confirm the applicability of actual NDT, several kinds of welded specimens are investigated. The result showed that the CT image obtained had good agreement with actual defect of specimens.     

Allelopathy of oats. II. Allelochemical effect ofl-Tryptophan and its concentration in oat root exudates

l-Tryptophan caused growth inhibition of roots and hypocotyls (or coleoptiles) of cockscomb (Amaranthus caudatus L.), lettuce (Lactuca sativa L.), cress (Lepidium sativum L.), timothy (Phleum pratense L.), rice (Oryza sativa L.), wheat (Triticum aestivum L.), and oat (Avena sativa L.), increasing the dose ofl-tryptophan increased the inhibition. The concentrations for 50% inhibition of the root growth were 0.14, 0.15, 0.21, 0.79, 0.95, 1.7, and 2.4 mM for cockscomb, cress, lettuce, timothy, rice, wheat, and oat, respectively; the concentrations for 40% inhibition of the hypocotyl (or coleoptile) growth were 0.28, 0.33, 0.43, 2.7, 4.5, 7.2, and 15 mM for cockscomb, cress, lettuce, timothy, rice, wheat and oat, respectively. The levels ofl-tryptophan in oat seedlings and in its root exudates were 29.3 mg/kg fresh wt and 0.25 mM under light conditions, and 21.1 mg/kg fresh wt and 0.18 mM under dark conditions, respectively. The presence ofl-tryptophan in the root exudates coupled with its effect on growth suggested thatl-tryptophan may play an important role in the growth inhibition of other plants in nature.     

Preparation of fine polymer particles containing metallocene derivatives

This article deals with preparations of fine particles of metallocene copolymers by emulsifierfree emulsion polymerization of vinylferrocene (VFc), ferrocenylmethyl methacrylate (FMMA), 1-ferrocenylethyl methacrylate (1-FEMA), 2-ferrocenylethyl methacrylate (2-FEMA), and 1-ruthenocenylethyl methacrylate (1-REMA) with acrylonitrile (AN), styrene (St), and methyl methacrylate (MMA) in water/ethanol medium. As a result, spherical copolymer particles containing metallocene derivatives have been successfully synthesized in the particle size of ca. 120 to 600 nm. The contents of ferrocenyl or ruthenocenyl groups in copolymer particles increased with increasing concentration of charged metallocene derivatives, while the amounts of metallocene derivatives incorporated into particles are much lower than the charged ratio. © 1994 John Wiley & Sons, Inc.     

A novel method for three-dimensional observation of the vascular networks in the whole mouse brain

A novel method for acquiring serial images suitable for three-dimensional reconstruction of vascular networks in the whole brain of mouse was developed. The brain infused with a White India ink-gelatin solution was fixed and embedded in paraffin containing Sudan Black B through xylene also containing Sudan Black B. Each sliced surface of the paraffin block was coated with liquid paraffin and its image was serially acquired. Coating with liquid paraffin extremely improved the quality of the image. The series of serial images was free of distortion and a three-dimensional image was reconstructed without the problem of the alignment and registration of adjacent images. The volume-rendered image indicated three-dimensional distribution of blood vessels in a whole brain. No ghost or shadow was observed on a volume-rendered image of the White India ink-gelatin infused brain. The z-axial resolution examined on the orthogonal sections reconstituted from serial images obtained at an interval of 5 mum showed no cross talk, indicating that the z-axial resolution was no larger than 5 mum. A proper understanding of the vascular system in a whole brain is indispensable to reveal the development of the vascular system in the brain of normal and genetically manipulated mouse and vascular alterations in pathological situation, such as stroke and neurodegenerative disease. Although simple and inexpensive, this method will provide fundamental information on the vascular system in a whole brain.     

INTERMETALLIC COMPOUNDS AND THEIR FORMATION REACTIONS IN SYSTEM Fe-Cr-Mo AT HIGH-TEMPERATURES

The stable ranges concerning the composition and temperature have been experimentally de-termined for the intermetallic compounds in system Fe-Cr-Mo at high-temperatures. Theisothermal section of the Fe-Cr-Mo ternary phase diagram at 1250℃ and the formation re-actions for the intermetallic compounds, which are different in part from those shown in theliterature, have been proposed.