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91.
The decomposition of CHF3 in a mixture with O2 and Ar was investigated in a coaxial dielectric barrier discharge at atmospheric pressure. CHF3 decomposition increased linearly in regard to specific energy input (SEI), whereas energy efficiency decreased. The main product was CO2, and its selectivity increased with high SEI and the presence of O2 in the feed, but an increase of O2 in the feed led to a decrease in decomposition rate. An increase in total flow rate led to an increase of the absolute amount of CHF3 decomposition and energy efficiency; however, the decomposition of CHF3 decreased. A complete CHF3 decomposition occurred under an SEI of 1.54 kJ/L with the selectivity of CO2 and CO as 89.87% and 7.00%, respectively. Optical emission spectroscopic analysis could explain the available reaction pathways for CHF3 decomposition in the CHF3/O2/Ar atmospheric plasma and show the possibility of F2 and HF formation. 相似文献
92.
93.
Seung Koo Lee Myung Shin Han Ching‐Hsuan Tung 《Small (Weinheim an der Bergstrasse, Germany)》2012,8(21):3315-3320
A long‐lasting particle‐based fluorescent label is designed for extended cell imaging studies. This onion‐like nanoprobe is constructed through layer‐by‐layer fabrication technology. The nanoprobes are assembled with multiple layers of optically quenched polyelectrolytes, the fluorescence signal of which can be released later by intracellular proteolysis. Upon incubation with cells, the assembled nanoprobes are taken up efficiently. The tight packing and layered assembly of the quenched polyelectrolytes slow subsequent intracellular degradation, and then result in a prolonged intracellular fluorescence signal for up to 3 weeks with no noticeable toxicity. 相似文献
94.
For elevated temperature design evaluations by the ASME-NH rules, the most important material data is the isochronous stress-strain
curves, which can provide design creep information. The main purpose of this paper is to investigate appropriate formulations
to be able to generate the isochronous stress-strain curves and implement it to the computer program which is coded the ASME-NH
design evaluation procedures. To do this, formulations by the strain-time relationship are investigated in detail and the
sensitivity studies for rapid initial transient creep contributions, slower and longer transient creep contribution, and secondary
creep contributions are carried out for type 316 austenitic stainless steel. From the results of this study, it is found that
the strain-time relationship formulations can well describe the isochronous stress-strain curves with the transient creep
contributions. 相似文献
95.
Marvin Ricaurte Jean-Philippe TorréJoseph Diaz Christophe Dicharry 《Chemical Engineering Research and Design》2014
This paper investigates an original method to efficiently trigger gas hydrate crystallization. This method consists of an in situ injection of a small amount of THF into an aqueous phase in contact with a gas-hydrate-former phase at pressure and temperature conditions inside the hydrate metastable zone. In the presence of a CO2–CH4 gas mixture, our results show that the THF injection induces immediate crystallization of a first hydrate containing THF. This triggers the formation of the CO2–CH4 binary hydrate as proven by the pressure and temperature reached at equilibrium. This experimental method, which “cancels out” the stochasticity of the hydrate crystallization, was used to evaluate the effect of the anionic surfactant SDS at different concentrations, on the formation kinetics of the CO2–CH4 hydrate. The results are discussed and compared with those published in a recent article (Ricaurte et al., 2013), where THF was not injected but present in the aqueous phase from the beginning and at much higher concentrations. 相似文献
96.
A continuous screening procedure interchangeably using the performance and surrogate variables is proposed. At the start of the inspection, the performance variable is measured for all items. As soon as i consecutive items are found to be free of defects, the surrogate variable is measured instead of the performance variable. If an item is rejected, the inspection based on the performance variable is resumed. All non-conforming items found in the inspection are either reworked or replaced with conforming items. The average outgoing quality (AOQ) expression is derived, and methods of finding the inspection procedure with a specified average outgoing quality limit (AOQL) are presented. 相似文献
97.
98.
James E. Warner Manuel I. Diaz Wilkins Aquino Marc Bonnet 《Computational Mechanics》2014,54(3):645-659
This work focuses on the identification of heterogeneous linear elastic moduli in the context of frequency-domain, coupled acoustic-structure interaction (ASI), using either solid displacement or fluid pressure measurement data. The approach postulates the inverse problem as an optimization problem where the solution is obtained by minimizing a modified error in constitutive equation (MECE) functional. The latter measures the discrepancy in the constitutive equations that connect kinematically admissible strains and dynamically admissible stresses, while incorporating the measurement data as additional quadratic error terms. We demonstrate two strategies for selecting the MECE weighting coefficient to produce regularized solutions to the ill-posed identification problem: 1) the discrepancy principle of Morozov, and 2) an error-balance approach that selects the weight parameter as the minimizer of another functional involving the ECE and the data misfit. Numerical results demonstrate that the proposed methodology can successfully recover elastic parameters in 2D and 3D ASI systems from response measurements taken in either the solid or fluid subdomains. Furthermore, both regularization strategies are shown to produce accurate reconstructions when the measurement data is polluted with noise. The discrepancy principle is shown to produce nearly optimal solutions, while the error-balance approach, although not optimal, remains effective and does not need a priori information on the noise level. 相似文献
99.
100.
You Jeong Eum Jungho Ryu Chang Young Koo Jung Min Park Jai-Yeoul Lee Hee Young Lee 《Ceramics International》2021,47(5):6371-6375
Magnetoelectric (ME) property modulation in heterostructured (Ni0.5Zn0.5)Fe2O4/Pt/Pb(Zr0.3Ti0.7)O3 (NZFO/Pt/PZT) thin films on platinized Si substrate by thermal annealing condition variation was studied. In an attempt to prevent interfacial reaction between NZFO and PZT layers during high temperature annealing, thin Pt layer was deposited which can serve as inter-diffusion barrier as well as electrode. The ferroelectric, magnetic, and ME properties of the heterostructured film were noticeably modulated due to microstructural evolution and clamping relaxation developed during thermal annealing process. Room temperature ME voltage coefficient of the heterostructured thin films was enhanced with increasing annealing temperature and reached to 29 mV/cm·Oe when annealed at 650 °C. 相似文献