Dynamic characterization and modification of dynamic properties of a micro scanner

Micro electro mechanical systems (MEMS) are used in many application areas in different disciplines and took their place among the most promising technologies. The performance of such systems is primarily related to their dynamical characteristics. This study presents the dynamic characterization techniques that are used to identify the modal parameters of a MEMS device and the methods that can be implemented to change its dynamic response. An electrostatic scanner is chosen as the case study to demonstrate the developed methodologies. Initially, the micro scanner is characterized using experimental modal analysis techniques to obtain frequency response function, modal damping, resonance frequencies, and mode shapes. Then, velocity and position feedback control loops are implemented to the scanner system to alter the damping and stiffness characteristics. A closed-loop Simulink model of the scanner is developed to verify the experimental measurements. Several curve fitting methods are used in order to have an accurate representation of the scanner system. Using the model, the influence of both position and velocity feedback on the effective damping, resonance frequency and the transient behavior of the scanner is investigated. The stability limits of the scanner under velocity feedback are also studied via numerical simulations. Based on the experimental and simulation results, the methodology developed in this study proves itself to be very efficient to alter the dynamical characteristics of the MEMS structures and it can be easily adapted to other MEMS applications.     

Effect of ZrO2 on phase transformation of Al2O3

This study investigates the effect of ZrO₂ on phase transformation of alumina. Alumina and alumina–zirconia composite powders were produced by the precipitation method from aluminum sulfate and zirconium sulfate precursors. Precipitates obtained at 15 °C were dried at 80 °C for 72 h, and then calcinated at four different temperatures; 1000 °C, 1100 °C, 1200 °C and 1300 °C for 1 h. Powders calcinated at 1300 °C were pressed uniaxially and sintered at 1600 °C for 1 h. XRD and DSC analyses showed that the presence of zirconia retarded the transformation to α-alumina. SEM studies on the powders calcinated at 1300 °C revealed that both alumina and alumina–zirconia particles were 100–300 nm in size and of near spherical shape. Zirconia additions inhibited abnormal grain growth of alumina and provided homogeneous, equaxied grain structure.     

Investigation of electrochromic properties of poly(3,5-bis(4-methoxyphenyl)dithieno[3,2-b;2′,3′-d]thiophene)

Electropolymerization of 3,5-bis(4-methoxyphenyl)dithieno[3,2-b;2′,3′-d]thiophene BMPhDTT, having strong electron-donating methoxy groups, was performed, utilizing potentiodynamic method. The homopolymer was characterized by cyclic voltammetry (CV), Fourier transform infrared (FTIR) and UV–vis spectroscopy. Spectroelectrochemical and electrochromic properties of the homopolymer film were investigated and a PBMPhDTT/PEDOT device was constructed to understand its characteristics in detail. It was revealed that the potential range of 0.0–2.0 V is suitable for operating the device between yellow and blue colors. It indicated a good open circuit memory and stability.     

Characterization of cryogenic heat treated Vanadis 4 PM cold work tool steel

The amount of retained austenite in the quenched cold work tool steel sample is 17.7%, in the condition of sub-zero heat treated and double tempered samples following by quenching is 1.9% determined by XRD analysis. The types of carbides (MC, M₇C₃, M₂₃C₆) present in the structure was determined by XRD and SEM-EDS analysis. The hardness of test samples were 865 HV(0.1) for quenched sample and 785 HV(0.1) forth sample subjected to sub-zero treatment and double tempered after the quenching.     

Physiological response to firefighting activities of various work cycles using extended duration and prototype SCBA

Firefighters’ self-contained breathing apparatus (SCBA) protects the respiratory system during firefighting but increases the physiological burden. Extended duration SCBA (>30 min) have increased air supply, potentially increasing the duration of firefighting work cycles. To examine the effects of SCBA configuration and work cycle (length and rest), 30 firefighters completed seven trials using different SCBA and one or two bouts of simulated firefighting following work cycles common in the United States. Heart rate, core temperature, oxygen consumption, work output and self-reported perceptions were recorded during all activities. Varying SCBA resulted in few differences in these parameters. However, during a second bout, work output significantly declined while heart rates and core temperatures were elevated relative to a single bout. Thirty seven per cent of the subjects were unable to complete the second bout in at least one of the two-bout conditions. These firefighters had lower fitness and higher body mass than those who completed all assigned tasks.

Practitioner Summary: The effects of extended duration SCBA and work/rest cycles on physiological parameters and work output have not been examined. Cylinder size had minimal effects, but extended work cycles with no rest resulted in increased physiological strain and decreased work output. This effect was more pronounced in firefighters with lower fitness.     

Detection and classification of vehicles from omnidirectional videos using multiple silhouettes

To detect and classify vehicles in omnidirectional videos, we propose an approach based on the shape (silhouette) of the moving object obtained by background subtraction. Different from other shape-based classification techniques, we exploit the information available in multiple frames of the video. We investigated two different approaches for this purpose. One is combining silhouettes extracted from a sequence of frames to create an average silhouette, the other is making individual decisions for all frames and use consensus of these decisions. Using multiple frames eliminates most of the wrong decisions which are caused by a poorly extracted silhouette from a single video frame. The vehicle types we classify are motorcycle, car (sedan) and van (minibus). The features extracted from the silhouettes are convexity, elongation, rectangularity and Hu moments. We applied two separate methods of classification. First one is a flowchart-based method that we developed and the second is K-nearest neighbour classification. 60% of the samples in the dataset are used for training. To ensure randomization in the experiments, threefold cross-validation is applied. The results indicate that using multiple silhouettes increases the classification performance.     

Multiple bulk-reaction asymptotics and the electrochemical pickling of steel

Asymptotic methods are used to explore the role of multiple homogeneous chemical reactions, water protolysis, and the disassociation of sulfuric acid in a recent numerical model for the industrial electrochemical pickling of steel. The analysis demonstrates the surprising result that, even though the asymptotic structure of the solution differs from that found when either one or both of the chemical reactions are neglected, the overall current density remains unchanged. Most importantly from an industrial perspective, the asymptotic model provides results of practical value for process design at a fraction of the computational cost of the earlier numerical model.     

The effects of Co/Ce loading ratio and reaction conditions on CDRM performance of CoCe/ZrO2 catalysts

This work mainly aims to establish a link between Co/Ce loading ratio in CoCe/ZrO₂ catalysts and their Carbon Dioxide Reforming of Methane (CDRM) performance. In this context, catalysts with different Co and Ce loadings were prepared and characterized via BET, XRD, HRTEM-EDX, XPS and Raman, and parametrically tested under different CDRM conditions. Dispersion of Co particles was nonhomogeneous on all samples. For the sample with the highest Co/Ce ratio (10%Co2%Ce/ZrO₂), higher amount of lattice oxygen vacancies and lowest degree of ceria reduction were determined. Raman analysis showed that graphitic carbon coexisted with amorphous carbon on the surface of all spent samples. The extent of side reactions prevailed in determining selectivity. It was expressed that both CoCe synergistic interaction and synchronous contribution of Ce and ZrO₂ were enhanced for the samples having lower Co/Ce ratio. It was confirmed that Ce is only responsible for oxygen transfer but not its formation.     

Shaping single-walled metal oxide nanotubes from precursors of controlled curvature

We demonstrate new molecular-level concepts for constructing nanoscopic metal oxide objects. First, the diameters of metal oxide nanotubes are shaped with angstrom-level precision by controlling the shape of nanometer-scale precursors. Second, we measure (at the molecular level) the subtle relationships between precursor shape and structure and final nanotube curvature. Anionic ligands are used to exert fine control over precursor shapes, allowing assembly into nanotubes whose diameters relate directly to the curvatures of the 'shaped' precursors.