Impermeable Graphene Skin Increases the Heating Efficiency and Stability of an MXene Heating Element

A Joule heater made of emerging 2D nanosheets, i.e., MXene, has the advantage of low-voltage operation with stable heat generation owing to its highly conductive and uniformly layered structure. However, the self-heated MXene sheets easily get oxidized in warm and moist environments, which limits their intrinsic heating efficiencies. Herein, an ultrathin graphene skin is introduced as a surface-regulative coating on MXene to enhance its oxidative stability and Joule heating efficiency. The skin layer is deposited on MXene using a scalable solution-phased layer-by-layer assembly process without deteriorating the excellent electrical conductivity of the MXene. The graphene skin comprises narrow and hydrophobic channels, which results in ≈70 times higher water impermeability of the hybrid film of graphene and MXene (GMX) than that of the pristine MXene. A complementary electrochemical analysis confirms that the graphene skin facilitates longer-lasting protection than conventional polymer coatings owing to its tortuous pathways. In addition, the sp² planar carbon surface with a low heat loss coefficient improves the heating efficiency of the GMX, indicating that this strategy is promising for developing adaptive heating materials with a tractable voltage range and high Joule heating efficiency.     

Chemically Recyclable Conjugated Polymer and One-Shot Preparation of Thermally Stable and Efficient Bulk-Heterojunction from Recycled Monomer

Recyclable conjugated polymers are important for realizing eco-friendly electronics with advantages of solution processability and flexibility. A recyclable conjugated polymer, PY-TIP is developed, of which a key monomer is successfully extracted via a mild depolymerization process and is reused for the synthesis of novel conjugated polymers. One-shot preparation of polymer acceptor and its bulk-heterojunction (BHJ) is demonstrated from the recycled monomer, Y5-TA, for the first time and the resulting BHJ film shows optimal nanoscale morphology for efficient charge generation and transport. As a result, the solar cells prepared using the BHJ film show a higher efficiency of 13.08% and much improved thermal and mechanical stability compared with those based on the small molecular acceptor. These results are important in that the various polymers can be prepared from the recycled monomer in a solid state without organic solvents and purification step and this strategy is effective for improving the thermal and mechanical stability of the BHJ film as well as achieving high photovoltaic performance. PY-TIP is exemplary in that it can reproduce its monomer which can be used to synthesize conjugated polymers with novel chemical structures and physical properties. This work provides a design guideline for developing recyclable conjugated polymers with dynamic covalent bonds.     

ARbility: re-inviting older wheelchair users to in-store shopping via wearable augmented reality

Virtual Reality - Engaging in outdoor daily activities such as shopping is an essential, yet challenging activity for older wheelchair users (OWU). However, little is investigated on how to augment...     

Online Avatar Motion Adaptation to Morphologically-similar Spaces

In avatar-mediated telepresence systems, a similar environment is assumed for involved spaces, so that the avatar in a remote space can imitate the user's motion with proper semantic intention performed in a local space. For example, touching on the desk by the user should be reproduced by the avatar in the remote space to correctly convey the intended meaning. It is unlikely, however, that the two involved physical spaces are exactly the same in terms of the size of the room or the locations of the placed objects. Therefore, a naive mapping of the user's joint motion to the avatar will not create the semantically correct motion of the avatar in relation to the remote environment. Existing studies have addressed the problem of retargeting human motions to an avatar for telepresence applications. Few studies, however, have focused on retargeting continuous full-body motions such as locomotion and object interaction motions in a unified manner. In this paper, we propose a novel motion adaptation method that allows to generate the full-body motions of a human-like avatar on-the-fly in the remote space. The proposed method handles locomotion and object interaction motions as well as smooth transitions between them according to given user actions under the condition of a bijective environment mapping between morphologically-similar spaces. Our experiments show the effectiveness of the proposed method in generating plausible and semantically correct full-body motions of an avatar in room-scale space.     

Recurrent Motion Refiner for Locomotion Stitching

Stitching different character motions is one of the most commonly used techniques as it allows the user to make new animations that fit one's purpose from pieces of motion. However, current motion stitching methods often produce unnatural motion with foot sliding artefacts, depending on the performance of the interpolation. In this paper, we propose a novel motion stitching technique based on a recurrent motion refiner (RMR) that connects discontinuous locomotions into a single natural locomotion. Our model receives different locomotions as input, in which the root of the last pose of the previous motion and that of the first pose of the next motion are aligned. During runtime, the model slides through the sequence, editing frames window by window to output a smoothly connected animation. Our model consists of a two-layer recurrent network that comes between a simple encoder and decoder. To train this network, we created a sufficient number of paired data with a newly designed data generation. This process employs a K-nearest neighbour search that explores a predefined motion database to create the corresponding input to the ground truth. Once trained, the suggested model can connect various lengths of locomotion sequences into a single natural locomotion.     

Free‐Standing,Multilayered Graphene/Polyaniline‐Glue/Graphene Nanostructures for Flexible,Solid‐State Electrochemical Capacitor Application

Graphene/polyaniline multilayered nanostructures (GPMNs) are prepared using a straightforward process through which graphite is physically exfoliated with quaternary polyaniline (PANI)‐glue. This is only accomplished by sonication of the graphite flakes in an organic solvent to form continuous films with PANI. During the sonication, the conductive PANI‐glue is spontaneously intercalated between the graphene sheet layers without deterioration of the sp² hybridized bonding structure. The resultant free‐standing, flexible films are composed of a network of overlapping graphene sheets and are shown to have a long‐range structure. The effects of different PANI content ratios and different interfacial energies (depending on the dispersion solvent) on the morphology and properties of the resulting GPMN are examined. It is found that GPMNs dispersed in water have a maximum specific capacitance of 390 F g⁻¹ in a three‐electrode configuration. Importantly, the unique structural design of GPMNs enables their use as electrode materials for the fabrication of flexible, solid‐state electrochemical capacitors, which show an enhanced performance compared to graphene‐only devices. They exhibit a high specific capacitance of 200 F g⁻¹, a cycling stability with capacitance retention of 82% after 5000 charge/discharge cycles, and, moreover, superior flexibility.     

Direct Applicability of La0.6Sr0.4CoO3 – δ Thin Film Cathode to Yttria Stabilised Zirconia Electrolytes at T ≤ 650 °C

For investigating the direct applicability of highly active cobalt containing cathodes on YSZ electrolytes at a lower processing and operating temperature range (T ≤ 650 °C), we fabricated a thin film lanthanum strontium cobalt oxide (LSC) cathode on an yttria stabilised zirconia (YSZ)‐based solid oxide fuel cell (SOFC) via pulsed laser deposition (PLD). Its electrochemical performance (5.9 mW cm^–2 at 0.7 V, 650 °C) was significantly inferior to that (595 mW cm^–2 at 0.7 V, 650 °C) of an SOFC with a thin (t ∼ 200 nm) gadolinium doped ceria (GDC) buffer layer in between the LSC thin film cathode and the YSZ electrolyte. It implies that even though the cathode processing and cell operating temperatures were strictly controlled not to exceed 650 °C, the direct application of LSC on YSZ should be avoided. The origin of the cell performance deterioration is thoroughly studied by glancing angle X‐ray diffraction (GAXRD) and transmission electron microscopy (TEM), and the decomposition of the cathode and diffusion of La and Sr into YSZ were observed when LSC directly contacted YSZ.     

Efficient flow‐control algorithm cooperating with energy allocation scheme for solar‐powered WSNs

Recently, solar energy emerged as a feasible supplement to battery power for wireless sensor networks (WSNs) which are expected to operate for long periods. Since solar energy can be harvested periodically and permanently, solar‐powered WSNs can use the energy more efficiently for various network‐wide performances than traditional battery‐based WSNs of which aim is mostly to minimize the energy consumption for extending the network lifetime. However, using solar power in WSNs requires a different energy management from battery‐based WSNs since solar power is a highly varying energy supply. Therefore, firstly we describe a time‐slot‐based energy allocation scheme to use the solar energy optimally, based on expectation model for harvested solar energy. Then, we propose a flow‐control algorithm to maximize the amount of data collected by the network, which cooperates with our energy allocation scheme. Our algorithms run on each node in a distributed manner using only local information of its neighbors, which is a suitable approach for scalable WSNs. We implement indoor and outdoor testbeds of solar‐powered WSN and demonstrate the efficiency of our approaches on them. Copyright © 2010 John Wiley & Sons, Ltd.     

Photocrosslinkable Zwitterionic Ligands for Perovskite Nanocrystals: Self-Assembly and High-Resolution Direct Patterning

Perovskite nanocrystals (PNCs) are attractive photoactive materials in various optoelectronic devices including light-emitting diodes, solar cells, and photodetectors. However, the weakly bound surface ligands on PNCs reduce colloidal stability and cause film formation and patterning difficulties, severely restricting their practical applications. Herein, a rationally designed photocrosslinkable zwitterionic (PZ) ligand is introduced to obtain directly patternable CsPbBr₃ PNCs with enhanced colloidal stability, optical properties, and self-assembly propensity. The PZ ligands strongly interact with the pre-synthesized PNCs in solution, substantially replacing the original capping ligands and effectively passivating surface defects. This surface engineering induces strong electrostatic interactions between the PNCs, enabling the fabrication of densely packed CsPbBr₃ PNC films. Furthermore, the methacrylate group of the PZ ligands serves as a bridge for active radical propagation in the ligand shells around the PNCs upon UV exposure. Accordingly, high-resolution direct photopatterning can be achieved through ligand crosslinking, and the resulting PNC patterns (minimum line spacing of 4 µm) maintain optical stability for over 2 weeks. Therefore, this study demonstrates that a tailored ligand design strategy enables the simultaneous achievement of high colloidal stability, optical properties, photopatternability, and self-assembly propensity and has considerable potential to be extended to other PNC materials.