Experimental and computational infrared imaging of bluff body stabilized laminar diffusion flames

The concept of comparing measured and computed images is extended to the mid-infrared spectrum to provide a non-intrusive technique for studying flames. Narrowband radiation intensity measurements of steady and unsteady bluff body stabilized laminar ethylene diffusion flames are acquired using an infrared camera. Computational infrared images are rendered by solving the radiative transfer equation for parallel lines-of-sight through the flame and using a narrowband radiation model with computed scalar values. Qualitative and quantitative comparisons of the measured and computed infrared images provide insights into the flame stabilization region and beyond. The unique shapes and sizes of the flames observed in the measured and computed infrared images are similar with a few exceptions which are shown to be educational. The important differences occur in the flame stabilization region suggesting improvements in thermal control of the experiment and soot formation and heat loss models.     

The awareness and practice of value management by South African consulting engineers: Preliminary research survey findings

The awareness of value management (VM) and the nature and extent of its practice by professional civil, electrical and mechanical engineers in the South African construction industry are investigated using a web-based, online questionnaire survey as the first part of a more extensive investigation. A primary objective of the early study is to test the UK-based assertion of Kelly et al. [Kelly, J., Male, S., Graham, D., 2004. Value Management of Construction Projects. Blackwell, Oxford] that VM is an established service with commonly understood tools, techniques and styles. The survey findings suggest that, while awareness of VM is reasonably prevalent among South African engineers, its practice is considerably less extensive. Where VM is undertaken, almost no attempt is made to benchmark VM activities against international standards nor does its use appear to conform to any standard methodology. Engineers prefer other ways of delivering value to projects, and do not generally employ VM to facilitate the client briefing process. The findings are important given the increasing globalization of construction services, especially given the international ties between designers, project managers and other professionals. Professional engineering associations in South Africa should adopt a proactive role in promoting the use of VM by engineers, possibly through continuing professional development programmes.     

Impulsivity as a mediating mechanism between early-life adversity and addiction: Theoretical comment on Lovic et al. (2011).

Early-life adversity, impulsivity, and dopaminergic function have all been implicated in adult drug addiction. The article by Lovic, Keen, Fletcher, and Fleming in this issue further elucidates this relationship by demonstrating that early-life adversity can increase impulsivity and decrease behavioral flexibility in adulthood. Recent literature suggests that these results are likely due to structural and functional changes in regions such as the orbitofrontal cortex (OFC) and nucleus accumbens (NAc), as well as altered dopamine activity. Impulsivity and behavioral inflexibility can increase susceptibility to addiction, and in turn, chronic substance abuse can impair the neurocircuitry underlying behavioral inhibition. Thus, early-life adversity may act as an entry point into a feed-forward spiral of impulsivity and addiction via the dysfunction of regions such as the OFC, NAc, and mesolimbic dopamine. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

A hybrid approach of goal programming for weapon systems selection

Because weapon systems are perceived as crucial in determining the outcome of a war, selecting weapon systems is a critical task for nations. Just as with other forms of decision analysis involving multiple criteria, selecting a weapon system poses complex, unstructured problems with a huge number of points that must be considered. Some defense analysts have committed themselves to developing efficient methodologies to solve weapon systems selection problems for the Republic of Korea’s (ROK) Armed Forces. In the present study, we propose a hybrid approach for weapon systems selection that combines analytic hierarchy process (AHP) and principal component analysis (PCA) to determine the weights to assign to the factors that go into these selection decisions. These weights are inputted into a goal programming (GP) model to determine the best alternative among the weapon systems. The proposed hybrid approach that combines AHP, PCA and GP process components offsets the shortcomings posed by obscurity and arbitrariness in AHP and therefore can provide decision makers with more reasonable and realistic decision criteria than AHP alone. A case study on weapon system selection for the air force demonstrates the usefulness and effectiveness of the proposed hybrid AHP–PCA–GP approach.     

An investigation of the mechanisms for strength gain or loss of geopolymer mortar after exposure to elevated temperature

When fly ash-based geopolymer mortars were exposed to a temperature of 800 °C, it was found that the strength after the exposure sometimes decreased, but at other times increased. This paper shows that ductility of the mortars has a major correlation to this strength gain/loss behaviour. Specimens prepared with two different fly ashes, with strengths ranging from 5 to 60 MPa, were investigated. Results indicate that the strength losses decrease with increasing ductility, with even strength gains at high levels of ductility. This correlation is attributed to the fact that mortars with high ductility have high capacity to accommodate thermal incompatibilities. It is believed that the two opposing processes occur in mortars: (1) further geopolymerisation and/or sintering at elevated temperatures leading to strength gain; (2) the damage to the mortar because of thermal incompatibility arising from non-uniform temperature distribution. The strength gain or loss occurs depending on the dominant process.     

HPLC/ESI-quadrupole ion trap mass spectrometry for characterization and direct quantification of amphoteric and nonionic surfactants in aqueous samples

An amphoteric (cocamidopropylbetaine, CAPB) and a nonionic (alcohol polyethoxylate, AE) surfactant were characterized by electrospray ionization quadrupole ion trap mass spectrometry (ESI-MS) as to their homologue distribution and ionization/fragmentation chemistry. Quantitative methods involving reversed-phase gradient HPLC and (+)ESI-MSn were developed to directly determine these surfactants in hydroponic plant growth medium that received simulated graywater. The predominant homologues, 12 C alkyl CAPB and 9 EO AE, were monitored to represent the total amount of the respective surfactants. The methods demonstrated dynamic linear ranges of 0.5-250 ng (r2 > 0.996) for CAPB and 8-560 ng (r2 > 0.998) for AE homologue mixture, corresponding to minimum quantification limits of 25 ppb CAPB and 0.4 ppm AE with 20-microL injections. This translated into an even lower limit for individual components due to the polydispersive nature of the surfactants. The procedure was successfully employed for the assessment of CAPB and AE biodegradation in a hydroponic plant growth system used as a graywater bioreactor.     

Phase-shifting birefringent scatterplate interferometer

We realized what we believe is a new phase-shifting scatterplate interferometer by exploiting the polarization characteristics of a birefringent scatterplate. The common-path design of the interferometer reduces its sensitivity to environmental effects, and phase shifting allows quick and accurate quantitative measurements of the test surface. A major feature of the birefringent scatterplate approach for phase shifting is that no high-quality optical components are required in the test setup. The theory of the interferometer is presented, the procedure for the fabrication of the birefringent scatterplate is described, and experimental results are shown.