Synthesis and structural characterization of methacrylic acid/octadecyl acrylate‐graft‐poly(methylhydrosiloxane) by hydrosilylation

Methylmethacrylate (MMA) and octadecyl acrylate (OA) were grafted to poly(methylhydrosiloxane) (PMHS) by hydrosilylation, respectively, with hexachloroplatinic acid as catalyst, and the former was further hydrolyzed to prepare methacrylic acid (MAA)‐graft‐PMHS under the alkaline condition. Through orthogonal experiment, main factors affecting the graft reaction between OA and PMHS were discussed and arranged in a decreasing order according to their abilities of the effect on the hydrosilylation of OA with PMHS: catalyst dosage, reaction temperature, reaction time, material ratio, and solvent dosage. It was found that the hydrosilylation of OA with PMHS was easier to that of MMA with PMHS. Under optimal conditions, the grafting ratios of MMA with PMHS and OA with PMHS reached about 90 and 95%, respectively. FTIR and ¹H NMR spectra indicated that the hydrosilylation reactions followed the Markovnikov's rule and played a strong preference toward β‐1,2‐addition. The test of contact angle indicated that surface energy of a system was mainly dependent on the polar groups. The surface energy of OA‐graft‐PMHS (35.07 mN/m) was similar to those of PMHS (35.62 mN/m) and polyoctadecyl acrylate (36.57 mN/m), and lower than that of MAA‐graft‐PMHS (43.50 mN/m). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

超临界流体中的酶催化

与其他非水相酶催化介质相比 ,超临界流体有其独特的优越性。阐述了超临界流体的概念、对超临界流体的选择原则以及在超临界流体中酶催化的各种影响因素 ,还讨论了在此类流体中酶催化的应用和发展前景     

On agent-mediated electronic commerce

This paper surveys and analyzes the state of the art of agent-mediated electronic commerce (e-commerce), concentrating particularly on the business-to-consumer (B2C) and business-to-business (B2B) aspects. From the consumer buying behavior perspective, agents are being used in the following activities: need identification, product brokering, buyer coalition formation, merchant brokering, and negotiation. The roles of agents in B2B e-commerce are discussed through the business-to-business transaction model that identifies agents as being employed in partnership formation, brokering, and negotiation. Having identified the roles for agents in B2C and B2B e-commerce, some of the key underpinning technologies of this vision are highlighted. Finally, we conclude by discussing the future directions and potential impediments to the wide-scale adoption of agent-mediated e-commerce.     

GB 19865 & GB 6675 ANNEX A.A——SAFETY OF ELECTRICAL TOYS Differences Between the new and old Chinese National Standards

This article anlayzes the different requirements for electrical toys safety between GB 6675-2003 and GB19865-2005. This information is summed up in table form to make it easy for toy designers and manufacturers to grasp the new standard.     

粒度控制——页岩、煤矸石空心砖原料制备的关键

阐述了页岩、煤矸石的原料粒度对制砖性能的影响,介绍了几种典型的控制颗粒粒度的工艺方案;简要分析了几种筛分机械的优缺点,着重介绍MVS电磁振动高频振网筛在几个使用现场的应用结果,为制砖企业解决原料生产的难题提供了办法。     

Preparation and Characterization of Carboxymethyl Chitosan and β-Cyclodextrin Microspheres by Spray Drying

Three kinds of carboxymethyl chitosan/β-cyclodextrin microspheres loaded with theophylline were prepared by spray drying intended for pulmonary delivery. Mucociliotoxicity, permeation rate, and drug release characteristics of the product were investigated. The microspheres obtained by spray drying were found to be spherical with smooth or wrinkled surfaces. The mean particle size was between 3.39 and 6.06 µm. The microspheres demonstrated high product yield (43.7-50.2%), high drug loading (13.7-38.1%), and high encapsulation efficiency (86.9-92.8%). FT-IR indicated that there were interactions of theophylline with carboxymethyl chitosan matrix. Further studies on mucociliotoxicity and permeation confirmed that microspheres had better adaptability and high permeation rate. In vitro drug release from the microspheres was not related to the drug/polymer ratios.     

Red Wine Polyphenols for Cancer Prevention

Conventional cancer therapies, the second leading cause of death worldwide, result in serious side effects and, at best, merely extend the patient''s lifespan by a few years. Searching for effective prevention is of high priority in both basic and clinical sciences. In recent decades natural products have been considered to be an important source of cancer chemopreventive agents. Red wine polyphenols, which consisted of various powerful antioxidants such as flavonoids and stilbenes, have been implicated in cancer prevention and that promote human health without recognizable side effects. Since resveratrol, a major component of red wine polyphenols, has been studied and reviewed extensively for its chemopreventive activity to interfere with the multi-stage carcinogenesis, this review focuses on recent progress in studies on cancer chemopreventive activities of red wine polyphenol extracts and fractions as well as other red wine polyphenols, like procyanidin B5 analogues and myricetin.     

GPS定位精度的提高及其应用

本文简明介绍了美国全球定位系统(GPS)的工作原理和误差来源,通过了解误差来源阐述了较准准确的定位技术DGPS的原理和应用。     

双工频感应加热淬火技术在小型冷轧工作辊上的应用

双工频感应加热淬火Φ200mm以下的小型冷轧工作辊，其性能优于单工频感应加热淬火，延长了轧辊的使用寿命。     

An Application of Interval Methods to Stock Market Forecasting

Stock market forecasting has been a challenging financial research topic for decades. In the literature, there are numerous results based on point methods. However, poor forecasting quality has been a continuous problem. Motivated by the fact that financial data varies within intervals, we apply interval methods on a well known stock pricing model [3] to predict stock market variability as intervals. Empirical results obtained with a few different approaches in this paper consistently suggest that interval forecasts have better overall quality than traditional point forecasts.