全文获取类型
收费全文 | 14979篇 |
免费 | 1287篇 |
国内免费 | 14篇 |
专业分类
电工技术 | 141篇 |
综合类 | 12篇 |
化学工业 | 3820篇 |
金属工艺 | 183篇 |
机械仪表 | 402篇 |
建筑科学 | 658篇 |
矿业工程 | 39篇 |
能源动力 | 403篇 |
轻工业 | 2962篇 |
水利工程 | 128篇 |
石油天然气 | 35篇 |
无线电 | 1015篇 |
一般工业技术 | 2731篇 |
冶金工业 | 776篇 |
原子能技术 | 46篇 |
自动化技术 | 2929篇 |
出版年
2024年 | 45篇 |
2023年 | 201篇 |
2022年 | 335篇 |
2021年 | 557篇 |
2020年 | 417篇 |
2019年 | 439篇 |
2018年 | 639篇 |
2017年 | 641篇 |
2016年 | 709篇 |
2015年 | 582篇 |
2014年 | 741篇 |
2013年 | 1361篇 |
2012年 | 1299篇 |
2011年 | 1226篇 |
2010年 | 812篇 |
2009年 | 773篇 |
2008年 | 837篇 |
2007年 | 739篇 |
2006年 | 591篇 |
2005年 | 446篇 |
2004年 | 399篇 |
2003年 | 330篇 |
2002年 | 326篇 |
2001年 | 180篇 |
2000年 | 181篇 |
1999年 | 127篇 |
1998年 | 163篇 |
1997年 | 137篇 |
1996年 | 112篇 |
1995年 | 116篇 |
1994年 | 97篇 |
1993年 | 77篇 |
1992年 | 54篇 |
1991年 | 48篇 |
1990年 | 33篇 |
1989年 | 38篇 |
1988年 | 34篇 |
1987年 | 19篇 |
1986年 | 25篇 |
1985年 | 35篇 |
1984年 | 39篇 |
1983年 | 27篇 |
1982年 | 25篇 |
1981年 | 29篇 |
1980年 | 19篇 |
1979年 | 33篇 |
1978年 | 17篇 |
1977年 | 16篇 |
1976年 | 14篇 |
1975年 | 17篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
121.
Qianyu Yang Chen Gao Xuemei Zhang Chihui Tsou Xingyu Zhao Manuel Reyes De Guzman Zejun Pu Xinyue Li Yue Lu Chunyan Zeng Li Yuan Yiqing Xia Yuping Sheng Yiqing Fu 《大分子材料与工程》2021,306(7):2100093
Hydrogels with excellent stiffness, toughness, anti-fatigue, and self-recovery properties are regarded as promising water-containing materials. In this work, a dual physically cross-linked (DPC) sodium alginate (SA)/poly[acrylamide (AAm)-acrylic acid (AAc)-octadecyl methacrylate (OMA)]-Fe3+ hydrogel is reported, which is constructed by hydrophobic association (HA) and ionic coordination (IC). The optimal DPC hydrogel demonstrates excellent mechanical performance: tensile modulus of 0.65 MPa, tensile strength of 3.31 MPa, elongation at break of 1547%, and toughness of 27.8 MJ m–3. SA/P(AAm-AAc-OMA)-Fe3+ DPC hydrogels also exhibit prominent anti-fatigue and self-recovery performance (99.1–109.7% modulus recovery and 90.4–108.9% dissipated energy recovery after resting for 5 min without additional stimuli at ambient temperature) through the reconstruction of reversible physical cross-linking. Some of the SA/P(AAm-AAc-OMA)-Fe3+ DPC hydrogels even exhibit a stretching-induced strengthening effect, which is similar to the performance of muscle—“the more training, the more strength.” Hence, the combination of HA and IC will provide an effective approach to design DPC hydrogels with desirable mechanical performances and a longer service life for wider applications of soft materials. 相似文献
122.
Luis A. Pérez-Maqueda José Manuel Criado Concepción Real 《Journal of the American Ceramic Society》2002,85(4):763-768
A new method for the kinetic analysis of the initial stage of sintering for constant-heating-rate data has been proposed. Unlike all of the methods previously reported in the literature, this new method proposed here allows the simultaneous determination of the activation energy and the kinetic model from a single dilatometric curve recorded under a linear-heating-rate program. The proposed method has been tested with simulated sintering curves and experimental results have been obtained for the sintering of a rutile sample. 相似文献
123.
Manuel Belmonte Vitor A. Silva Antonio José Fernandes Florinda Costa Rui Silva 《Journal of the American Ceramic Society》2003,86(5):749-754
The efficiency of different surface pretreatments (four standard chemical etchings and four diamond powder abrasive procedures) on silicon nitride (Si3 N4 ) substrates for chemical vapor deposition (CVD) of diamond has been systematically investigated. Blank Si3 N4 samples were polished with colloidal silica (∼0.25 μm). Diamond nucleation and growth runs were conducted in a microwave plasma chemical vapor deposition apparatus for 10 min and 6 h, respectively. Superior results concerning nucleation density ( N d ∼ 1010 cm−2 after 10 min), film uniformity, and grain size (below 2 μm after 6 h) were obtained for the mechanically microflawed samples, revealing that chemical etchings (hot and cold strong acids, molten base or CF4 plasma) are not crucial for good CVD diamond quality on Si3 N4 . 相似文献
124.
Marcos R. Guilherme Adriano V. Reis Alexandre T. Paulino André R. Fajardo Edvani C. Muniz Elias B. Tambourgi 《应用聚合物科学杂志》2007,105(5):2903-2909
This contribution describes the absorption percentage of Pb2+ and Cu2+ from water by a superabsorbent hydrogel matrix (SH) made from an anionic polysaccharide copolymerized with acrylic acid (AAc) and acrylamide (AAm). Metal‐absorption tests, upon sequential pH variation, indicated that the SH has pH‐sensitivity for the absorption of both metals from solution, attributed to the functional ionic groups (? COOH) present in the AAc and arabic gum (AG) segments. At the pH 5.0, the SH exhibited good absorption capacity: 73.10% for Pb2+, 81.99% for Cu2+ in water and 63.64% for Pb2+, and 76.67% for Cu2+ in saline water with 0.1 mol kg?1 ionic strength. A replicated 22 full factorial design with a central point was built to evaluate the maximum absorption capacity of the metals into the SH. It was found that both the interaction and main effects of the pH and the initial concentration of metal solution on absorption percentage of the metals were statistically significant. Surface response plots indicated that the absorption capacity of both metals into the SH may be appreciably improved by using the solutions with lower initial concentration of metal and with higher pH values. Metal‐absorption results demonstrated that the SH is a convenient material for absorption of Pb2+ and Cu2+ from pure aqueous and saline aqueous environments. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
125.
Ethylene-propylene copolymers have been prepared by using Ziegler-Natta catalysts based on TiCl4, MgCl2, PCl3 and (n-Bu)3PO4. The catalysts TiCl4/MgCl2/PCl3 and TiCl4/MgCl2/(n-Bu)3PO4 were prepared by reacting TiCl4 with pretreated MgCl2. The support was prepared by ball milling of MgCl2 with varied amounts of PCl3 or (n-Bu)3PO4. The addition of PCl3 has remarkably increased the MgCl2 surface area in comparison with (n-Bu)3PO4. The effects of PCl3 and (n-Bu)3PO4 on ethylene homopolymerization, ethylene-propylene copolymerization and on copolymer properties were evaluated. The catalyst
system containing PCl3 permitted to synthesize propylene-ethylene copolymers with up to 75% (w/w) of propylene and provided control of copolymer
crystallinity. The reduction of the copolymer molecular weight distribution suggested that PCl3 acted as an internal donor, poisoning some active catalytic sites.
Received: 2 April 1997/Revised: 6 June 1997/Accepted: 18 June 1997 相似文献
126.
André F. van Rooyen Peter Ramshaw Martin Moyo Richard Stirzaker Henning Bjornlund 《国际水资源开发杂志》2017,33(5):804-823
AbstractMany small-scale irrigation systems are characterized by low yields and deteriorating infrastructure. Interventions often erroneously focus on increasing yields and rehabilitating infrastructure. Small-scale irrigation systems have many of the characteristics of complex socio-ecological systems, with many different actors and numerous interconnected subsystems. However, the limited interaction between the different subsystems and their agents prevents learning and the emergence of more beneficial outcomes. This article reports on using Agricultural Innovation Platforms to create an environment in which irrigation scheme actors can engage, experiment, learn and build adaptive capacity to increase market-related offtake and move out of poverty. 相似文献
127.
Bernhard Beckermann Jorge Bustamante Reinaldo Martínez-Cruz José M. Quesada 《Calcolo》2014,51(2):319-328
For a given $\theta \in (a,b)$ , we investigate the question whether there exists a positive quadrature formula with maximal degree of precision which has the prescribed abscissa $\theta $ plus possibly $a$ and/or $b$ , the endpoints of the interval of integration. This study relies on recent results on the location of roots of quasi-orthogonal polynomials. The above positive quadrature formulae are useful in studying problems in one-sided polynomial $L_1$ approximation. 相似文献
128.
In this paper we propose and evaluate a set of new strategies for the solution of three dimensional separable elliptic problems on CPU–GPU platforms. The numerical solution of the system of linear equations arising when discretizing those operators often represents the most time consuming part of larger simulation codes tackling a variety of physical situations. Incompressible fluid flows, electromagnetic problems, heat transfer and solid mechanic simulations are just a few examples of application areas that require efficient solution strategies for this class of problems. GPU computing has emerged as an attractive alternative to conventional CPUs for many scientific applications. High speedups over CPU implementations have been reported and this trend is expected to continue in the future with improved programming support and tighter CPU–GPU integration. These speedups by no means imply that CPU performance is no longer critical. The conventional CPU-control–GPU-compute pattern used in many applications wastes much of CPU’s computational power. Our proposed parallel implementation of a classical cyclic reduction algorithm to tackle the large linear systems arising from the discretized form of the elliptic problem at hand, schedules computing on both the GPU and the CPUs in a cooperative way. The experimental result demonstrates the effectiveness of this approach. 相似文献
129.
The equation of state model developed by Lacombe and Sanchez (J Phys Chem 1976, 80, 2352) is used in the form proposed later by Sanchez and Stone (Polymer Blends, Vol. 1: Formulation, 2000; Chapter 2) to correlate experimental vapor‐liquid equilibrium (VLE) data for the three binaries and the ternary systems. Experimental data from the binary systems carbon dioxide‐isopropyl alcohol (CO2‐IPrOH), isopropyl alcohol‐polystyrene (IPrOH‐PS), and carbon dioxide‐polystyrene (CO2‐PS) are used to calculate VLE properties for the ternary system CO2‐IPrOH‐PS. Two‐dimensional VLE‐phase diagrams were calculated and used to describe from a thermodynamic point of view the pressure, volume, and temperature values that characterize a thermoplastic foam evolution process, from the extruder to the foaming die. For different initial mixture CO2 + IPrOH concentrations, pressure reduction produces liquid foaming until the vitrification curve arrests the final foam volume expansion. The dependence of the vitreous transition with the system CO2 + IPrOH concentration while foaming is represented by the Chow (Macromolecules 1980, 13, 362) equation. The calculation procedure is proposed as a design tool to reduce the amount of experimental data usually needed as a requirement previous to the design stage. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2663–2671, 2007 相似文献
130.
Rana M. Tubaileh Antonio Garrido-Fernández M. Victoria Ruiz-Méndez Manuel León-Camacho Enrique Graciani-Constante 《Journal of the American Oil Chemists' Society》2002,79(1):101-104
Changes in the contents of waxes and fatty alcohols during deodorization/physical refining of bleached olive oil were studied.
Experiments were carried out with 1.85% acidity oil, which was physically refined in a discontinuous deodorizer of 250-kg
maximum capacity using nitrogen as stripping gas instead of steam. The variables studied were load and temperature of oil
in the deodorizer as well as N2 flow. Analyses of waxes and alcohols were carried out at different operation times. The maximum content of wax was always
observed when the oil reached the deodorization temperature. The variation in the wax content depended on temperature and
N2 flow. Wax decomposition started and continued during the operating time, and a progressive decrease, which was pronounced
between 3 and 4 h, was observed. Small changes in waxes were observed between 4 and 5 h. Total content of fatty alcohols diminished
throughout the operating time, and changes did not depend on the variables studied. 相似文献