Phase study on solid fission products,Ba, Sr and Zr in oxide fuel

Behavior of pseudo-fission products (Ba, Sr, and Zr) as oxides in UO₂ has been investigated by means of high-temperature X-ray diffraction and microprobe analysis. Two identifiable compounds were formed as reaction products in the mixed oxides which initially consisted of UO₂, BaO, SrO, and ZrO₂ powder. These compounds were present and were identified crystallographically as (Ba, Sr) ZrO₃ and (Ba, Sr)UO₃ after heat treatment of the powders at 1500°C for 30 min. Both compounds are isostructural with perovskite, CaTiO₃, and the lattice parameters of both (Ba, Sr)ZrO₃ and (Ba, Sr)UO₃ decrease with increasing content of Sr. (Ba, Sr)UO₃ is decomposed almost completely at 1800°C while (Ba, Sr) ZrO₃ is stable up to 2000°C. The behavior of Ba, Sr, and Zr in fuel under irradiation is discussed.     

Mechanical properties of high purity polycrystalline cBN synthesized by direct conversion sintering method

Mechanical properties of high purity polycrystalline cBN sintered bodies synthesized by the direct conversion method under high pressure and high temperature have been investigated by hardness and transverse rupture strength (TRS) measurement in the temperature range of 20–1200 °C. It was confirmed that the hardness and TRS of the polycrystalline cBN depends strongly on the cBN grain size and the amount of residual (compressed) hBN in the sintered body. The fine-grained (<0.5 m) and high purity (cBN > 99.9%) polycrystalline sintered body synthesized at 7.7 GPa, 2200–2400°C has highest hardness and TRS at any temperature. The TRS of the sintered body shows a positive temperature dependence up to 1200 °C. The high hardness and high TRS at high temperature of the fine-grained high purity polycrystalline cBN suggest that the sintered body has high potential in cutting tool uses.     

Investigation of gas-liquid interface in atmospheric-pressure micro plasma with solution

An atmospheric-pressure glow-discharge micro plasma in contact with liquid paraffin is stably generated by using a capacitively coupled plasma method with a mesh electrode. When characteristics of the plasma are measured in the boundary between the micro plasma (gas-phase) and liquid paraffin (liquid-phase) using optical emission spectroscopy, spectrum peaks of the emission of CH and C₂ which dissociate from paraffin are observed. The result indicates that solution can feed particles to the plasma at gas-liquid interface and this plasma is accordingly expected to promote an attractive plasma process for creating materials consisting of elements in various solutions.     

Performance of SOR methods on modern vector and scalar processors

The building-cube method (BCM) is a new generation algorithm for CFD simulations. The basic idea of BCM is to simplify the algorithm in all stages of flow computation to achieve large-scale simulations. Calculation of a pressure field using the Successive Over Relaxation (SOR) method consumes most of the total execution time required for BCM. In this paper, effective implementations on modern vector and scalar processors are investigated. NEC SX-9 and Intel Nehalem-EX are the latest vector and scalar processors. Those processors have much higher peak performances than their previous-generation processors. However, their memory bandwidth improvement cannot catch up with the performance improvement of processors. This is the so-called memory wall problem. In our paper, we discuss optimization techniques for implementation of the SOR method based on architectural characteristics of these modern processors, and evaluate their effects on the sustained performances of these processors for BCM.     

Main R&D issues for fast reactor structural design standard

For realization of economical and reliable fast reactor (FR) plants, the Japan Atomic Energy Agency (JAEA) and the Japan Atomic Power Company (JAPC) are cooperating on the “Feasibility Study on Commercialized FR Cycle Systems”. To certify the design concepts through evaluation of the structural integrity of FR plants, the research and development of the “Elevated Temperature Structural Design Guide for Commercialized Fast Reactor (FDS)” is recognized as an essential theme. The FDS focuses on particular failure modes of FRs such as ratchet deformation and creep-fatigue damage due to cyclic thermal loads. For precise evaluation of these modes, the research and development for three main issues is in progress. First, the “Refinement of Failure Criteria” needs to be addressed for particular failure modes of FRs. Secondly, the development of “Guidelines for Inelastic Design Analysis” is conducted to predict elastic plastic and creep deformation under elevated temperature conditions. Lastly, efforts are being made toward preparing “Guidelines for Thermal Load Modeling” for the design of FR components where thermal loads are dominant.     

Selective vapor phase hydroformylation of ethylene over cluster-derived cobalt catalyst

Vapor phase hydroformylation of ethylene was studied with silica-supported metal catalysts. A cobalt metal catalyst derived from Co₂(CO)₈ gave propanal and its derivatives in as high selectivity of about 36% as Rh/SiO₂ catalyst under the reaction conditions of 1.1 MPa of a gas-mixture of ArCOC₂H₄H₂ = 1333 at 423–503 K. On the other hand, conventional cobalt catalysts derived from cobalt nitrate, chloride, or acetate, and other noble metal catalysts (Pd/SiO₂ and Ir/SiO₂) produced mainly ethane.     

A dynamic default revision mechanism for speculative computation

In this work a default revision mechanism is introduced into speculative computation to manage incomplete information. The default revision is supported by a method for the generation of default constraints based on Bayesian networks. The method enables the generation of an initial set of defaults which is used to produce the most likely scenarios during the computation, represented by active processes. As facts arrive, the Bayesian network is used to derive new defaults. The objective with such a new dynamic mechanism is to keep the active processes coherent with arrived facts. This is achieved by changing the initial set of default constraints during the reasoning process in speculative computation. A practical example in clinical decision support is described.     

Estimation of compound classes in coal hydrogenation liquids by thin-layer chromatography

Compound classes in coal liquids were investigated by thin-layer chromatography coupled with a flame ionization detector (t.l.c.-f.i.d.). Individual t.l.c. peaks for coal liquids were identified as paraffins, aromatics, polar compounds and more strongly polar compounds or asphaltenes in order of increasing R_f values by comparison with specific compounds separated previously by conventional liquid chromatography. Concentrations of compound classes for a series of samples obtained by varying the hydrogenation time were estimated and good agreement was found with the results obtained by the USBM-API 60 liquid chromatography procedure. By using the t.l.c.-f.i.d. method, the relation of distribution of compound classes to the reaction conditions of coal hydrogenation could be derived quantitatively with relative ease.