Reproducibility of plastic measurements: The need to modify State Standard GOST 1186-87

A very important characteristic of coking coal is its clinkering ability, i.e., its ability to form a nonvolatile solid residue, consisting of disparate grains, on heating in specific conditions. The clinkering ability of the coal is determined by the properties of its plastic mass. Various methods may be used to evaluate the plastic-ductile properties of the coal. However, since the 1930s, the main method used to evaluate the clinkering properties of coal, within the nations of the former Soviet Union, has been the Sapozhnikov-Bazilevich plastometric method, because it provides more information than competing approaches. For the same reason, the thickness of the plastic layer, which is one of the parameters determined by this method, is used for coal classification in State Standard GOST 25543-88 (Lignite, Coal, and Anthracite: Genetic and TEchnological Classification) and its Ukrainian counterpart DSTU 3472-96 (Lignite, Coal, and Anthracite: Classification). This explains the strict requirements on the accuracy and reliability of the plastometric characteristics.     

Noise–Power Optimization of Incremental Data Converters

Incremental data converters (IDCs) are useful in instrumentation and measurement applications, where low-frequency analog signals need to be converted into digital form with high accuracy and low power dissipation. They are particularly well suited for applications where a single analog-digital converter is multiplexed between many channels. This paper proposes an exact design methodology for IDCs, which optimizes the signal-to-noise ratio of the converter under practical design constraints. The process also allows the designer to apportion the noise budget in an arbitrary manner between thermal and quantization noise. The design process is illustrated by an example which describes the optimization of a third-order multiplexed IDC.     

Swift and Selective Reduction of Nitroaromatics to Aromatic Amines with Ni–Boride–Silica Catalysts System at Low Temperature

Various nitroaromatics are successfully reduced to amines with 100% conversion and selectivity in methanol at low temperature (≈5 °C), by using versatile system of 5% Ni–SiO₂ catalyst and NaBH₄ and in situ generation of Ni boride. The catalytic efficiency of Ni loading (5%, 10% and 15%) with silica or titania as support materials is investigated for reduction of nitrobenzene. The Ni–titania/NaBH₄ system recorded lower conversion and selectivity. The IR studies indicate that silica support does not have free –OH group on its surface. Thus the nickel boride is anchored to the silica to facilitate the catalytic process.     

Robustness of classification rules that incorporate additional information

The discrimination problem for two normal populations with the same covariance matrix when additional information on the population is available is considered. A study of the robustness properties against training sample contamination of classification rules that incorporate this additional information is performed. These rules have received recently attention where their total misclassification probability (TMP) is proved to be lower than Fisher's linear discriminant rule. The results of a simulation study on the TMP which compares the behaviour of the new rules against Fisher's rule and some of its robustified versions under different types of contamination are presented. These results show that the rules that incorporate the additional information not only have lower TMP, but they also prevent against some types of contamination. In order to achieve prevention from all types of contamination a robustifed version of these rules is recommended.     

Prediction and quality control of the melt index during production of high-density polyethylene

In polyolefin processes the melt index (MI) is the most important control variable indicating product quality. Because of the difficulty in the on-line measurement of MI, a lot of MI estimation and correlation methods have been proposed. In this work a new dynamic MI estimation scheme is developed based on system identification techniques. The empirical MI estimation equation proposed in the present study is derived from the 1 ^st -order dynamic models. Effectiveness of the present estimation scheme was illustrated by numerical simulations based on plant operation data including grade change operations in high density polyethylene (HDPE) processes. From the comparisons with other estimation methods it was found that the proposed estimation scheme showed better performance in MI predictions. The virtual sensor model developed based on the estimation scheme was combined with the virtual on-line analyzer (VOA) to give a quality control system to be implemented in the actual HDPE plant. From the application of the present control system, significant reduction of transition time and the amount of off-spec during grade changes was achieved     

Onset of buoyancy-driven convection in melting from below

When a horizontal homogeneous solid is melted from below, convection can be induced in a thermally unstable melt layer. In this study the onset of buoyancy-driven convection during time-dependent melting is investigated by using similarly transformed disturbance equations. The critical Rayleigh numbers based on the melt-layer thickness are found numerically for various conditions. For small superheats, the present predictions approach the well known results of classical Rayleigh-Bénard problems, that is, critical Rayleigh numbers are located between 1,296 and 1,708, regardless of the Prandtl number. However, for high superheats the critical Rayleigh number increases with an increase in phase change rate but with decrease in Prandtl number.     

Laminar-turbulent transition in an electromagnetically levitated droplet

During experiments on the MSL-1 (first microgravity science laboratory) mission of the space shuttle (STS-83 and STS-94, April and July 1997), a droplet of palladium-silicon alloy was electromagnetically levitated for viscosity measurements. For the nondeforming droplet, the resultant magnetohydrodynamic (MHD) flow inside the drop can be inferred from motion of impurity particulates on the surface. In the experiments, subsequent to melting, Joule heating produces a continuous reduction of viscosity of the fluid resulting in an acceleration of the flow with time. These observations indicate formation of a pair of co-rotating toroidal flow structures inside the spheroidal drop that undergo flow instabilities. As the fluid temperature rises, the amplitude of the secondary flow increases, and beyond a point, the tracers exhibit noncoherent chaotic motion signifying emergence of turbulence inside the drop. Assuming that the observed laminar-turbulent transition is shear-layer type, the internal structure of the toroidal loops is used to develop a semiempirical correlation for the onset of turbulence. Our calculations indicate that the suggested correlation is in modest agreement with the experimental data, with the transition occurring at a Reynolds number of 600.     

Complex processing of fluorine-containing wastes of fluorite ores

The possibility of processing fluorine-containing wastes of fluorite ore, which include fluorite, calcite, quartz, and anorthite, has been investigated. A manufacturing flow chart of the complex processing of the ore waste materials with the production of sodium fluoride, alumina, soda ash, and raw materials suitable for the production of Portland cement and wollastonite is suggested.     

Removal of impurities from liquid solutions by vacuum desorption with solvent evaporation

Mass transfer with solvent evaporation in the vapor-liquid two-phase film evaporators used for the removal of undesirable impurities from liquid solutions at low pressure is studied. The average concentrations of solution components in the falling liquid film are determined. The most efficient operating conditions for impurity removal, in which the resistance to mass transfer is concentrated in the liquid phase, are found. Original Russian Text ? V.N. Babak, T.B. Babak, L.P. Kholpanov, 2008, published in Teoreticheskie Osnovy Khimicheskoi Tekhnologii, 2008, Vol. 42, No. 6, pp. 654–670.