Development of Nd (III)-Based Terahertz Absorbers Revealing Temperature Dependent Near-Infrared Luminescence

Molecular vibrations in the solid-state, detectable in the terahertz (THz) region, are the subject of research to further develop THz technologies. To observe such vibrations in terahertz time-domain spectroscopy (THz-TDS) and low-frequency (LF) Raman spectroscopy, two supramolecular assemblies with the formula [Nd^III (phen)₃ (NCX)₃] 0.3EtOH (X = S, 1-S; Se, 1-Se) were designed and prepared. Both compounds show several THz-TDS and LF-Raman peaks in the sub-THz range, with the lowest frequencies of 0.65 and 0.59 THz for 1-S and 1-Se, and 0.75 and 0.61 THz for 1-S and 1-Se, respectively. The peak redshift was observed due to the substitution of SCN⁻ by SeCN⁻. Additionally, temperature-dependent TDS-THz studies showed a thermal blueshift phenomenon, as the peak position shifted to 0.68 THz for 1-S and 0.62 THz for 1-Se at 10 K. Based on ab initio calculations, sub-THz vibrations were ascribed to the swaying of the three thiocyanate/selenocyanate. Moreover, both samples exhibited near-infrared (NIR) emission from Nd (III), and very good thermometric properties in the 300–150 K range, comparable to neodymium (III) oxide-based thermometers and higher than previously reported complexes. Moreover, the temperature dependence of fluorescence and THz spectroscopy analysis showed that the reduction in anharmonic thermal vibrations leads to a significant increase in the intensity and a reduction in the width of the emission and LF absorption peaks. These studies provide the basis for developing new routes to adjust the LF vibrational absorption.     

Development and Evaluation of a Robust Sandwich Immunoassay System Detecting Serum WFA-Reactive IgA1 for Diagnosis of IgA Nephropathy

Aberrant glycosylation of IgA1 is involved in the development of IgA nephropathy (IgAN). There are many reports of IgAN markers focusing on the glycoform of IgA1. None have been clinically applied as a routine test. In this study, we established an automated sandwich immunoassay system for detecting aberrant glycosylated IgA1, using Wisteria floribunda agglutinin (WFA) and anti-IgA1 monoclonal antibody. The diagnostic performance as an IgAN marker was evaluated. The usefulness of WFA for immunoassays was investigated by lectin microarray. A reliable standard for quantitative immunoassay measurements was designed by modifying a purified IgA1 substrate. A validation study using multiple serum specimens was performed using the established WFA-antibody sandwich automated immunoassay. Lectin microarray results showed that WFA specifically recognized N-glycans of agglutinated IgA1 in IgAN patients. The constructed IgA1 standard exhibited a wide dynamic range and high reactivity. In the validation study, serum WFA-reactive IgA1 (WFA+-IgA1) differed significantly between healthy control subjects and IgAN patients. The findings indicate that WFA is a suitable lectin that specifically targets abnormal agglutinated IgA1 in serum. We also describe an automated immunoassay system for detecting WFA+-IgA1, focusing on N-glycans.     

Modeling of Nonlinear Magnetizing Characteristics of Pole Transformer for Analyzing Islanding Prevention of Photovoltaic System

With increasing penetration of distributed generators such as photovoltaic (PV) systems in distribution systems, it is very important to quickly detect islanding caused by power system faults in order to assure electrical safety. We have developed a nonlinear magnetizing characteristics model of pole transformers for use in analyzing islanding prevention in PV systems. Basic experiments on the islanding detection were performed for verification of the proposed model. Analytical results obtained by the proposed model agreed well with experimental results.     

Rupture nucleation on an interface with a power-law relation between stress and displacement discontinuity

We consider rupture initiation and instability on a displacement-weakening interface. It is assumed to follow a power-law relation between a component of displacement discontinuity (whether tensile opening in mode I or shear slippage in modes II or III) and the reduction from peak strength of a corresponding component of stress (normal or shear stress) on the interface. That is, the stress decrease from peak strength, as the interface discontinuity develops, is assumed to be proportional to displacement-discontinuity to some exponent n > 0. The study is done in the 2D context of plane or anti-plane strain, for an initially coherent interface which is subjected to a locally peaked “loading” stress which increases quasi-statically in time. We seek to establish the instability point, when no further quasi-static solution exists for growth of the ruptured zone along the interface, so that dynamic rupture ensues. We have previously addressed the case of linear displacement-weakening (n = 1), and proven the remarkable result that for an unbounded solid, the length of the displacement-weakening zone along the interface at instability is universal, in the sense of being independent of the detailed spatial distribution of the locally peaked loading stress. Present results show that such universality does not apply when n differs from 1. Also, if n < 2/3, there is no phase of initially quasi-static enlargement of the rupturing zone; instead instability will occur as soon as the maximum value of the loading stress reaches the peak strength. We first employ an energy approach to give a Rayleigh–Ritz approximation for the dependence of quasi-static rupture length and maximum displacement-discontinuity on the loading stress distribution of a quadratic form. Results, depending on curvature of the loading distribution, show that qualitative features of the displacement-discontinuity development are significantly controlled by n, with the transition noted at n = 2/3. Predictions of the simple energy approach are in reasonable quantitative agreement with full numerical solutions and give qualitative features correctly.     

Reappraisal of loading rate effects on sand behavior in view of seismic design for pile foundation

This study re-visits the effects of loading rate on sand behavior in view of seismic design of pile foundation. Based on an extensive literature review covering both element testing and model testing, the paper summarizes the current understanding of the loading rate effects. The paper then describes the development of test apparatus used in this study and presents the data obtained from a series of monotonically increasing triaxial compression tests on Toyoura sand, varying the strain rate in the range of 0.005%/s to 250%/s. A total of 36 tests were conducted on dry and saturated sand, both under drained and undrained conditions with two confining pressures. The experimental results confirm that the soil strength and the soil stiffness increase as the strain rate increase. This paper also concludes that the internal friction angle and deformation modulus increase when the strain rate is high. The implications of the loading rate effect on pile foundation design are then presented.     

Advantage of Sodium Polyoxyethylene Lauryl Ether Carboxylate as a Mild Cleansing Agent

Five anionic surfactants widely used in commercial skin cleansers were studied: sodium polyoxyethylene lauryl ether carboxylate (EC), sodium polyoxyethylene alkyl ether sulfate (ES), sodium dodecyl sulfate, potassium laurate, and N-cocoyl-l-glutamic acid monosodium salt. The amount of surfactant from aqueous solution adsorbed into the stratum corneum (SC), the degree of SC swelling, the change of the secondary structure of SC proteins (denaturation). The surface tension of surfactant–zein mixed solutions, and the solubilization behavior of zein were measured. Results showed that EC had the lowest adsorption into SC, the lowest SC swelling, and lowest denaturation of SC proteins. Low interactions between surfactants and SC proteins were also observed for EC/ES mixture solutions as well as. Mixing EC with ES good foaming performance. The EC/ES mixture, at about 1:1 ratio, is an excellent surfactant system for skin cleanser applications having cleansing characteristics and mildness to the skin.     

Novel functional polymers: Poly(dimethylsiloxane)–polyamide multiblock copolymer. III. Synthesis and surface properties of disiloxane–aromatic polyamide multiblock copolymer

Disiloxane–aromatic polyamide(aramid) multiblock copolymers(2SiPASs) were synthesized using 1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane(BATS) as an analog of aramidsilicone resin consisting of aromatic polyamide and poly(dimethylsiloxane) (PDMS). 2SiPASs afford a transparent and toughened plastic film. The surface properties of 2SiPAS were investigated by X-ray photoelectron spectroscopy (xps) and static contact angle measurement. The results of surface analysis suggested that BATS content of the 2SiPAS surface increased with increasing BATS content in bulk. The interaction between the platelets and the 2SiPAS surface was found to be very weak when the BATS content reached 26 wt % in bulk. © 1996 John Wiley & Sons, Inc.