π‐Conjugated Molecules Crosslinked Graphene‐Based Ultrathin Films and Their Tunable Performances in Organic Nanoelectronics

Graphene‐based ultrathin films with tunable performances, controlled thickness, and high stability are crucial for their uses. The currently existing protocols, however, could hardly simultaneously meet these requirements. Using amino‐substituted π‐conjugated compounds, including 1,4‐diaminobenzene (DABNH2), benzidine (BZDNH2), and 5,10,15,20‐tetrakis (4‐aminophenyl)‐21H,23H‐porphine (TPPNH2), as cross‐linkages, a new protocol through which graphene oxide (GO) nanosheets can be anchored on solid supports with a high stability and controlled thickness via a layer‐by‐layer method is presented. A thermal annealing leads to the reduction of the films, and the qualities of the samples can be inherited by the as‐produced reduced GO films (RGO). When RGO films are integrated as source/drain electrodes in OFETs, tunable performances can be realized. The devices based on the BZDNH2‐crosslinked RGO electrodes exhibit similar electrical behaviors as those based on the non‐π‐conjugated compound crosslinked electrodes, while improved performances can be gained when those crosslinked by DABNH2 are used. The performances can be further improved when RGO films crosslinked by TPPNH2 are employed. This work likely paves a new avenue for graphene‐based films of tunable performances, controlled thickness, and high stability.     

61单元分立式压电变形反射镜的研制

用于校正波前误差的61单元分立式压电变形反射镜是61单元自适应光学系统（AO）的关键器件之一。由于系统对单元数（61单元）和变形量（±3μm）的要求超过以往曾研制的变形镜，对研制工作带来许多困难。我们从理论分析到工艺研究采取措施，使研制的变形镜成功用于AO系统实验。     

Entwurf nichtrekursiver Digitalfilter mit beliebigen Betrags- und Phasengängen

This paper presents an efficient multiple exchange algorithm for the frequency domain design of digital FIR filters with arbitrary magnitude and phase responses. The designed filters minimize theL ₂ norm of the weighted complex frequency domain error function subject to constraints on the resulting magnitude and phase errors. This general design criterion allows for an arbitrary trade-off between complexL ₂ approximation and Chebyshev approximation of given magnitude and phase responses. The optimization can be carried out by iteratively solving small quadratic programs. These linearly constrained subproblems can be solved using robust standard software.     

从上海市民的居住生活习惯看能源消耗特征

通过对上海市314户居民进行问卷调查,根据当地居民的居住条件、生活习惯和家用电器使用情况,分析能源消费特征。在此基础上分析了居民能源使用结构和能源消费观念,为相关部门进行能源规划和政策调整提供参考依据。     

PLC课程体系的多层次实验结构的研究

因为可编程控制器PLC课程具有自动控制、计算机和网络技术相结合的特色,本文以PLC为核心,从控制系统的知识结构出发,构建了一个PLC、组态技术和工业控制网络交互的多模式、多层次的实验系统,使学生达到知识与能力的有机统一。该研究与实践为推动自动化专业创新教育,培养具有综合素质和全面发展的应用型高级工程技术人才起到一个重要的作用。     

Protocol-aided channel equalization in wireless ATM

We study the equalization problem in time division multiple access wireless asynchronous transfer mode (ATM) systems. Aiming at minimizing the overhead associated with equalization, we propose a protocol-aided channel equalization (PACE) approach for wireless ATM. Specifically, the medium access control (MAC) and data link control (DLC) protocols are exploited to provide known ATM cell headers to the receiver at the base station. A blind channel estimation-decision feedback equalizer (BCE-DFE) algorithm is developed for uplink data transmissions. There are two advantages of the BCE-DFE algorithm: the elimination of training symbols for uplink data bursts and the removal of channel estimation error propagation suffered by conventional block equalization schemes. Simulation results show the BCE-DFE has a robust performance for wireless ATM uplink data transmissions over fast time-varying channels     

Nanoporous Surface High-Entropy Alloys as Highly Efficient Multisite Electrocatalysts for Nonacidic Hydrogen Evolution Reaction

Electrocatalytic hydrogen evolution in alkaline and neutral media offers the possibility of adopting platinum-free electrocatalysts for large-scale electrochemical production of pure hydrogen fuel, but most state-of-the-art electrocatalytic materials based on nonprecious transition metals operate at high overpotentials. Here, a monolithic nanoporous multielemental CuAlNiMoFe electrode with electroactive high-entropy CuNiMoFe surface is reported to hold great promise as cost-effective electrocatalyst for hydrogen evolution reaction (HER) in alkaline and neutral media. By virtue of a surface high-entropy alloy composed of dissimilar Cu, Ni, Mo, and Fe metals offering bifunctional electrocatalytic sites with enhanced kinetics for water dissociation and adsorption/desorption of reactive hydrogen intermediates, and hierarchical nanoporous Cu scaffold facilitating electron transfer/mass transport, the nanoporous CuAlNiMoFe electrode exhibits superior nonacidic HER electrocatalysis. It only takes overpotentials as low as ≈240 and ≈183 mV to reach current densities of ≈1840 and ≈100 mA cm⁻² in 1 m  KOH and pH 7 buffer electrolytes, respectively; ≈46- and ≈14-fold higher than those of ternary CuAlNi electrode with bimetallic Cu–Ni surface alloy. The outstanding electrocatalytic properties make nonprecious multielemental alloys attractive candidates as high-performance nonacidic HER electrocatalytic electrodes in water electrolysis.     

LD泵浦Nd∶YVO4与Nd∶GdVO4腔内倍频绿光激光器的对比研究

报道了LD端面分别泵浦Nd∶YVO4、Nd∶GdVO4晶体,腔内Ⅱ类相位匹配KTP倍频的绿光激光器.通过对激光材料热透镜效应的分析,得出优化的谐振腔参数,在泵浦功率为6.1 W时得到的绿光激光器的光-光转化效率分别为15.5%、10.7%.从实验结果中,得到两种激光晶体的一些性能差异,为以后的研究提供一些参考.     

Field Measurements with a 5.25 GHz Broadband MIMO-OFDM Communication System

Theoretical capacity calculations and corresponding simulations show significant capacity/throughput gains from MIMO systems. Whether these gains are achievable in a real system, deployed in a practical environment, depends on a variety of factors, such as the choice of the communication algorithms, analog impairments and the "quality" of the wireless channel to sustain MEMO communications. In this paper, a 5.25 GHz broadband MIMO-OFDM testbed is described along with field measurements conducted with it. The MIMO-OFDM communication algorithms and also the impact of analog impairments on the performance of the system are described. Detailed system calibration results are described which serve as a baseline for results of field measurements. The results of wireless measurements are compared with the theoretical capacity, computed with the channel estimates obtained during the demodulation process. The average achievable capacity in the indoor wireless environment is shown to be 9.97 bps/Hz (bits per sec per Hz) while the capacity loss due to analog impairments and the choice of algorithms is about 2.33 bps/Hz. Also, field measurements conducted with the system in various environments are presented comparing the average throughput/capacity achieved in each of these environments.     

浅谈网络安全

介绍了网络建设中的安全问题 ,并从两个方面提出了相应的解决措施。