Monodisperse polymer/metal composite particles by electroless chemical deposition: Effect of surface functionality of polymer particles

Micron‐sized polymer particles were coated with layers of nickel compounds by plating electrolessly in the presence of aqueous solutions of nickel chloride, sodium hypophosphite, sodium citrate, and ammonium chloride at elevated temperature. The uniform functional polymer particle could be obtained by seeded polymerization. To investigate the effect of surface functionality on the conditions for nickel deposition, the polymer particle was functionalized with the thiol group. From morphological observation, it was found that the mode of nickel deposition was greatly dependent on the surface functionality of the polymer particle. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 420–424, 2003     

Effects of the reinforcement and toughening of acrylate resin/CaCO3 nanoparticles on rigid poly(vinyl chloride)

Novel composite particles based on nanoscale calcium carbonate (nano‐CaCO₃) as the core and polyacrylates as the shell were first synthesized by in situ encapsulating emulsion polymerization in the presence of the fresh slush pulp of calcium carbonate (CaCO₃) nanoparticles. Subsequently, these modified nanoparticles were compounded with rigid poly(vinyl chloride) (RPVC) to prepare RPVC/CaCO₃ nanocomposites. At the same time, the effects of the reinforcement and toughening of these modified nanoparticles on RPVC were investigated, and the synergistic effect of modified nanoparticles with chlorinated polyethylene (CPE) was also studied. The results showed that in the presence of nano‐CaCO₃ particles, the in situ emulsion polymerization of acrylates was carried out smoothly, and polyacrylates successfully encapsulated on the surface of nano‐CaCO₃ to prepare the modified nanoparticles, breaking down nano‐CaCO₃ particle agglomerates, improving their dispersion in the matrix, and also increasing the particle–matrix interfacial adhesion. Thus, the effects of the reinforcement and toughening of these modified nanoparticles on RPVC were very significant, and the cooperative effect of the nanoparticles with CPE occurred in the united modification system. Scanning electron microscopy analyses indicated that large‐fiber drawing and network morphologies coexisted in the system of joint modification of nanoparticles with CPE. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3940–3949, 2007     

Synthesis and Morphology of TiO2 Nanotube Arrays by Anodic Oxidation Using Modified Glycerol-Based Electrolytes

Titanium dioxide (TiO₂) nanotube arrays were prepared by electrochemical anodization of titanium sheets in the glycerol 176 mL/H₂O 44 mL/NH₄F 0.5 wt% electrolytes modified with H₂SO₄ and NaAc addition. The surface morphologies, average inner diameter, and the length of the nanotube arrays changed with the solution pH in the range from 5.6 to 4.0 by adding H₂SO₄. A uniform surface morphology of the nanotubes with average inner diameter of ∼80 nm and a length of ∼1000 nm was obtained when the solution pH was 5.0. The growth rates of the nanotubes were remarkably enhanced by NaAc addition in the range of 0.04–0.14 M . With NaAc addition of 0.10 M , the length of the nanotube arrays reached 4.16 μm after an 8-h anodization, increasing 3.23 μm compared with no NaAc addition. The relationship between solution pH and growth of TiO₂ nanotubes was analyzed by current–time curves, solution electrical conductivities, and scanning electron microscopy (SEM), and the role of NaAc was also discussed based on SEM and solution electrical conductivities.     

红外吸收法测硅铁中的超低硫

应用高频红外碳硫仪,建立了硅铁合金中超低硫测定方法,对选择适当的测定条件如助熔剂、分析时间等进行了探讨,最佳测定条件:最大工作电流为400～480 mA;载气纯度为99.99%;陶瓷坩埚需经1 100℃灼烧2 h后,可使空白降至最小;硫元素最短分析时间为40 s,比较水平为5.00.     

Performance evaluation of anti-radiation based on the gamma degradation process

In the environment of space radiation, the high-energy charged particles or high-energy photons acting on a spacecraft can cause either temporary device degradation or permanent failure. The traditional probability model is difficult to obtain reliable estimation of unit radiation resistance performance with small samples. Considering that different products will change differently after high-energy particle radiation, we construct a model based on the gamma degradation process. This model can efficiently describe the law of unit radiation resistance variation with the total radiation dose levels under the effect of the total dose and displacement damage. Finally, the proposed model is used to assess the anti-radiation performance of the N-channel power MOSFET device STRH60N20FSY3 produced by STM to obtain average unit radiation resistance, survival probability, survival function, etc.     

四川地震灾区民族体育旅游开发研究——以阿坝州为例

本文主要通过文献资料和实地调研研究方法对四川地震灾区阿坝州目前民族体育旅游开发现状进行研究,找出开发的内容和途径以及存在的问题,以促进这些地区民族体育旅游资源更有效的开发和利用。     

Non-Fourier heat conduction in a thin gold film heated by an ultra-fast-laser

Based on the dual-phase-lagging(DPL)heat conduction model,the Cattaneo-Vernotte(CV)model and the improved CV model we investigate the one-dimensional heat conduction in gold films with nano-scale thickness exposed to an ultra-fast laser heating.The influence of system parameters on the temperature field is explored.We find that for all the non-Fourier heat conduction models considered in this work,a larger Knudsen number normally leads to a higher temperature.For the DPL model,the large ratio of the phase lag of temperature gradient to the phase lag of heat flux reduces the maximum temperature and shortens the time for the system to reach its steady state.The CV model and the improved CV model lead to the similar thermal wave behavior of the temperature field,but the thermal wave speeds for these two models are different,especially for large Knudsen numbers.When the phase lag of temperature gradient is smaller,the difference between the DPL model and the improved CV model is not significant,but for the large phase lag of temperature gradient the difference becomes quite significant,especially for the large Knudsen number.In addition,the effect of the surface accommodation coefficient,which is a parameter in the slip boundary condition,on the temperature field of the gold film heated by ultra-fast laser pulses is investigated based on the DPL model.     

介质阻挡放电反应器降解邻二甲苯的特性研究

采用介质阻挡放电(DBD)降解常压下流动态的邻二甲苯模拟废气,系统地考察了放电极值电压,气体的初始质量浓度、停留时间以及相对湿度等工艺参数对邻二甲苯降解的影响,并初步探讨了邻二甲苯的降解产物.实验研究结果表明:在7.0kV的放电极间电压下,邻二甲苯的初始质量浓度为1 500mg/m3,停留时间为9s,其去除率可达到80%以上.降解产物主要为CO2、H2O以及苯甲酸、苯乙酸、苯乙醛等有机物,并且经降解后产物的生物可生化性得到提高,因而为后续的等离子-生物法联合处理VOCs提供了依据.     

Ti和V对Fe中氢与位错交互作用的影响

研究了Fe-0.5wt-%Ti和Fe-0.5wt-%V合金中由氢与位错交互作用所形成的氢致冷加工内耗峰(H-CWP)。实验结果表明:合金元素对H-CWP、对氢与位错之间的交互作用有显著的影响,与氢作用愈强的元素,对H-CWP的影响愈大,内耗实验结果与力学性能之间存在着一定的联系.     

新日铁高炉冷却壁技术的进展及其在宝钢的应用

从结构、材料、冷却方式和壁厚等方面介绍了新日铁高炉用冷却壁的1～4代演变过程，同时简述了宝钢引进的第3代冷却壁制造技术及其应用概况。认为今后大型高炉冷却系统的设计会向冷却壁倾斜。