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91.
This paper reports on the synthesis of rice-like NiSe2 nanoparticles via a simple hydrothermal method by employing [bis(2-hydoxyacetophenato)nickle(II)], [Ni(HAP)2], as a novel nickel precursor. Effect of nickel source on morphology and size of nanostructures was also investigated. Moreover, the as-synthesized NiSe2 nanostructures were utilized as the photocatalyst for the degradation of methylene blue (MB) and as the counter electrode in dye-sensitized solar cells. The results showed that structures size and morphology have salient effect on solar cells and using rice-like NiSe2 nanoparticles leads to an increase in DSSCs efficiency compared to agglomerated sphere-like particles from 6.04 to 8.99?% (~49?% improvement). 相似文献
92.
Viscosity is a parameter that plays a pivotal role in reservoir fluid estimations. Several approaches have been presented in the literature (Beal, 1946; Khan et al, 1987; Beggs and Robinson, 1975; Kartoatmodjo and Schmidt, 1994; Vasquez and Beggs, 1980; Chew and Connally, 1959; Elsharkawy and Alikhan, 1999; Labedi, 1992) for predicting the viscosity of crude oil. However, the results obtained by these methods have significant errors when compared with the experimental data. In this study a robust artificial neural network (ANN) code was developed in the MATLAB software environment to predict the viscosity of Iranian crude oils. The results obtained by the ANN and the three well-established semi-empirical equations (Khan et al, 1987; Elsharkawy and Alikhan, 1999; Labedi, 1992) were compared with the experimental data. The prediction procedure was carried out at three different regimes: at, above and below the bubble-point pressure using the PVT data of 57 samples collected from central, southern and offshore oil fields of Iran. It is confirmed that in comparison with the models previously published in literature, the ANN model has a better accuracy and performance in predicting the viscosity of Iranian crudes. 相似文献
93.
Tianjiao Jia Yang Wang Yuanyuan Dou Yaowang Li Monica Jung de Andrade Run Wang Shaoli Fang Jingjing Li Zhou Yu Rui Qiao Zhuangjian Liu Yuan Cheng Yewang Su Majid Minary‐Jolandan Ray H. Baughman Dong Qian Zunfeng Liu 《Advanced functional materials》2019,29(18)
Smart textiles that sense, interact, and adapt to environmental stimuli have provided exciting new opportunities for a variety of applications. However, current advances have largely remained at the research stage due to the high cost, complexity of manufacturing, and uncomfortableness of environment‐sensitive materials. In contrast, natural textile materials are more attractive for smart textiles due to their merits in terms of low cost and comfortability. Here, water fog and humidity‐driven torsional and tensile actuation of thermally set twisted, coiled, plied silk fibers, and weave textiles from these silk fibers are reported. When exposed to water fog, the torsional silk fiber provides a fully reversible torsional stroke of 547° mm?1. Coiled‐and‐thermoset silk yarns provide a 70% contraction when the relative humidity is changed from 20% to 80%. Such an excellent actuation behavior originates from water absorption‐induced loss of hydrogen bonds within the silk proteins and the associated structural transformation, which are corroborated by atomistic and macroscopic characterization of silk and molecular dynamics simulations. With its large abundance, cost‐effectiveness, and comfortability for wearing, the silk muscles will open up additional possibilities in industrial applications, such as smart textiles and soft robotics. 相似文献
94.
Hadis Mohajerani Majid Kholghi Abolfazl Mosaedi Raziyeh Farmani Amir Sadoddin Markus Casper 《Water Resources Management》2017,31(6):1859-1879
This paper presents management of groundwater resource using a Bayesian Decision Network (BDN). The Kordkooy region in North East of Iran has been selected as study area. The region has been sub-divided into three zones based on transmissivity (T) and electrical conductivity (EC) values. The BDN parameters: prior probabilities and Conditional Probability Tables - CPTs) have been identified for each of the three zones. Three groups of management scenarios have been developed based on the two decision variables including “Crop pattern” and “Domestic water demand” across the three zones of the study area: 1) status quo management for all three zones represent current conditions; 2) the effect of change in cropping pattern on management endpoints and 3) the effect of future increased domestic water demand on management endpoints. The outcomes arising from implementing each scenario have been predicted by use of the constructed BDN for each of the zones. Results reveal that probability of drawdown in groundwater levels of southern areas is relatively high compared with other zones. Groundwater withdrawal from northern and northwestern areas of the study area should be limited due to the groundwater quality problems associated with shallow groundwater of these two zones. The ability of the Bayesian Decision Network to take into account key uncertainties in natural resources and perform meaningful analysis in cases where there is not a vast amount of information and observed data available – and opportunities for enabling inputs for the analysis based partly on expert elicitation,emphasizes key advantages of this approach for groundwater management and addressing the groundwater related problems in a data-scarce area. 相似文献
95.
96.
Majid Hamzehloo Jahangir Karimi Narges Eghbali Mohsen Mirzakhani Kioumars Aghapoor 《Drying Technology》2017,35(14):1688-1695
The microencapsulation of macrolides with polymers has been reported to retard the release of the drug in oral cavity. However, these methods are unable to control drug release in gastrointestinal tract. The aim of the present study was to investigate the effect of formulation of a new polymeric encapsulation of azithromycin which is suitable for both masking and sustained release usage. Eudragit E100 and polyethylene glycol (PEG) 4000 were chosen as the barrier coatings. The spray drying technique was used to obtain the microcapsules containing azithromycin. To obtain the initial results, the effects of several parameters were evaluated. A 3:2:1 ratio of E100:PEG 4000:azithromycin at pH 6 gave the best coating condition. Thermogravimetric analysis and IR analysis data confirmed the encapsulation of azithromycin inside polymers. The encapsulated drug was released in different rates from the particles by changing the pH (1.7 and 7.4). An analysis of the kinetic release properties indicates that the release of the drug is a combination of swelling and diffusion mechanism. The synergistic cooperation between polymers and drug due to the existence of several hydrogen bonding is supposed to influence the pH-responsive property of the encapsulated drug. Moreover, the use of mixtures of E100 and PEG 4000 appears to offer a good balance between cost and efficiency. 相似文献
97.
Hasan Ali Rayat Azimi Majid Zarei Amir Rafati Mohammad Noormohammadi 《Journal of Porous Materials》2016,23(2):357-363
A hard anodization (HA) technique is employed using different mixtures of phosphoric/oxalic acid for fast fabrication of alumina nanopore arrays in voltages higher than 200 V. The mixtures enable to avoid the breakdown of porous anodic alumina (PAA) in the high voltages. It is revealed for the first time that continuously tunable pore intervals (Dint) from 500 to 750 nm can be controlled by varying the concentrations of oxalic acid at anodization voltages (Uanod) from 230 to 360 V, far beyond the Uanod in the single electrolyte of phosphoric acid or oxalic acid. The ratios of interpore distance, pore diameter and barrier layer thickness to anodization voltage are in the range of conventional HA process for each acid mixture. In this approach, the PAA film growth rate is 26 µm/h, being 7 times larger than that in typical mild anodization. 相似文献
98.
The optimal design for heat recovery steam generator (HRSG) should be chosen based on technical and economic considerations. Therefore, parameters that are related to thermodynamic and economic aspects should be considered in optimization approaches. It is worth mentioning that one of the significant issues in the HRSG design is the diversity of arrangements between various components (economizer, evaporator, and superheater), which absolutely affect the HRSG performance. According to these facts, in the present article, different arrangements of a dual pressure HRSG are analyzed, and the economizer at the high‐pressure level is divided into two parts; these arrangements are optimized by applying different optimization approaches to achieve the optimal configuration. These approaches include the reduction of gas pressure drop, the reduction of generated steam cost and the consideration of both approaches as the third approach. These three approaches are also considered to perform economic and thermodynamic optimization. With regard to the limitations of optimization such as the pinch and approach point, seven different configurations are considered. First, a comprehensive model is developed for calculating thermodynamic, heat transfer, and pressure loss. To perform a thorough optimization, both thermodynamic and geometric variables as well as diversity of various arrangements is considered using genetic algorithm. The results of the optimization study show that the best arrangement is not unique, and each arrangement has different characteristics. Hence, the best arrangement for the HRSG is chosen according to the importance of the objective functions. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
99.
Seyed Hamed Aboutalebi Mohsen Moazzami Gudarzi Qing Bin Zheng Jang‐Kyo Kim 《Advanced functional materials》2011,21(15):2978-2988
A novel process is developed to synthesize graphene oxide sheets with an ultralarge size based on a solution‐phase method involving pre‐exfoliation of graphite flakes. Spontaneous formation of lyotropic nematic liquid crystals is identified upon the addition of the ultralarge graphene oxide sheets in water above a critical concentration of about 0.1 wt%. It is the lowest filler content ever reported for the formation of liquid crystals from any colloid, arising mainly from the ultrahigh aspect ratio of the graphene oxide sheets of over 30 000. It is proposed that the self‐assembled brick‐like graphene oxide nanostructure can be applied in many areas, such as energy‐storage devices and nanocomposites with a high degree of orientation. 相似文献
100.
Roozbeh Javad Kalbasi Majid Kolahdoozan Keinaz ShahabianFarzad Zamani 《Catalysis communications》2010,11(14):1109-1115
This work is concerned about the preparation and characterization of MnO4− supported poly (4-methyl vinylpyridinium)/SBA-15 which was effectively employed as a heterogeneous oxidant for oxidation of aromatic alcohols. P4MVPMnO4/SBA-15 exhibited excellent activity and selectivity under mild and solvent-less conditions. 相似文献