Effects of LiAl-layered double hydroxides on early hydration of calcium sulphoaluminate cement paste

As a 3D micro-nano material, layered double hydroxides have been widely used in many fields, especially for reinforced composite materials. In this paper, LiAl-LDHs was obtained by a hydrothermal method. In order to investigate the effects of LiAl-LDHs on the early hydration of calcium sulphoaluminate (CSA) cement paste, compressive strength, setting time and hydration heat were tested while X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scaning electron microscopy (SEM) and differential scanning calorimetry (DSC) analysis were employed. The results indicated that LiAl-LDHs could significantly improve the early compressive strength and shorten the setting time of calcium sulphoaluminate cement paste with 3wt% concentration. Besides, the hydration exothermic rate within 5 h was accelerated with increasing LiAl-LDHs content. Moreover, the addition of LiAl-LDHs did not result in the formation of a new phase, but increased the quantity of hydration products providing higher compressive strength, shorter setting time and denser microstructure.     

Preparation and performance research of cement-based grouting materials with high early strength and expansion

Main performance of the cement grouting materials made up by Portland cement(PC) and sulphoaluminate cement(SAC) was investigated in this program, a kind of expanding agent(EA) which was mainly constituted by metakaolin and alunite was utilized for the compensation of the shrinkage, the hydration products and micro structure of the grouting materials were researched by X-ray diffraction(XRD) and scanning electron microscopy (SEM). The results showed that a high expansion rate of the grouting materials could be reached as the expanding agent mixed in 6% of PC mass; the addition of SAC in the S2(PC:SAC:EA=34:6:2.25) brought a further improvement of the expansion rate of the grouting materials, the analysis of XRD and SEM showed that due to the reaction of expanding agent and SAC in the grouting materials, more ettringite crystal was generated, which resulted in a higher early strength, the addition of SAC played an expansion and strength reinforcement role in the grouting materials.     

Inter-comparative study of quantitative methods of industrial clinker

Impurities from the raw materials, the grinding and the homogenization of the raw materials, the kiln instability and the complexity of the cooling step, all these factors make it difficult to obtain a perfect evaluation of the mineralogical composition of Portland clinker. We studied the limitations of the most commonly used quantitative methods and recommend some procedures to obtain reliable and reproducible results of quantitative analyses. Different clinker samples (provided by the Bizerte Cement Company (Tunisia)) were subjected to an elemental analysis by X-ray fluorescence and the mineralogical composition was determined by the Bogue calculation and by X-ray powder diffraction combined with the Rietveld method (Different softwares were used: XPert High Score Plus version 2.0 and TOPAS version 4.2). We then compared the results obtained by the Rietveld method and the Bogue calculation to the specific peak areas of each phase. The content of each phase, determined by the Rietveld method, varied proportionally to the change in peak area; a significant difference in these results was found by using the elementary Bogue calculation.     

Synthesis of HTPB based PU-PS IPN membrane for pervaporation recovery of butanol

Hydroxyl terminated polybutadiene(HTPB) based polyurethane(PU)-polystyrene(PS) interpenetrating polymer network(IPN) was prepared and characterized by FTIR, TGA, WCA, swelling experiments, and SEM. The IPN was used for pervaporation(PV) recovery of butanol. Both the permeation flux and separation factor increased with feed temperature, and both water and butanol fluxes increased with feed concentration while no obvious effect of concentration on separation factor was found. Through the formation of IPN structure, the total flux of HTPB based PU increased greatly with the decrease of separation factor. At the feed temperature of 60 °C, the IPN membrane obtained a total flux of 613.3 g/m~2 h with a separation factor of 6.15.     

A new way of strengthening and toughening for carbon fiber reinforced polyphenylene sulfide (CF/PPS) composites via matrix modification

The effect of pressure-induced flow(PIF) processing on the mechanical properties of noncontinuous carbon fiber(CF) reinforced polyphenylene sulfide(PPS) composites was investigated. A series of CF/PPS composites under different processing conditions were prepared through PIF-processing. SEM observations showed that the interfaces adhesion between CFs and PPS became stronger and ductile fracture mainly occurred in PPS matrix. This brought to a great increase of both strength and toughness by about 2 folds, when the composites were processed at 240 ℃ and under 263 MPa. The results in differential scanning calorimetry(DSC) and X-ray diffraction(XRD) measurements indicated more regular crystalline structures and orientation of lamellae formed during PIF-processing.     

Effect of fly ash on drying shrinkage of thermal insulation mortar with glazed hollow beads

Drying shrinkage of thermal insulation mortar with glazed hollow beads was measured by a vertical length comparator, and the influences of fly ash with different contents (0, 18%, 36%, and 54% were used) on the long-term drying shrinkage were discussed. The mass loss was measured by the weighting method and the pore structure was characterized using three different methods, including the light microscopy, the mercury intrusion porosimetry (MIP), and the nitrogen adsorption/desorption (NAD) experiments, and the correlations among them were researched. The results show that drying shrinkage process of thermal insulation mortar includes three steps with increasing curing time: the acceleration period (before 7 d), the deceleration period (7-365 d), and the metastable period (after 365 d). Drying shrinkage in the first stage (7 d before) increases quickly owing to the fast water loss, and its development in the last two stages is attributed to the increment of the pore volume of mortar with the radius below 50 nm, especially the increment of the pore volume fraction of the pore radius within the size range between 7.3 nm and 12.3 nm. There is no change in the drying shrinkage development trend of mortar with fly ash addition, and three steps in the service life, but fly ash addition in the mortar restrains its value. There is a linear relationship between the drying shrinkage and fly ash content, which means that drying shrinkage reduces with fly ash addition.     

Growth and characterization of indium doped zinc oxide films sputtered from powder targets

Indium doped Zn O films were grown on quartz glass substrates by radio frequency magnetron sputtering from powder targets. Indium content in the targets varied from 1at% to 9at%. In doping on the structure, optical and electrical properties of Zn O thin films were studied. X-ray diffraction shows that all the films are hexagonal wurtzite with c-axis perpendicular to the substrates. There is a positive strain in the films and it increases with indium content. All the films show a high transmittance of 86% in the visible light region. Undoped Zn O thin film exhibits a high transmittance in the near infrared region. The transmittance of indium doped Zn O thin films decreases sharply in the near infrared region, and a cut-off wavelength can be found. The lowest resistivity of 4.3×10~(-4) Ω·cm and the highest carrier concentration of 1.86×10~(21) cm~(-3) can be obtained from Zn O thin films with an indium content of 5at% in the target.     

Efficiency analysis and optimization of wireless power transfer system for freely moving biomedical implants

In the wireless power transfer system for freely moving biomedical implants,the receiving unit was generally inefficient for the reason that its design parameters including the receiving coil's dimension and receiving circuits' topology were always determined by experiments.In order to build the relationship between these parameters and the total transfer efficiency,this paper developed a novel efficiency model based on the impedance model of the coil and the circuit model of the receiving circuits.According to the design constraints,the optimal design parameters in the worst case were derived.The results indicate that the combination of the two-layered receiving coil and half-bridge rectifier has more advantages in size,efficiency and safety,which is preferred in the receiving unit.Additionally,when the load resistance increases,the optimal turn number of the receiving coil basically keeps constant and the corresponding transmitting current and total efficiency decrease.For 100 Ω load,the transmitting current and total efficiency in the worst case were measured to be 5.30 A and 1.45% respectively,which are much better than the published results.In general,our work provides an efficient method to determine the design parameters of the wireless power transfer system for freely moving biomedical implants.     

Overall efficiency optimization of controllable mechanical turbo-compounding system for heavy duty diesel engines

A controllable mechanical turbo-compounding (CMTC) system including continuously variable transmission (CVT) and power turbine bypass valve is proposed to recover waste heat from engine exhaust. The combined matching principle considering swallowing capacity of both charging turbine and power turbine, main gear ratio is investigated at first based on the analysis of individual influence. Then the effects and strategies of CVT and power turbine bypass valve are studied for better performance under off-design conditions. At last, the transient response of intake pressure of engine with CMTC system is researched and the fuel saving potential is tested under driving cycle conditions. The results indicate that the overall fuel efficiency elevates at the off-design conditions if CVT is adopted due to the improvement of power turbine operating efficiency by speed modulation. The diversion of exhaust through power turbine bypass valve under the low load condition is necessary. The back pressure of the charging turbine infuences the transient response of intake pressure for a fixed CMTC configuration. A method featured by the assistance of power turbine bypass valve is tested to improve the transient response of the intake pressure. The fuel consumption reduces by 2% and 3.4% under highway fuel economy test (HWFET) and Tianjin 503 (TJ503) driving cycles respectively.     

Load identification in one dimensional structure based on hybrid finite element method

The new hybrid elements are proposed by combing modified Hermitian wavelet elements with ANASYS elements. Then hybrid elements are substituted into finite element formulations to solve the load identification. Transfer matrix can be constructed by using the inverse Newmark algorithm and hybrid finite element method. Loads can obtain through the responses and the transfer matrix. Load identification law was studied under different excitation cases in rod and Timoshenko beam. Regularization method is adopted to solve ill-posed inverse problem of load identification. Compared with ANSYS results, hybrid elements and HCSWI elements can accurately identify the applied load. Numerical results show that the algorithm of hybrid elements is effective. The accuracy of hybrid elements and HCSWI elements can be verified by comparing the load identification result of ANASYS elements with the experiment data. Hermitian wavelet finite element methods have high accuracy advantage but it is difficult to apply the engineering practice. In practical engineering, complex structure can be analyzed by using the hybrid finite element methods which can be obtained the high accuracy in the crucial component.