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排序方式: 共有2198条查询结果,搜索用时 15 毫秒
71.
Beata Tryba Antoni W. Morawski Michio Inagaki Masahiro Toyoda 《Applied catalysis. B, Environmental》2006,63(3-4):215-221
H2O2 used in the photo-Fenton reaction with iron catalyst can accelerate the oxidation of Fe2+ to Fe3+ under UV irradiation and in the dark (in the so called dark Fenton process). It was proved that conversion of phenol under UV irradiation in the presence of H2O2 predominantly produces highly hydrophilic products and catechol, which can accelerate the rate of phenol decomposition. However, while H2O2 under UV irradiation could decompose phenol to highly hydrophilic products and dihydroxybenzenes in a very short time, complete mineralization proceeded rather slowly. When H2O2 is used for phenol decomposition in the presence of TiO2 and Fe–TiO2, decrease of OH radicals formed on the surface of TiO2 and Fe–TiO2 has been observed and photodecomposition of phenol is slowed down. In case of phenol decomposition under UV irradiation on Fe–C–TiO2 photocatalyst in the presence of H2O2, marked acceleration of the decomposition rate is observed due to the photo-Fenton reactions: Fe2+ is likely oxidized to Fe3+, which is then efficiently recycled to Fe2+ by the intermediate products formed during phenol decomposition, such as hydroquinone (HQ) and catechol. 相似文献
72.
Yunosuke Abe Toshiki Aoki Hongge Jia Shingo Hadano Takeshi Namikoshi Yuriko Kakihana Lijia Liu Yu Zang Masahiro Teraguchi Takashi Kaneko 《Polymer》2012,53(11):2129-2133
A soluble and stable one-handed helical conjugated polymer without the coexistence of any other chiral moieties was successfully synthesized by asymmetric-induced polymerization of a chiral monomer having two hydroxyl groups followed by desubstitution of the chiral groups in a solid membrane state. The reason for the success was the polymer reaction was carried out in the membrane state. This is an alternative method to obtain such a unique chiral polymer which was obtained only by the helix-sense-selective polymerization (HSSP) we reported before. In addition the efficiency of the chiral induction was higher than that of the HSSP. It is interesting that the “Membrane state” acted like as if a protecting group. 相似文献
73.
Koji Fushimi Takatoshi Shimada Hiroki Habazaki Hidetaka Konno Masahiro Seo 《Electrochimica acta》2011,(4):1773
Depassivation–repassivation of iron surfaces in boric–borate solutions were investigated by using the micro-indentation test. A pair of current peaks due to repair of the passive film following rupture of the film were observed during a series of indenter drives, i.e., loading and unloading of the indenter. The shape of the current peak depended on environmental conditions (conductivity and pH of the solution) and substrate conditions (mechanical processing history, alloyed element) as well as indentation conditions (repetition, maximum depth, and maximum load). Plastic deformation of the surface was accompanied by surface depassivation, while no depassivation occurred during the elastic deformation, indicating that the passive film on iron has a ductile property. The solution conditions did not affect the scale of depassivation but affected the rate of repassivation. Dislocations in the substrate made surface depassivation difficult but enhanced reactivity during the repassivation. The test also revealed that type-312L stainless steel has high corrosion resistance in a concentrated NaCl solution. 相似文献
74.
Diamond-like-carbon (DLC) coating of thickness 3 and 10 μm were developed with and without radical nitriding pretreatment on steel rollers and spur gear pair. The friction coefficient and wear amount were evaluated under sliding rolling contact condition in vacuum and under oil lubrication. Delamination of coatings was observed at the interface of the substrate. The wear resistance of coatings improved with the thickness of the coating. In vacuum both the roller and the gear pair of 10 μm coating thickness with radical nitriding showed identical wear behavior. The radical nitriding seemed to enhance the life of DLC coatings. 相似文献
75.
76.
Kanokwan Srirattana Masahiro Kaneda Rangsun Parnpai 《International journal of molecular sciences》2022,23(4)
Mammalian oocytes can reprogram differentiated somatic cells into a totipotent state through somatic cell nuclear transfer (SCNT), which is known as cloning. Although many mammalian species have been successfully cloned, the majority of cloned embryos failed to develop to term, resulting in the overall cloning efficiency being still low. There are many factors contributing to the cloning success. Aberrant epigenetic reprogramming is a major cause for the developmental failure of cloned embryos and abnormalities in the cloned offspring. Numerous research groups attempted multiple strategies to technically improve each step of the SCNT procedure and rescue abnormal epigenetic reprogramming by modulating DNA methylation and histone modifications, overexpression or repression of embryonic-related genes, etc. Here, we review the recent approaches for technical SCNT improvement and ameliorating epigenetic modifications in donor cells, oocytes, and cloned embryos in order to enhance cloning efficiency. 相似文献
77.
Masahiro Takahashi Yutaka Kimura Mitsuki Hagiwara Keiki Kishikawa Shigeo Kohmoto 《Synthetic Metals》2011,161(15-16):1557-1562
Improved synthesis and reinvestigation of the magnetic properties of triphenylamine bearing three nitronylnitroxide radicals (1) were carried out. Single crystal X-ray crystallographic analysis of 1 established that its molecular shape had a C3-symmetry. Our newly prepared 1 showed different physical properties from those of reported. SQUID measurements of 1 showed that each of the three spins of 1 behaved independently at room temperature. In contrast, the three spins coupled antiferromagnetically at lower temperature as low as ca. 1.8 K. These spin behaviors can be explained by a regular triangular antiferromagnetic model (J/kB = ?3.3 K) and interpreted as a spin frustration system. 相似文献
78.
Kiyoharu Nakagawa Hirokazu Oda Akira Yamashita Masahiro Okamoto Yoichi Sato Hidenori Gamo Mikka Nishitani-Gamo Kazuyuki Ogawa Toshihiro Ando 《Journal of Materials Science》2009,44(1):221-226
We developed a novel spherical carbon material. The spherical carbon is composed of a high density of carbon nanotubes or
nanofilaments, and includes an oxidized diamond particle as a core. Syntheses of this carbon in high volume with high selectivity
may be possible. It is expected that this carbon will be useful as a catalyst material for fuel cells, electric double-layer
capacitors, etc. 相似文献
79.
Konosuke Nishida Yasuo Yanagibashi Masahiro Osako 《The International journal of environmental studies》2013,70(3):237-249
The adoption of the sensory odor test will prevail widely in many local self governments in Japan in order to evaluate and regulate the complex odor in fields. This is also done by the tri‐angle choice bag test. However, this procedure has several problems in the reliability and reproducibility of the results obtained. It is desired to solve these problems by the mechanization of the method. From this point of view, an experimental study on the flow rate of test odor has been carried out and the results obtained are described in this paper. It is confirmed that the optimum flow rate of test odor is about 41/min at the inlet of the mask in the dynamic sniffing method. 相似文献
80.
Huan-Bang Li Takashi Takahashi Masahiro Toyoda Yasuyuki Mori Ryuji Kohno 《Wireless Personal Communications》2009,51(4):697-709
Wireless Body Area Network (WBAN) is expected to play an important role in supporting medical and healthcare services with
increased convenience and comfort. One main advantage of WBAN is that it enables automatic biosignal collection in real time
which is essential in medical treatment and healthcare vigilance. To harmonize with the strong demands from both medical and
healthcare societies, and information and communications technology industries, IEEE 802 Standard Committee set up a task
group of TG15.6 to develop an IEEE wireless standard on WBAN. In this paper, we first review the main activities of TG15.6
with the updated status. Then, we present a prototype WBAN system that is implemented by using ultra-wideband technology.
Multi-hop mechanism is adopted to guarantee reliable connection. Finally, we describe an experimental system that uses the
developed WBAN system by combining with satellite communication in supporting remote medical treatment and healthcare. In
case of less of medical resources such as in emergency, in rural or isolated areas, such a system is important in sending
the corresponding biosignal to a remote hospital in real time to help patient management. The relative delay of WBAN data
delivery via satellite is measured which is dependent on the satellite link capacity. 相似文献