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21.
Circular data are those for which the natural support is the unit circle and its toroidal extensions. Numerous constructions have been proposed which can be used to generate models for such data. We propose a new, very general, one based on the normalization of the spectra of complex-valued stationary processes. As illustrations of the new construction's application, we study models for univariate circular data obtained from the spectra of autoregressive moving average models and relate them to existing models in the literature. We also propose and investigate multivariate circular models obtained from the high-order spectra of stationary stochastic processes generated using linear filtering with an autoregressive moving average response function. A new family of distributions for a Markov process on the circle is also introduced. Results for asymptotically optimal inference for dependent observations on the circle are presented which provide a new paradigm for inference with circular models. The application of one of the new families of spectra-generated models is illustrated in an analysis of wind direction data. 相似文献
22.
Direct Formation of Crystalline Gadolinium-Doped Ceria Powder via Polymerized Precursor Solution 总被引:2,自引:0,他引:2
Shuqiang Wang Kunihiro Maeda Masanobu Awano 《Journal of the American Ceramic Society》2002,85(7):1750-1752
Synthesis of Ce0.9 Gd0.1 O1.95 (CGO) powder from a polymeric precursor solution containing a mixture of nitrates, nitric acid, and ethylene glycol was investigated with emphasis on the effect of polymerization of the precursor solution on the crystallization and morphology of the derived solid intermediate and the final oxide powder. It is shown for the first time in this work that the solid intermediate derived from the polymerized solution is present in the form of well-crystallized cerium-gadolinium formate solid solution, Ce1− x Gd x (HCOO)3 , exhibiting anisotropic growth. Further polymerization of the precursor solution resulted in the direct formation of loosely agglomerated nanoscaled CGO oxide powder from the polymerized solution at temperatures as low as 130°C. 相似文献
23.
Hyunjeong Kim Kouji Sakaki Itoko Saita Hirotoshi Enoki Kazuo Noguchi Akihiko Machida Tetsu Watanuki Yumiko Nakamura 《International Journal of Hydrogen Energy》2014
The effect of the vanadium content on the cyclic stability of V–Ti binary alloys was investigated. V1−xTix, x = 0.2 and 0.5 samples were hydrogenated and dehydrogenated at 410 K and 553 K respectively, for more than 100 times. During hydrogen cycling, reduction in the reversible hydrogen storage capacity was clearly observed from both samples. No prominent V-effect was found. In fact, the reduction rates of two samples were similar; both samples showed a ∼25% reduction in the reversible hydrogen storage capacity after 100 cycles. In addition, the shape of the pressure–composition-isotherm (PCT) curves was significantly altered over the testing cycle period; the absorption and desorption plateaus got markedly inclined and the hysteresis became evidently smaller. We found that even after the hydrogen storage capacity of V1−xTix was significantly reduced, at low enough temperature V1−xTix was able to absorb hydrogen as much as it did at the first cycle. Furthermore, the reversible hydrogen storage capacity of V0.8Ti0.2 at 410 K was recovered to a certain degree after hydrogenating the sample at low temperatures. 相似文献
24.
25.
Moriwaki H Takagi Y Tanaka M Tsuruho K Okitsu K Maeda Y 《Environmental science & technology》2005,39(9):3388-3392
Perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) are shown to be globally distributed, environmentally persistent, and bioaccumulative. Although the toxicities of these compounds were reported, the cleanup procedure from the environment is not developed because of their inertness. In this report the sonochemical degradations of PFOS and PFOA to the products through the fission of the perfluorocarbon chains were observed and the half-life times of the PFOS and PFOA degradations under an argon atmosphere determined to be 43 and 22 min, respectively. The shortening of perfluorocarbon chain of PFOS and PFOA leads to the lowering of the toxicity in view of the decrease of the persistence, and the technique would contribute to the remediation of the environmental pollution by these compounds. 相似文献
26.
In this paper, we consider the estimation of the coefficient of a stochastic regression model whose explanatory variables and disturbances are permitted to exhibit short-memory or long-memory dependence. Three estimators of the coefficient are proposed. A variety of their asymptotics are illuminated under various assumptions on the explanatory variables and the disturbances. Numerical studies of the theoretical results are given. They show some unexpected aspects of the asymptotics of the three estimators. 相似文献
27.
28.
T. Kato H. Funahashi H. Nakamura M. Fujimoto T. Machida H. Sakata S. Nakao T. Hasegawa 《Journal of Superconductivity and Novel Magnetism》2010,23(5):771-773
We have performed low-temperature scanning tunneling spectroscopy on overdoped Bi2Sr2−x
La
x
CuO6+δ
(x=0.1 and 0.2) at 4.2 K. The tunneling spectra in both samples obviously exhibit two energy gaps: one has clear gap structure
with sharp gap edge peaks, and another is observed as kinks inside the larger gap. Both the energy gaps inhomogeneously vary
on the surface at nanometer scale, and their values positively correlate each other. The distributions of both gaps normalized
to the mean values are identical independent of the doping level. These results suggest that the two gaps are commonly affected
by the source of the electronic disorder. 相似文献
29.
Presently, it has become an urgent and important concern worldwide to reduce the volume of waste and rationally use the waste for electric power generation. Sludge is a dominant part in the family of wastes. Drying of sludge, not only for volume reduction but also for further utilization, is becoming an essential and integral process. On the other hand, as the requirement of new materials production, for example, fine particles of micron or sub-micron scale for advanced materials, some new drying technologies and techniques have emerged. The market-pull may be the direct and active impetus to drying research and development (R&D). In this paper, drying technologies for sludges, fine particles, coatings as well as advanced dewatering are discussed to reflect the “hot” points of drying and dewatering R&D in Japan. And some novel dryers are also presented. 相似文献
30.
KyoungHou Kim Ryo Aida YoungAh Kang Yutaka Ohkoshi Yasuo Gotoh Masanobu Nagura Hiroshi Urakawa 《Polymer》2009,50(19):4429-4431
The structure development in the continuous laser-heated drawing process of poly(ethylene 2,6-naphthalene dicarboxylate) (PEN) fiber was analyzed by in-situ X-ray diffraction measurement. Because of the rapid and uniform laser heating, and the resultant steady-state nature of the necking-drawing, the structure development after the on-set of necking could be measured in the time resolution of several hundred microseconds. We found for the first time the temporal appearance of meridional (001′) diffraction at several milliseconds after the on-set of necking indicating that the mesophase structure similar to the one reported for poly(ethylene terephthalate) was also formed in the initial stage of fiber structure development of PEN. The d-spacing of the (001′) diffraction 1.230 ± 0.003 nm was shorter than the c-axis lengths of both α and β crystals. 相似文献