Effects of thiol additives on urethane acrylate UV primers for SMC applications

Sheet molded compound (SMC) is a highly filled, glass fiber reinforced, thermoset material used in trim and body panel automotive parts. When SMC-substrates are coated with conventional thermally cured paints, inherent porosity and entrapped volatiles of the substrate result in popping (“paint pops”) defects. UV-curable primers (UVP) provide an order of magnitude reduction of paint defects in SMC coatings, but typically have poor adhesion. Mercaptan polymers have a long history, dating back to 1928, of use in adhesives and sealant applications. The present study investigates a series of UVPs, showing the effect of resin functionality and thiol functional additive content on the adhesion of the coatings to SMC substrates. The SMC formulation is also considered when evaluating UVP adhesion, regarding variables such as surface chemistry, morphology, and surface area. The present study brings to light how adhesion of acrylate UVP can be enhanced with mercaptan moieties in additive amounts. The effect is most apparent on SMC substrates that have been treated to expose inorganic fillers as opposed to untreated surfaces of polyester. Additionally annealing the films boosts adhesion, but only in thiol containing formulations. This is a result of the decrease in T_gs and modulus of the films with the addition of mercaptans, thus providing better contact with the substrate in comparison to non-thiol containing formulations.     

Eccentric Circumferential Cracks in Cylindrical Specimens

The effect of eccentricity on the stress intensity factors for circumferential cracks in cylindrical specimens subjected to torsional and axial loading is studied. BEM solutions are compared with proposed approximate methods and some agreement is found for the axial load cases. A simple method of how the eccentricity develops under axial loading as the crack grows is presented. It shows that the eccentricity accelerates as the crack grows and that the problem thereby can be characterized as unstable.     

Highly reflective coatings for interior and exterior steel cladding and the energy efficiency of buildings

The effect of surface heat-radiation properties of coil-coated steel cladding material on the energy efficiency of buildings in Nordic climate is addressed by parallel temperature and energy usage measurements in a series of test cabins with different exterior solar reflectivity and interior thermal reflectivity. During one year, a number of one- or two-week experiments with air conditioner cooling and electrical floor heating were made while logging air-, radiation- and surface temperatures, energy consumption and weather conditions. Measurements show significant energy savings in the test cabins by the use of high thermal reflectivity interior surfaces both during heating and cooling and a strongly reduced cooling demand by the use of high solar reflectivity exterior surfaces. Results are interpreted within the context of a steady-state energy flux model, to illuminate the importance of surface resistance properties (radiation and convective heat dissipation).     

ANN modeling applied to NO x reduction with octane in a new microreactor

A silver/alumina catalyst was tested for its NO _x reduction activity during oxygen-rich conditions and during variation in the input parameters (nitric oxide, octane and oxygen). The experimental data using the microreactor was investigated by means of artificial neural networks (ANN).     

An assessment of the CaO-SiO2 system

An evaluation of the CaO-SiO₂ system has been made using a newly developed model, a two-sublattice model for ionic solutions. Two alternatives were tested. In the first one, three anions were assumed, O⁻², SiO₄ ⁻⁴, and SiO₃ ⁻². In the second one, SiO₃ ⁻² was omitted. A set of parameter values describing the Gibbs energy of the liquid phase and solid phases was fixed for each alternative by a computer-operated optimization procedure called PARROT. Satisfactory assessments were achieved over the whole phase diagram range with both alternatives. The main difference between them occurs at the monotectic point. A comparison between calculated properties and experimental data is given. Formerly Research Associate, Royal Institute of Technoloy     

Human fear conditioning is related to dopaminergic and serotonergic biological markers.

Biological markers for acquisition and extinction of fear conditioning were studied in 40 individuals selected for displaying either good or poor acquisiton of fear conditioning, as estimated by the skin conductance response. Participants with a short serotonin transporter (5-HTT) promoter allele or low monoamine oxidase activity in platelets (trbc-MAO) displayed better acquisition than those with only long alleles or high trbc-MAO, whereas participants with a long dopamine D4 receptor (D4DR) exon III allele showed delayed extinction compared with those with only short alleles. The findings, that D4DR exon III and 5-HTT promotor genotypes and trbc-MAO activity are related to human fear conditioning, a basic form of associative learning, are consistent with animal studies suggesting a genetic contribution to fear conditioning. The authors suggest that in humans these genetic mechanisms are partly dopaminergic and serotonergic in origin. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Monitoring struturants of fat blends with ultrasound based in‐line rheometry (ultrasonic velocity profiling with pressure difference)

Ultrasonic velocity profiling with pressure difference (UVP‐PD) was demonstrated to be a successful, non‐invasive, in‐line measurement system for instantaneous velocity and rheological flow profiling of complex, opaque fat blends. Model systems of 25% Akomic, 75% rapeseed oil; and 25% Akomic, 74% rapeseed oil and 1% Grindsted^® Crystalliser 110 were compared under real process conditions with UVP‐PD. Results indicated that the sample containing the crystalliser had twice the viscosity of the control. These in‐line results are in agreement with previous off‐line results, and offer the chance to probe the mechanics of fat blend physics under real, dynamic conditions.     

Practical Construction and Analysis of Pseudo-Randomness Primitives

We give a careful, fixed-size parameter analysis of a standard (Blum and Micali in SIAM J. Comput. 13(4):850–864, 1984; Goldreich and Levin in Proceedings of 21st ACM Symposium on Theory of Computing, pp. 25–32, 1989) way to form a pseudo-random generator from a one-way function and then pseudo-random functions from said generator (Goldreich et al. in J. Assoc. Comput. Mach. 33(4):792–807, 1986) While the analysis is done in the model of exact security, we improve known bounds also asymptotically when many bits are output each round and we find all auxiliary parameters efficiently, giving a uniform result. These optimizations makes the analysis effective even for security parameters/key-sizes supported by typical block ciphers and hash functions. This enables us to construct very practical pseudo-random generators with strong properties based on plausible assumptions.     

Characterization of Ce0.9Gd0.1O1.95 powders synthesized by spray drying

Ce_0.9Gd_0.1O_1.95 powders were synthesized by spray drying and successive calcinations. The phase purity, BET surface area, and particle morphology of as-sprayed and calcined powders were characterized. After calcination above 300 °C, the powders were single phase and showed a BET surface area of 68 m²/g when calcined at 300 °C. The conductivity, in air, of sintered pellets was measured by electrochemical impedance spectroscopy (EIS) and it was found to be comparable with literature values. The activation energy for the total conductivity was around 0.83 eV. The powder calcined at lower temperature showed better sinterability and higher total conductivity due to an increased bulk conductivity.