全文获取类型
收费全文 | 1179篇 |
免费 | 73篇 |
专业分类
电工技术 | 24篇 |
化学工业 | 397篇 |
金属工艺 | 36篇 |
机械仪表 | 36篇 |
建筑科学 | 37篇 |
能源动力 | 30篇 |
轻工业 | 52篇 |
水利工程 | 3篇 |
石油天然气 | 3篇 |
武器工业 | 1篇 |
无线电 | 86篇 |
一般工业技术 | 220篇 |
冶金工业 | 104篇 |
原子能技术 | 8篇 |
自动化技术 | 215篇 |
出版年
2023年 | 10篇 |
2022年 | 59篇 |
2021年 | 88篇 |
2020年 | 39篇 |
2019年 | 40篇 |
2018年 | 45篇 |
2017年 | 39篇 |
2016年 | 38篇 |
2015年 | 49篇 |
2014年 | 55篇 |
2013年 | 84篇 |
2012年 | 70篇 |
2011年 | 70篇 |
2010年 | 65篇 |
2009年 | 67篇 |
2008年 | 39篇 |
2007年 | 51篇 |
2006年 | 44篇 |
2005年 | 24篇 |
2004年 | 24篇 |
2003年 | 20篇 |
2002年 | 25篇 |
2001年 | 4篇 |
2000年 | 11篇 |
1999年 | 6篇 |
1998年 | 17篇 |
1997年 | 19篇 |
1996年 | 16篇 |
1995年 | 11篇 |
1994年 | 13篇 |
1993年 | 15篇 |
1992年 | 9篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 7篇 |
1988年 | 5篇 |
1987年 | 8篇 |
1986年 | 6篇 |
1985年 | 4篇 |
1984年 | 6篇 |
1983年 | 4篇 |
1981年 | 10篇 |
1980年 | 5篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1976年 | 10篇 |
1974年 | 1篇 |
1969年 | 1篇 |
1966年 | 1篇 |
1953年 | 1篇 |
排序方式: 共有1252条查询结果,搜索用时 46 毫秒
51.
Synthesis of trimethylene carbonate/ϵ‐caprolactone copolymers initiated with zinc alkoxide: influence of copolymer chain microstructure on thermal and mechanical properties
下载免费PDF全文
![点击此处可从《Polymer International》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Malgorzata Pastusiak Piotr Dobrzynski Janusz Kasperczyk Michal Sobota Bozena Kaczmarczyk Henryk Janeczek 《Polymer International》2017,66(9):1259-1268
Ethylzinc(II ) ethoxide is a highly active and efficient initiator for the bulk polymerization of 1,3‐trimethylene carbonate and its copolymerization with ? ‐caprolactone. This initiator allows one to obtain (co)polymers with high molar masses in quite a short time. Significant difference in co‐monomer reactivity and relatively low participation of intermolecular transesterification processes lead to the obtained copolymers being characterized by a gradient chain microstructure. In 13C NMR spectra, in all regions, we observed the presence of triads which were distinctly represented by four peaks for the carbonyl signal. Mechanical tests showed that copolymers containing 70% and more of ? ‐caprolactone presented a relatively high Young's modulus and a very high maximum elongation factor; therefore these materials are promising in many biomedical applications. Due to the high reaction rate, we also made an attempt at copolymerization using reactive extrusion which gave promising results. © 2017 Society of Chemical Industry 相似文献
52.
We report on electron spin resonance (ESR) investigations of a FeVO4 single crystal. Temperature and angular dependences of ESR resonance positions were measured and calculated in temperature range of 35–100 K. The spectra show rich angular dependences of the linewidth, the shape and the resonance field. They consist of a single broad line with asymmetric distortion. Due to the low symmetry of the crystal lattice this distortion can be explained by taking into account the influence of non diagonal dynamic susceptibility. 相似文献
53.
The pin power density distribution in reactor is an important quantity, necessary for the adequate assessment of fuel conditions and of core structures and pressure vessel radiation embrittlement as well.The paper shows the detailed comparison of calculated and experimentally determined pin by pin power distribution. To verify the reliability of measured data used for comparison with calculated data, the symmetrically located pins were measured. The calculations have been done with deterministic and Monte Carlo approach. The effect of different data libraries used for calculations are discussed as well. 相似文献
54.
Insulating and Other Physical Properties of CoO‐Doped Zinc Oxyfluoride‐Borate Glass‐Ceramics
下载免费PDF全文
![点击此处可从《Journal of the American Ceramic Society》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Padamati Naresh Goli Naga Raju Yerramreddy Gandhi Michal Piasecki Nalluri Veeraiah 《Journal of the American Ceramic Society》2015,98(2):413-422
Zinc oxy fluoro borate glasses mixed with different concentrations of CoO (ranging from 0 to 2.0 mol%) are synthesized and subsequently crystallized. The scanning electron microscopy pictures have exhibited crystallinity. Differential scanning calorimetric studies have indicated that the prepared samples consist of multiple crystal phases. The X‐ray diffraction patterns have indicated that the glass‐ceramic samples are composed of αZn(BO2)2, (Zn)3(BO3)2, CoF2, CoF3, Co3FB7O13, ZnCo2O4, Co3O4 crystalline phases. The optical absorption and photoluminescence studies have indicated that there is a gradual increase of tetrahedral cobalt ion concentration with increase of CoO concentration in the glass network. IR spectroscopic studies have pointed out increased degree of polymerization of the zinc oxy fluoro borate glass network with increase of CoO content. The analysis of results of dielectric properties indicated increase of insulating strength of the glass‐ceramics with increase of CoO content. Finally, the dielectric breakdown strength of the samples is measured at room temperature in air medium and it is found to increase from 12.9 to 19.2 kV/cm with increase of CoO from 0.2 to 2.0 mol%. The reasons for such increase of breakdown strength are discussed quantitatively in terms of dielectric parameters with aid of data on spectroscopic properties. 相似文献
55.
56.
Roni Efrati Michal Natan Avishay Pelah Anina Haberer Ehud Banin Ana Dotan Amos Ophir 《应用聚合物科学杂志》2014,131(11)
Antimicrobial packaging can preserve and increase shelf life of free preservatives food products. Active materials present in the packaging material can migrate, in a controlled manner, to the food surface, avoiding bacterial and fungal proliferation and keeping the food product edible for longer periods of time. Essential oils (EO) are natural antimicrobial agents that can be released to the headspace with no direct contact between the package and the food. To minimize loses of EO during high heat melt processing, a three stages process was implemented and tested. Antimicrobial films were prepared by melt mixing a variety of polyethylene copolymers in the presence of organo‐modified montmorillonite nano clay (NC) and thymol, an EO present in oregano and thyme. A controlled EO desorption from films can be achieved by changing the polymer crystallinity and polarity. As the crystallinity increased, the thermal stability of the EO during the extrusion process improved. The addition of NC affects the structure and homogeneity of the crystals. The combination of high polymer crystallinity and chemical affinity between EO and NC increased the thermal stability of the EO during film processing, enabling to control the desorption rate. The effect of multilayer structure based on varied densities and polarities was also studied. Increasing the polarity of the outer layers in multilayered film reduced the EO desorption rate as a result of chemical interactions between the polymer and the EO. The final antimicrobial activity of the films was also found to be dependent on the EO partitioning. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40309. 相似文献
57.
Poly(acrylic acid) [poly(polypropenoic acid)] (PAA) can form stable and insoluble, colorless hydrogels with HfCl4, TiCl4, and ZrCl, in water. Two carboxylic groups of PAA are complexed by the M(OH)22+ ions. Hydrogels formed from PAA–MCl2,(OH)2, (where M = Hf, Zr) (2 : 1) have found practical application in the blocking of microscopic channels in tooth dentin, and thereby decrease the fluid permeability and protect against tooth decay. © 1996 John Wiley & Sons, Inc. 相似文献
58.
Aneta Sevcikova Nikola Izoldova Viola Stevurkova Barbora Kasperova Michal Chovanec Sona Ciernikova Michal Mego 《International journal of molecular sciences》2022,23(1)
Understanding the mechanisms of resistance to therapy in human cancer cells has become a multifaceted limiting factor to achieving optimal cures in cancer patients. Besides genetic and epigenetic alterations, enhanced DNA damage repair activity, deregulation of cell death, overexpression of transmembrane transporters, and complex interactions within the tumor microenvironment, other mechanisms of cancer treatment resistance have been recently proposed. In this review, we will summarize the preclinical and clinical studies highlighting the critical role of the microbiome in the efficacy of cancer treatment, concerning mainly chemotherapy and immunotherapy with immune checkpoint inhibitors. In addition to involvement in drug metabolism and immune surveillance, the production of microbiota-derived metabolites might represent the link between gut/intratumoral bacteria and response to anticancer therapies. Importantly, an emerging trend of using microbiota modulation by probiotics and fecal microbiota transplantation (FMT) to overcome cancer treatment resistance will be also discussed. 相似文献
59.
Tama Dinur Peter Bauer Christian Beetz Guido Kramp Claudia Cozma Marius-Ionu Iuracu Michal Becker-Cohen Majdolen Istaiti Arndt Rolfs Ari Zimran Shoshana Revel-Vilk 《International journal of molecular sciences》2022,23(3)
For years, the gold standard for diagnosing Gaucher disease (GD) has been detecting reduced β-glucocerebrosidase (GCase) activity in peripheral blood cells combined with GBA1 mutation analysis. The use of dried blood spot (DBS) specimens offers many advantages, including easy collection, the need for a small amount of blood, and simpler transportation. However, DBS has limitations for measuring GCase activity. In this paper, we recount our cross-sectional study and publish seven years of experience using DBS samples and levels of the deacylated form of glucocerebroside, glucosylsphingosine (lyso-Gb1), for GD diagnosis. Of 444 screened subjects, 99 (22.3%) were diagnosed with GD at a median (range) age of 21 (1–78) years. Lyso-Gb levels for genetically confirmed GD patients vs. subjects negative to GD diagnosis were 252 (9–1340) ng/mL and 5.4 (1.5–16) ng/mL, respectively. Patients diagnosed with GD1 and mild GBA1 variants had lower median (range) lyso-Gb1, 194 (9–1050), compared to GD1 and severe GBA1 variants, 447 (38–1340) ng/mL, and neuronopathic GD, 325 (116–1270) ng/mL (p = 0.001). Subjects with heterozygous GBA1 variants (carrier) had higher lyso-Gb1 levels, 5.8 (2.5–15.3) ng/mL, compared to wild-type GBA1, 4.9 (1.5–16), ng/mL (p = 0.001). Lyso-Gb1 levels, median (range), were 5 (2.7–10.7) in heterozygous GBA1 carriers with Parkinson’s disease (PD), similar to lyso-Gb1 levels in subjects without PD. We call for a paradigm change for the diagnosis of GD based on lyso-Gb1 measurements and confirmatory GBA1 mutation analyses in DBS. Lyso-Gb1 levels could not be used to differentiate between heterozygous GBA1 carriers and wild type. 相似文献
60.
Edyta Janik Marcin Niemcewicz Marcin Podogrocki Joanna Saluk-Bijak Michal Bijak 《International journal of molecular sciences》2021,22(11)
COVID-19 is a respiratory disease caused by newly discovered severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2). The disease at first was identified in the city of Wuhan, China in December 2019. Being a human infectious disease, it causes high fever, cough, breathing problems. In some cases it can be fatal, especially in people with comorbidities like heart or kidney problems and diabetes. The current COVID-19 treatment is based on symptomatic therapy, so finding an appropriate drug against COVID-19 remains an immediate and crucial target for the global scientific community. Two main processes are thought to be responsible for the COVID-19 pathogenesis. In the early stages of infection, disease is determined mainly by virus replication. In the later stages of infection, by an excessive immune/inflammatory response, leading to tissue damage. Therefore, the main treatment options are antiviral and immunomodulatory/anti-inflammatory agents. Many clinical trials have been conducted concerning the use of various drugs in COVID-19 therapy, and many are still ongoing. The majority of trials examine drug reposition (repurposing), which seems to be a good and effective option. Many drugs have been repurposed in COVID-19 therapy including remdesivir, favipiravir, tocilizumab and baricitinib. The aim of this review is to highlight (based on existing and accessible clinical evidence on ongoing trials) the current and available promising drugs for COVID-19 and outline their characteristics. 相似文献