Prediction of higher heating values for saturated fatty acids from their physical properties

Higher heating values (HHVs) of fatty acids (C₄–C₁₈) were measured and correlated using linear least square regression analysis. Equations were developed for the estimation of the HHVs of saturated fatty acids from their molecular weight (Mw), density (DN) and carbon number (CN). These equations are HHV = 0.0518 Mw + 29.76, HHV = −93.4 DN + 122.67 and HHV = 0.7271 CN + 31.419 with R² values of 0.9895, 0.9798, and 0.9895, respectively. The correlations may be used for HHV estimation of mixtures of fatty acids developed from vegetable oils.     

Fire performance of wood (Pinus radiata) treated with fire retardants and a wood preservative

In this work, we co‐formulated an oil‐borne copper naphthenate/permethrin wood preservative system with synthetic polymer‐based fire‐retardant additives prior to the impregnation of Pinus radiata sapwood. We evaluated what effect, if any, the preservative had upon the fire performance properties of the fire retardants and whether the fire retardants impacted on the fungicidal and termiticidal efficacy of the preservative. The fire retardants included halogenated and phosphorus‐based systems. A mass loss calorimeter, in conjunction with a thermopile, was used to measure the time to ignition and the peak heat release rate (PHRR) from which the fire performance index (FPI) was determined. The preservative properties were evaluated using termite and soil‐block decay bioassays. In summary, we found that the rate of fire growth was reduced when the fire retardants were used in combination with the wood preservative. We also found that the PHRR was a better determinant of fire performance than the FPI. The performance of the wood preservative was enhanced against fungal decay and termite attack when used in combination with the fire retardants. The fire retardants also demonstrated some wood preservative properties of their own. Copyright © 2008 John Wiley & Sons, Ltd.     

Fire evacuation skills: Cognitive-behavioral versus computer-mediated instruction

Fifty-six fourth-grade children participated in this study to assess three training procedures for relative effectiveness in acquiring fire emergency skills and attaining knowledge. The first training approach was behavioral, the second used animated graphics, and the third used still graphics. Each of the training groups was compared to a control group that received no treatment. Performance on dependent measures was assessed before and immediately after training. It was hypothesized that the behavioral and animated-graphics conditions would produce the greatest level of skill and knowledge acquisition. Results demonstrated a significantly higher level of fire emergency skill acquisition and knowledge attainment for both the behavioral and animated-graphics groups relative to the still-graphics group and the control group, which had no training. The value of using computer-mediated strategies for fire-safety skills training was demonstrated.     

Thermal Diffusivity/Conductivity and Specific Heat of Mullite-Zirconia-Silicon Carbide Whisker Composites

The thermal diffusivity of mullite-ZrO₂-SiC_w materials was determined from 25° to 1000°C for composites in which the ZrO₂ had different amounts of monoclinic and tetragonal phase, and varying SiC _w content. At 25°C the thermal diffusivity of the matrix materials increased with increasing amounts of monoclinic phase, and little or no anisotropy was seen. Composites with SiC _w additions showed significant increases in thermal diffusivity and anisotropy as compared with the matrix materials. With increasing temperature, thermal diffusivities of the matrices and their respective composites decreased, and at 1000°C differences were small. Specific heat was determined from 25° to 700°C and thermal conductivity values calculated. Specific heat increased with temperature and was not composition dependent, except for one sample. Thermal conductivity values as a function of temperature followed the same trends as the thermal diffusivity values.     

On the application of CAD technology for the synthesis of spatial revolute–revolute dyads

This work presents a method based on Computer Aided Design or CAD for facilitating the synthesis of Revolute–Revolute (R–R) dyads with adjustable moving pivots. The CAD-based method presented in this work ensures that all prescribed rigid-body parameters used to synthesize the R–R dyad satisfy particular kinematic requirements of an R–R dyad. Through the application of this CAD method, five of the six general R–R dyad constraint equations are satisfied and therefore not essential for the synthesis of the R–R dyad. By reducing the number of dyad design constraints from six to one, the user can synthesize R–R links with adjustable moving pivots for multi-phase motion and path generation applications. The example included demonstrates the use of the CAD method in the synthesis of an RRSS path generator with adjustable moving pivots.     

George Martin Haslerud (1906–1990): Obituary.

Commemorates G. M. Haslerud, who died suddenly on April 10, 1990. In his doctoral dissertation (1934) he addressed free and prescribed maze patterns in rats, pointing to a lifetime interest in creative transfer. In 1972 he completed his magnum opus, Transfer, Memory, and Creativity: After-Learning as Perceptual Process, which reflects continuing conversations with his mentor, Robert Yerkes. Haslerud is remembered as a co-founder of the New Hampshire Psychological Association. (0 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

High-temperature polyimide nanofoams for microelectronic applications

Foamed polyimides have been developed in order to obtain thin film dielectric layers with very low dielectric constants for use in microelectronic devices. In these systems the pore sizes are in the nanometer range, thus, the term ‘nanofoam’. The polyimide foams are prepared from block copolymers consisting of thermally stable and thermally labile blocks, the latter being the dispersed phase. Foam formation is effected by thermolysis of the thermally labile block, leaving pores of the size and shape corresponding to the initial copolymer morphology. Nanofoams prepared from a number of polyimides as matrix materials were investigated as well as from a number of thermally labile polymers. The foams were characterized by a variety of experiments including TEM, SAXS, WAXD, DMTA, density measurements, refractive index measurements and dielectric constant measurements. Thin film foams, with high thermal stability and low dielectric constants approaching 2.0, can be prepared using the copolymer/nanofoam approach.     

Dietary fibre of coconuts from a pacific atoll: Soluble and insoluble components in relation to maturity

Polysaccharide fractions were measured in coconuts at three stages of maturity, which corresponded to dietary usage in the Tokelau Islands of the South Pacific. Kernel was sequentially extracted with cold water (CW), hot water (HW) hot 0.5% ammonium oxalate (HOX), 1M H² SO⁴ and 72% H² SO⁴, and the monosaccharide compositions of the fractions determined. Total readily soluble fractions (CW+HW+HOX) were predominantly galactomannan, and decreased from 77% of the polysaccharide in the immature kernel to 8.8% of that in the mature kernel. Insoluble mannan increased during maturation to be the major polysaccharide component in mature kernel. This indicates that marked differences exist between the three stages of maturity examined, in the properties of their dietary fibre. The results suggest that in studies of diets in which coconut is a staple part, there is a need for careful definition of the coconut component with respect to maturity. Furthermore, they show the importance of using dietary fibre methods which are appropriate to the solubility characteristics of the indigestible polysaccharide.