Development of a distributed sensing technique using Brillouinscattering

This paper reviews the developments of a distributed strain and temperature sensing technique that uses Brillouin scattering in single-mode optical fibers. This technique is based on strain- and temperature-induced changes in the Brillouin frequency shift. Several approaches for measuring the weak Brillouin line are compared     

Time-series primitive static states for detailing work state and flow of human-operated work machine

This paper proposes a quantification method for a comprehensive work flow in construction work for describing work states in more detail on the basis of analyzing state transitions of primitive static states (PSS), which consist of 16 symbolic work states defined by using on-off state of the lever operations and joint loads for the manipulator and end-effector. On the basis of the state transition rules derived from a transition-condition analysis, practical state transitions (PST), which are common and frequent transitions in arbitrary construction work, are defined. PST can be classified into essential state transition (EST) or nonessential state transitions (NST). EST extracts common phases of work progress and estimates positional relations between a manipulator and an object. NST reveals wasted movements that degrade the efficiency and quality of work. To evaluate comprehensive work flows modeled by combining EST and NST, work-analysis experiments using our instrumented setup were conducted. Results indicate that all the PSS definitely changes on the basis of PST under various work conditions, and work analysis using EST and NST easily reveals work characteristics and untrained tasks related to wasted movements.     

Fabrication and flow-sensor application of flexible thermal MEMS device based on Cu on polyimide substrate

A Cu on polyimide (COP) substrate was proposed as a MEMS material, and the fabrication process for a flexible thermal MEMS sensor was developed. The COP substrate application to MEMS devices has the advantage that typical MEMS structures fabricated in a SOI wafer in the past—such as a diaphragm, a beam, a heater formed on a diaphragm—can also be easily produced in the COP substrate in the flexible fashion. These structures can be used as the sensing element in various physical sensors, such as flow, acceleration, and shear stress sensors. A flexible thermal MEMS sensor was produced by using a lift-off process and sacrificial etching of a copper layer on the COP substrate. A metal film working as a flow sensing element was formed on a thin polyimide membrane produced by the sacrificial etching. The fabricated flexible thermal MEMS sensor was used as a flow sensor, and its characteristics were evaluated. The obtained sensor output versus the flow rate curve closely matched the approximate curve derived using King’s law. The rising and falling response times obtained were 0.50 and 0.67 s, respectively.

     

Uterine Deletion of Bmal1 Impairs Placental Vascularization and Induces Intrauterine Fetal Death in Mice

Recently, it was demonstrated that the expression of BMAL1 was decreased in the endometrium of women suffering from recurrent spontaneous abortion. To investigate the pathological roles of uterine clock genes during pregnancy, we produced conditional deletion of uterine Bmal1 (cKO) mice and found that cKO mice could receive embryo implantation but not sustain pregnancy. Gene ontology analysis of microarray suggested that uterine NK (uNK) cell function was suppressed in cKO mice. Histological examination revealed the poor formation of maternal vascular spaces in the placenta. In contrast to WT mice, uNK cells in the spongiotrophoblast layer, where maternal uNK cells are directly in contact with fetal trophoblast, hardly expressed an immunosuppressive NK marker, CD161, in cKO mice. By progesterone supplementation, pregnancy could be sustained until the end of pregnancy in some cKO mice. Although this treatment did not improve the structural abnormalities of the placenta, it recruited CD161-positive NK cells into the spongiotrophoblast layer in cKO mice. These findings indicate that the uterine clock system may be critical for pregnancy maintenance after embryo implantation.     

On a posteriori estimates of inverse operators for linear parabolic initial-boundary value problems

We present numerically verified a posteriori estimates of the norms of inverse operators for linear parabolic differential equations. In case that the corresponding elliptic operator is not coercive, existing methods for a priori estimates of the inverse operators are not accurate and, usually, exponentially increase in time variable. We propose a new technique for obtaining the estimates of the inverse operator by using the finite dimensional approximation and error estimates. It enables us to obtain very sharp bounds compared with a priori estimates. We will give some numerical examples which confirm the actual effectiveness of our method.     

Nanoconfined (Bio)Catalysts as Efficient Glucose‐Responsive Nanoreactors

Herein, the design, synthesis, and characterization of bifunctional hybrid nanoreactors used for concurrent one‐pot chemoenzymatic reactions are shown. In the design, the enzyme, glucose oxidase, is wrapped with a peroxidase‐mimetic catalytic polymer. Hemin, the organic catalyst, is linked to the flexible polymeric scaffold through coordination to the imidazole groups that hang out the network. This spatial arrangement, which works as a metabolic channel, is optimized for cooperative chemoenzymatic reactions in which the enzyme catalyzes first. A deep characterization of the integrated nanoreactors demonstrates that the confinement of two distinct catalytic sites in the nanospace is very effective in one‐pot reactions. Moreover, besides its role as scaffold material, the polymeric mantel protects both the biocatalyst and the chemical catalyst from degradation and inactivation in the presence of organic solvents. Furthermore, the polymeric environment of the nanoreactors can be tailored in order to trigger the assembly of those into highly active heterogeneous hybrid catalysts. Finally, the new nanoreactors are applied to the efficient degradation of organic aromatic compounds using glucose as the only fuel.     

Approaching Trap-Minimized Polymer Thin-Film Transistors

Semiconducting π-conjugated polymers are the most promising candidates for flexible electronics owing to their facile processability and mechanical robustness; however, achieving steep and stable switching operations in polymer thin-film transistors (TFTs) remains a serious challenge. Herein, it is shown that whole optimizations for eliminating interfacial carrier traps throughout the conductive path are necessary in achieving TFTs showing both exceptionally sharp switching and bias-stress-free characteristics. Inverted-coplanar-type TFTs composed of a highly lyophobic amorphous perfluoropolymer gate–dielectric interfaced with a push-coated semiconducting polymer layer are manufactured. The use of the dielectric allows the establishment of bias-stress-free characteristics with minimized contact resistance. Additionally, fairly sharp on/off switching TFTs with the smallest normalized subthreshold swing can be obtained by utilizing a particular donor–acceptor copolymer that involves a self-passivation mechanism working to achieve a trap-minimized interface. These findings have opened a way for low-power and robust device operations in polymer-based flexible electronics.     

Thermal effects of Brillouin gain spectra in single-mode fibers

Brillouin gain spectra in two 250-m-long single-mode fibers with GeO₂-doped core/pure-silica cladding (fiber A) and pure-silica core/F-doped cladding (fiber B) were measured at temperatures ranging from -40 to +60°C at a wavelength of 1.32 μm. The temperature coefficients of Brillouin frequency shift were found to be 1.17 and 1.33 MHz/°C for fibers A and B, respectively. Temperature coefficients of Brillouin gain bandwidth were found to be -0.12 and -0.10 MHz/°C. These measurements provide useful information for applications of stimulated Brillouin scattering     

Measurements of waveguide structure fluctuation in a multimode optical fiber by backscattering technique

Utility of a backscattering technique for measuring waveguide structure fluctuation along a fiber is confirmed quantitatively. The backscattering technique is applied to three graded-index fibers: one fiber has uniform structure and the others have core diameter and refractive-index difference changes along the fiber length. The structural parameter fluctuations measured by the technique are in good agreement with those measured directly by the interference microscopy at several positions along the fibers. The resolvability and accuracy of the measured results by the backscattering technique is also compared with the relative error of the direct measurements.     

热化学蓄热系统研究进展

热化学蓄热通过可逆化学反应来储存和释放热量,其蓄热密度高于显热蓄热和相变蓄热,且能够实现能量的长期储存,在未来能源利用领域具有广阔前景。根据热化学蓄热系统的结构,可将其分为开式系统和闭式系统。本文针对开式系统和闭式系统,对蓄热材料、环境气氛条件、反应过程优化以及反应器设计等影响系统性能的重要因素进行概述与讨论,为热化学蓄热系统的发展和实际应用提供参考。