The effect of carbon surface oxidation on platinum supported carbon particles (Pt/C) with nitric acid was investigated by
cyclic voltammetry, electrochemical impedance spectroscopy, polarization experiments and chronoamperometry. Cyclic voltammograms,
polarization curves and electrochemical impedance spectra showed that the treated catalyst had much larger active surface
area and higher ionic conductivity than the untreated catalyst, and provided enhanced performance for oxygen reduction. The
formation of acidic groups was examined by IR spectra. The Pt/C surface oxidation had a large effect on the performance of
a gas diffusion electrode for oxygen reduction reaction. 相似文献
Electrochemical treatment processes can significantly contribute to the protection of the environment through the minimization
of waste and toxic materials in effluents. From a pharmaceutical point of view and due to the existing resemblance between
the electrochemical and biological reactions, it can be assumed that the oxidation mechanisms on the electrode and in the
body share similar principles. In this paper, the application of electrochemical studies in the design of an environmentally
friendly method was delineated for the new hydrocaffeic acid (HCA, 3,4-dihydroxy hydrocinnamic acid) derivatives synthesis
at carbon electrodes in an undivided cell. In this cell, the EC mechanism reaction was involved, comprising two steps alternatively;
(1) electrochemical oxidation and (2) chemical reaction. In particular, the electro-organic reactions of HCA, an important
biological molecule, were studied in a water–acetonitrile (90:10 v/v) mixture in the presence of benzenesulfinic acid (3) and p-toluenesulfinic acid (4). The research included the use of a variety of experimental techniques, such as cyclic voltammetry, controlled-potential
electrolysis and product spectroscopic identification. 相似文献
In this study, analytical modeling of the tensile strength of hot-mix asphalt (HMA) mixtures at low temperatures was developed. To do this, HMA mixtures were treated as a two-phase composite material with aggregates (coarse and fine) dispersed in an asphalt mastic matrix. A two-phase composite model, which was similar to Papanicolaou and Bakos's [J. Reinforced Plast. Compos. 11 (1992) 104] model with a particle embedded in an infinite matrix, was proposed. Unlike Papanicolaou and Bakos's model, an axial stress was introduced to the fiber end to consider the load transferred from the asphalt mastic the aggregate. Efforts were also made to consider the effect of aggregate gradation, asphalt mastic degradation, and interfacial damage between the aggregates and asphalt mastic matrix on the tensile strength of the HMA mixtures. Experimental investigations were conducted to validate the developed theoretical relations. A reasonable agreement was found between the predicted tensile strength and the experimental results at low temperatures. Parameters affecting the tensile strength of asphalt mixtures were discussed based on the calculated results. 相似文献
A study of radiation effects on various types of glasses, dielectric optical coatings, cemented optics and fiber was undertaken with a view to select them for extreme radiation environments. Samples were exposed to different radiation doses in the Pakistan Research Reactor-I (PARR-I) for neutron and Cobalt 60 source for gamma irradiation. Transmissions were measured before and after irradiation. The dielectric coatings were subjected to additional tests (adhesion, abrasion and humidity, etc.) as per MIL-M-13508C and MIL-C-675C. All 15 glasses studied showed varying amounts of transmission loss as expected, with negligible degradation for three types. Recovery of transmissions with time/ageing was also studied, with more or less complete recovery with temperature annealing. A faster bleaching of darkened/brown glasses was achieved by using UV lamps or UV laser. The dielectric coatings (HR, AR) and one of the two commercial optical cements showed excellent resistance to neutrons and gamma radiations, and could be good candidates for the fabrication and utilization of optical components in extreme radiation environments. The data allowed several Chinese glasses to be studied for the first time. 相似文献
This study deals with the neuro-fuzzy (NF) modelling of a real industrial winding process in which the acquired NF model can be exploited to improve control performance and achieve a robust fault-tolerant system. A new simulator model is proposed for a winding process using non-linear identification based on a recurrent local linear neuro-fuzzy (RLLNF) network trained by local linear model tree (LOLIMOT), which is an incremental tree-based learning algorithm. The proposed NF models are compared with other known intelligent identifiers, namely multilayer perceptron (MLP) and radial basis function (RBF). Comparison of our proposed non-linear models and associated models obtained through the least square error (LSE) technique (the optimal modelling method for linear systems) confirms that the winding process is a non-linear system. Experimental results show the effectiveness of our proposed NF modelling approach. 相似文献
Water Resources Management - Reference evapotranspiration (ET0) is a crucial element for deriving irrigation scheduling of major crops. Thus, precise projection of ET0 is essential for better... 相似文献
One of the most important analysis in many hydrological and agricultural studies is to convert the daily rainfall data into sub-daily (hourly) because in many rainfall stations, only the daily rainfall data are available and for a comprehensive rainfall analysis, these data should be converted to sub-daily. Many experimental and analytical methods are available for this conversion but one of the simplest yet accurate ones has been proposed by the Indian Meteorological Department (IMD). Since the IMD method has shown low accuracy in some regions, in this study, the IMD method is modified to a single parameter equation, called Modified Indian Meteorological Department (MIMD) in order to improve the accuracy of the conversion. For this reason, the parameter is calibrated so that the maximum correlation between observed and estimated values is achieved. Five stations in different regions with different climatic conditions were selected so that the daily and sub-daily rainfall data were available in each of them. Then, the parameter of the MIMD method was derived for each station. The results were compared with both observed data and IMD method and it was shown that the mean correlation coefficient of MIMD and IMD methods were 0.9 and 0.73 respectively for 12-h rainfall depth which indicated that the accuracy of the MIMD method in estimation of sub-daily rainfall depths was significantly increased. Moreover, the results showed that the accuracy of the MIMD method decreases as rainfall duration decreases.