Novel HPLC-RI-UV based method for simultaneous estimation of saturates,olefins, conjugated dienes and aromatics in full range cracked gasoline

Abstract

A fast method based on High performance liquid chromatography technique for the estimation of Saturates, Olefins, Conjugated dienes and Aromatics in Cracked gasoline samples has been developed. In this work, the focus was on choosing the right reference standard against which olefin could be estimated. The olefin reference standard was first shortlisted using Nuclear Magnetic Resonance spectroscopy and Gas chromatography based Simulated Distillation analysis as per ASTM D2887. The values estimated against shortlisted standards using HPLC were compared with values obtained using standard Flourescent Indicator Adsorption(FIA) based ASTM D1319 method to select one. The aromatics were estimated against o-Xylene.     

Performance estimation of sub-30 nm junctionless tunnel FET (JLTFET)

In this paper we examined the short channel behavior of junction less tunnel field effect transistor (JLTFET) and a comparison was made with the conventional MOSFET on the basis of variability of device parameter. The JLTFET is a heavily doped junctionless transistor which uses the concept of tunneling, by narrowing the barrier between source and channel of the device, to turn the device ON and OFF. The JLTFET exhibits an improved subthreshold slope (SS) of 24 mV/decade and drain-induced barrier lowering (DIBL) of 38 mV/V as compared to SS of 73 mV/decade and DIBL of 98 mV/V for the conventional MOSFET. The simulation result shows that the impact of length scaling on threshold voltage for JLTFET is very less as compared to MOSFET. Even a JLTFET with gate length of 10 nm has better SS than MOSFET with gate length of 25 nm, which enlightens the superior electrostatic integrity and better scalability of JLTFET over MOSFET.     

Waves in dual-phase-lag thermoelastic materials with voids based on Eringen’s nonlocal elasticity

The main idea of the present work is to extend Eringen’s theory of nonlocal elasticity to generalized thermoelasticity with dual-phase-lag and voids. Then we study the propagation of time harmonic plane waves in an infinite nonlocal dual-phase-lag thermoelastic medium with voids. Three sets of coupled dilatational waves and an independent transverse wave may travel with distinct speeds through the medium. All these waves are found to be dispersive in nature. The coupled dilatational waves are damping, while the transverse wave is undamped in a certain range of the angular frequency. Coupled dilatational waves are found to be influenced by the presence of voids, thermal field and elastic nonlocal parameter, while the transverse wave is found to be influenced by the nonlocal parameter, but independent of void and thermal parameters. For a particular model, the effects of angular frequency, elastic nonlocality parameter, and some voids and thermal parameters on the wave speeds and damping coefficients of all the propagating waves have been studied numerically. Some comparisons are made between the results obtained for local and nonlocal cases. All the computed results have been depicted graphically and explained in details.     

Corrosion Behaviour of New Railway Axle Steels

Corrosion behaviour of two newly developed axle steels (MS3 and MS6) is critically analysed and compared with that of the conventional railway axle steel with respect to the rust formed on the surface and microstructure of the steels. The microstructure of all three steels is ferrite–pearlite. Immersion, salt-fog exposure and dynamic polarisation tests in 3.5 wt% NaCl solution are carried out. New steels have much better mechanical properties and comparable corrosion resistance in immersion and dynamic polarisation test and much better corrosion resistance in salt-fog exposure test than that of the conventional axle steel.     

Unsteady Forced Convection Heat Transfer Over a Semicircular Cylinder at Low Reynolds Numbers

An unsteady two-dimensional numerical simulation is performed to investigate the laminar forced convection heat transfer for flow past a semicircular cylinder in an unconfined medium. The Reynolds number considered in this study ranges from 50 to 150 with a fixed Prandtl number (Pr = 0.71). Two different configurations of the semicircular cylinder are considered; one when the curved surface facing the flow and the other when the flat surface facing the flow. Fictitious confining boundaries are chosen on the lateral sides of the computational domain that makes the blockage ratio B = 5% in order to make the problem computationally feasible. A finite volume-based technique is used for the numerical computation. The flow and heat transfer characteristics are analyzed with the streamline and isotherm patterns at various Reynolds numbers. The dimensionless frequency of vortex shedding (Strouhal number), drag coefficient, and Nusselt numbers are presented and discussed. Substantial differences in the global flow and heat transfer quantities are observed for the two different configurations of the obstacle chosen in the study. It is observed that the heat transfer rate is enhanced substantially when the curved surface is facing the flow in comparison to the case when the flat surface is facing the flow.     

Investigation of Mixed Convection in a Ventilated Cavity in the Presence of a Heat Conducting Circular Cylinder

The study is aimed to investigate the mixed convective transport within a ventilated square cavity in presence of a heat conducting circular cylinder. The fluid flow is imposed through an opening at the bottom of the left cavity wall and is taken away by a similar opening at the top of the right cavity wall. The cylinder is placed at the center of the cavity. Two cases are considered depending on the thermal conditions of the cavity walls. In the first case, the left and right vertical walls are kept isothermal with different temperatures and the top and bottom horizontal walls are considered as thermally insulated. For the second case, the top and bottom walls are maintained at different constant temperatures and the left and right walls are considered adiabatic. Heat transfer due to forced flow, thermal buoyancy, and conduction within the cylinder are taken into account. Effect of the cylinder size (0.1 ≤ D ≤ 0.5) and the solid–fluid thermal conductivity ratio (0.1 ≤ K ≤ 10) are explored for various values of Richardson number (0 ≤ Ri ≤ 5) at fixed Reynolds (Re = 100) and Prandtl (Pr = 0.71) numbers. The fluid dynamic and thermal transport phenomena are depicted through streamline and isotherm plots. Additionally, the global thermal parameters such as the average Nusselt number and average fluid temperature of the cavity are presented. It is found that the aforementioned parameters have significant influences on the fluid flow and heat transfer characteristics in the cavity.     

Mixed Convection Heat Transfer From an Equilateral Triangular Cylinder in Cross Flow at Low Reynolds Numbers

A two-dimensional numerical study is undertaken to investigate the influences of cross buoyancy on the vortex shedding phenomena behind a long heated equilateral triangular cylinder for the low-Reynolds-number laminar regime. The flow is considered in an unbounded medium; however, fictitious confining boundaries are chosen on the lateral sides to make the problem computationally feasible. Numerical calculations are performed by using a finite-volume method based on the pressure-implicit with splitting of operators algorithm in a collocated grid system. The range of Reynolds number is chosen to be 10–100 with a fixed Prandtl number, 0.71. The mixed convection effect is studied for the Richardson number range of 0–1. The effects of superimposed thermal buoyancy on flow and isotherm patterns are presented and discussed. The global flow and heat transfer quantities such as the overall drag and lift coefficients, local and surface average Nusselt numbers, and Strouhal number are calculated and discussed for various Reynolds and Richardson numbers.     

Additive free thermoplastic vulcanizates based on natural rubber

Electron induced reactive processing (EIReP) is an eco-friendly and sustainable reactive processing method based on the use of high energy electrons. It was used to cross-link the elastomeric domain phase during melt mixing in order to prepare natural rubber (NR) and polypropylene (PP) based thermoplastic vulcanizates (TPVs). The electron treatment with various values of absorbed dose showed a prominent effect on mechanical, rheological, and morphological characteristics of the PP/NR TPVs. SEM and TEM studies confirmed that these TPVs can exists across the co-continuous or discrete phase morphology. The maximum set of mechanical properties (tensile strength of 15 MPa and elongation at break of more than 500%) were obtained at an absorbed dose of 100 kGy for a 50/50 blend ratio of NR and PP without addition of any compatibilizer or chemicals. At higher values of absorbed dose the degradation of polypropylene showed a negative impact on the properties of the TPVs. Depending on the morphology and the evaluation of mechanical properties a structure–property co-relationship is drawn on the basis of common phenomenological understanding of the TPVs.     

X-ray study of weak interactions in two flavonoids

X-ray diffraction studies were carried out on single crystals of two flavonoids, viz. 5-hydroxy-6,7,4′-trimethoxyflavone, C₁₈H₁₆O₆, (I) and 5-hydroxy-3,7,4′-trimethoxyflavone, C₁₈H₁₆O₆, (II). Crystal structures of both the flavonoids were solved by direct methods and refined by full-matrix least-squares procedures. In both the molecules, the benzopyran moiety is planar. The dihedral angle between the phenyl ring and the benzopyran portion is 5.50(4)° in (I) and 29.11(5)° in (II). In (I), the crystal packing is influenced by O-H…O hydrogen bonds, and weak C-H…O and π…π interactions whereas in (II) the crystal structure is stabilized by the presence of four intermolecular short contacts of the type C-H…O. There is also one C-H…π hydrogen bond with H… centroid distance of <2.7 Å. The molecules are further stabilized by π-π interactions.     

Molecules that target beta-amyloid

The devastating effects of Alzheimer's and related amyloidogenic diseases have inspired the synthesis and evaluation of numerous ligands to understand the molecular mechanism of the aggregation of the beta-amyloid peptide. Our review focuses on the current knowledge in this field with respect to molecules that have been demonstrated to interact with either oligomeric or fibrillar forms of the beta-amyloid peptide. We describe natural proteins, peptides, peptidomimetics, and small molecules that have been found to interfere with beta-amyloid aggregation. We also detail recent efforts in selecting molecules that target beta-amyloid isolated from antibody, protein, and peptide libraries. These new molecules will likely aid in deciphering the details of the aggregation pathway for the beta-amyloid peptide and provide reagents that may stabilize relevant oligomeric intermediates which likely have bearing on the pathophysiology of Alzheimer's disease. Moreover, the described anti-amyloid molecular toolbox will also provide an avenue for designing new diagnostic and therapeutic reagents.