Fault-surge calculation using phase-domain ARMA line model

For fault-surge studies, the most important and also most difficult part of the simulation is inclusion of the frequency dependence of the transmission line, because the simulation requires high accuracy in a wide frequency range, from the power frequency to a few megahertz. The authors have developed a highly efficient method of modeling a transmission line considering its complete frequency dependence, which cannot be dealt with in the present line models in the Electro-Magnetic Transients Program (EMTP). According to the method, a transmission line is modeled directly in the phase domain in order to avoid model transformation and thus to eliminate the problems of representing its frequency dependence. The method also includes sophisticated acceleration of transient calculations by means of an autoregressive moving average (ARMA) model. This paper presents a method of steady-state initialization of the phase-domain ARMA line model for applying it to fault-surge calculations. The calculated results agree well with rigorous frequency-domain simulations and show improved accuracy compared with an existing frequency-dependent line model (J. Marti model) widely used as a standard model in the EMTP. © 1998 Scripta Technica, Inc. Electr Eng Jpn, 121(3): 27–35, 1997     

Enzymatic hydrolysis of potato starches containing different amounts of phosphorus

The rapid hydrolysis of potato starches differing in phosphorus content, as well as sweet potato, cassava and yam starches, was accomplished by treatment of gelatinised starches with bacterial liquefying α-amylase at 50 °C for 1 h, followed by Bacillus licheniformis α-amylase at 55 °C up to 24 h, and then by glucoamylase at 40 °C for a further 24 h. Among the potato starches, the high-phosphorus starches showed higher starch resistant capacity than the medium-phosphorus starches, as well as other tuber and root starches. The hydrolysis rate of tuber and root starches was not greatly influenced by their amylose content and median granule size. Only glucose was detected in the almost completely hydrolysed tuber and root starch samples, indicating that the concomitant enzymes treatment could hydrolyse both the α-1,4 and α-1,6 linkages of the starches examined.     

Development of effective detection method for Coxiella burnetii in mayonnaise by real-time PCR and investigation of C. burnetii contamination in commercial mayonnaise in Tokyo

A PCR method for the effective detection of Coxiella burnetii in commercially available mayonnaise was developed. Sample preparations were isolated from 50 g portions of each mayonnaise product by four successive extraction steps in phosphate buffer with 2.0 M NaCl. These extracts were then centrifuged at 20,000 x g for 60 min. DNA was isolated from the solution containing the precipitate with a commercial kit, and amplified quantitatively using real-time PCR that targeted the com1 region of C. burnetii. The recoveries of C. burnetii from 2 kinds of commercial mayonnaise specimens, with a baseline control of 1 x 10(7) particles of the Nine Mile phase II strain, were 85.0 +/- 6.0% and 72.0 +/- 0.4%, respectively. The determination limit of this method was 500 C. burnetii particles per 50 g of mayonnaise. The DNA specimens isolated from 50 different commercial mayonnaise samples sold in Tokyo using this method were amplified using both nested PCR and real-time PCR. No contamination by C. burnetii was detected in any of the mayonnaise samples.     

One-dimensional self-assembly of alkoxy-capped silicon nanoparticles

We demonstrate here a novel method for self-assembling in dimensional alignment the alkoxy-capped silicon nanoparticles synthesized through a room-temperature chemical route. The alkoxy-capped silicon nanoparticles were prepared via a reduction of silicon tetrachloride with sodium-naphthalide and subsequent surface capsulation with 1-octanol monolayers. In the present method, a sublimation process, which was employed as a final purification process for removing the residual naphthalene, influenced significantly on the final morphology of the resultant nanoparticles. Scanning transmission electron microscope (STEM) confirmed the spherical nanoparticles on a holey carbon grid after sublimation process, while only the fibril-like morphology just before sublimation process. In the former sample, the resultant particle size was measured by STEM to be about 9.5 nm +/- 3.4 nm. On the other hand, in the latter sample, the fibril-like structures were shaped by self-assembled silicon nanoparticles in dimensional alignment. The diameters and lengths of the fibril-like assemblies were approximately measured to be 10 to 20 nm and over 5 microm, respectively.     

Sensitive analyses of neutral N-glycans using anion-doped liquid matrix G3CA by negative-ion matrix-assisted laser desorption/ionization mass spectrometry

Negative-ion fragmentation of N-glycans has been proven to be more informative than that of positive-ion. In particular, it defines structural features such as the specific composition of the two antennae and the location of fucose. However, negative-ion formation of neutral N-glycans by matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) remains a challenging task, and the detection limit of N-glycans in negative-ion mode is merely at the subpicomole level. Thus, practical applications are limited. In this study, combinations of five liquid matrices and nine anions were used to ionize N-glycans as anionic adducts, and their performances for sensitive analyses were evaluated. The best results were obtained with anion-doped liquid matrix G(3)CA, which consists of p-coumaric acid and 1,1,3,3-tetramethylguanidine; the detection limits of anion adducted N-glycans were 1 fmol/well for NO(3)(-), and 100 amol/well for BF(4)(-). Negative-ion MS(2) spectra of 1 fmol N-glycans were successfully acquired with a sufficient signal-to-noise ratio and were quite useful for MS-based structural determination. The anion-doped G(3)CA matrix opens the way for sensitive and rapid analysis of neutral N-glycans in negative-ion MALDI at a low femtomole level.     

Nano-photocatalytic materials: possibilities and challenges

Semiconductor photocatalysis has received much attention as a potential solution to the worldwide energy shortage and for counteracting environmental degradation. This article reviews state-of-the-art research activities in the field, focusing on the scientific and technological possibilities offered by photocatalytic materials. We begin with a survey of efforts to explore suitable materials and to optimize their energy band configurations for specific applications. We then examine the design and fabrication of advanced photocatalytic materials in the framework of nanotechnology. Many of the most recent advances in photocatalysis have been realized by selective control of the morphology of nanomaterials or by utilizing the collective properties of nano-assembly systems. Finally, we discuss the current theoretical understanding of key aspects of photocatalytic materials. This review also highlights crucial issues that should be addressed in future research activities.     

Crystal and electronic structure change determined by various method for delithiation process of Lix(Ni,Mn)O2-based cathode material

We investigated effects of delithiation on crystal, electronic structure, thermodynamic stability and physical property of Li_xNi_0.5Mn_0.5O₂ by using a chemical delithiation treatment with ammonium peroxodisulfate, and compared the results with those of electrochemical delithiation. X-ray diffraction and thermodynamic data indicated that there was no phase transition in the samples after the chemical delithiation treatment within the lithium range of 0.50 ≤ x ≤ 1.00. From the ICP measurements and potentiometric titration, it was found that the chemical treatment successfully remove Li from the structure without any elution of Ni and Mn, but it accompanied O₂ removal at an initial process of the delithiation, i.e. 0.80 ≤ x ≤ 1.00. Crystal and electronic structure analyses also suggested such a O₂ removal at the lithium content range in the chemical delithiation method, although the estimated structure changes below x = 0.80 showed similar tendencies to those by the electrochemical delithiation.     

Submicron-sized boron carbide particles encapsulated in turbostratic graphite prepared by laser fragmentation in liquid medium

Submicron-sized B4C spherical particles were obtained by laser fragmentation of large B4C particles dispersed in ethyl acetate. The irradiated surface of large B4C raw particles was heated and melted by laser energy absorption. B4C droplets were then cooled down, and finally B4C spherical particles were obtained. Moreover, each B4C particle obtained was encapsulated in a graphitic layer that is useful for medical functionalization of particles. Thus, obtained B4C particles encapsulated in graphitic layer may have potential uses in boron neutron capture therapy.     

Ab initio study on plane defects in zirconium–hydrogen solid solution and zirconium hydride

Hydrogen embrittlement of zirconium alloys is one of the main causes of the mechanical degradation of the fuel cladding in light water reactors, and has therefore been extensively studied. Although various conjectures have been proposed as the origin of such embrittlement, it is not known which one plays the most important role: the brittle nature of the hydride, micro-crack nucleation by interaction of hydride precipitates with dislocations or void nucleation at the interface between hydride precipitates and zirconium matrix. The purpose of the present study was to elucidate the origin of the embrittlement by investigating the fracture properties of the hydride. We have evaluated the surface energy γ_S and unstable stacking energy γ_US of Zr–H systems by using ab initio calculations. The ductile/brittle behavior of the hydride is discussed based on the difference between γ_S and γ_US among the hydride, pure zirconium and hydrogen solid solution. For the solid solution at a H/Zr ratio less than 0.5 we obtained a monotonous decrease by 15–34% and 50–100% in γ_S and γ_US, respectively, from those in pure zirconium, indicating a reduction in both brittleness and ductility. Thus, hydrogen-induced embrittlement of the hcp Zr matrix was not confirmed. On the other hand, for the hydride we obtained a 25% smaller γ_S and a 200–300% larger γ_US than those in pure zirconium. This indicates that zirconium hydride has an extremely brittle nature due to the synergistic effect of a small γ_S, implying easy generation of a fracture surface, and large γ_US, implying a difficulty in dislocation motion, compared with pure zirconium. Furthermore, Rice’s ductile/brittle parameter D was 1.4 in the δ-hydride, indicating that it undergoes brittle fracture more easily than iridium, known as an extremely brittle material. These results seem sufficient to attribute hydrogen embrittlement of zirconium alloys substantially to the brittle nature of the hydride.