Explicit form of new class of extremal filter functions with mini-max behaviour of summed sensitivity function

In this article, the all-pole low-pass filter function with mini-max for the summed sensitivity function in the pass-band is considered. With the application of Chebyshev polynomials of the first kind, the proposed filter function is obtained in an explicit form with a maximum number of oscillations of the summed sensitivity function in the pass-band. The calculation of the filter function is derived by using the summed sensitivity function as a starting point. New original approximation function is derived in order to achieve a mini-max summed sensitivity function in the filter pass-band. Sensitivity analysis is carried out and a comparison of the summed sensitivity and the group delay of the proposed and classical all-pole filters is given. Minimisation of the summed sensitivity function is important for reduction of the deviation of the magnitude response caused by temperature changes of the continuous-time active filters implemented into the analogue front end or as programmable chips.     

Room Temperature Spin-Phonon Coupling in Cr2O3 Nanocrystals

In this study, nanocrystals of antiferromagnetic Cr₂O₃ are shown via Raman spectroscopy to display peculiar lattice dynamics in terms of phonon softening and the occurrence of an exceptionally strong spin-phonon coupling. This effect, which is observed to persist well above the onset of the antiferromagnetic ordering temperature, is ascribed to locally correlated spin fluctuations due to the modulation of the magnetic exchange interactions as the chromium atoms oscillate about their equilibrium position. It is found that the spin-phonon coupling strength is governed by the competing antiferromagnetic and ferromagnetic interactions, where changes in the surface spin configuration can also play a crucial role. Overall, this work proves the size dependence of the interplay between the crystalline and magnetic structures in 3D antiferromagnets varying the surface-to-volume ratio and helps establish the fundamentals for a spin-phonon coupling engineering at the nanoscale via a simple route in a very stable and easy to synthesize material. More importantly, it demonstrates the possibility of coupling phononic excitations with the magnetization dynamics at room temperature, offering a highly prospective nanomaterial for the design of novel magnonic devices.     

On‐the‐Spot Immobilization of Quantum Dots,Graphene Oxide,and Proteins via Hydrophobins

Class I hydrophobin Vmh2, a peculiar surface active and versatile fungal protein, is known to self‐assemble into chemically stable amphiphilic films, to be able to change wettability of surfaces, and to strongly adsorb other proteins. Herein, a fast, highly homogeneous and efficient glass functionalization by spontaneous self‐assembling of Vmh2 at liquid–solid interfaces is achieved (in 2 min). The Vmh2‐coated glass slides are proven to immobilize not only proteins but also nanomaterials such as graphene oxide (GO) and quantum dots (QDs). As models, bovine serum albumin labeled with Alexa 555 fluorophore, anti‐immunoglobulin G antibodies, and cadmium telluride QDs are patterned in a microarray fashion in order to demonstrate functionality, reproducibility, and versatility of the proposed substrate. Additionally, a GO layer is effectively and homogeneously self‐assembled onto the studied functionalized surface. This approach offers a quick and simple alternative to immobilize nanomaterials and proteins, which is appealing for new bioanalytical and nanobioenabled applications.     

Condensation Induced Delamination of Nanoscale Hydrophobic Films

Vapor condensation is a crucial phenomenon governing the efficiency of many processes. In particular, dropwise condensation on hydrophobic thin films (≈100 nm‐thick) has the potential to achieve remarkable heat transfer. However, the lack of durability of these thin films has limited applications for a century. Although degradation due to steam condensation has been described as “blistering,” no satisfactory insight exists capable of elucidating the driving force for film delamination. Here, it is shown that nanoscale pinholes in hydrophobic films are the source of blister formation. By creating artificial pinholes via nanoindentation on thin (30 to 500 nm‐thick) fluorinated hydrophobic films, it is demostrated that water blisters can be initiated at the pinholes during condensation. It is experimentally demonstrated that vapor is transferred to the blister through the nanoscale pinhole, and the driving force for delamination is capillary pressure generated at the pinhole by the pinned liquid–vapor interface. The techniques and insights presented here will inform future work on polymeric thin film and enable their durable design for a variety of applications.     

Small-molecule vacuum processed melamine-C60, organic field-effect transistors

The transfer of benchtop knowledge into large scale industrial production processes represents a challenge in the field of organic electronics. Large scale industrial production of organic electronics is envisioned as roll to roll (R2R) processing which nowadays comprises usually solution-based large area printing steps. The search for a fast and reliable fabrication process able to accommodate the deposition of both insulator and semiconductor layers in a single step is still under way. Here we report on the fabrication of organic field effect transistors comprising only evaporable small molecules. Moreover, both the gate dielectric (melamine) and the semiconductor (C₆₀) are deposited in successive steps without breaking the vacuum in the evaporation chamber. The material characteristics of evaporated melamine thin films as well as their dielectric properties are investigated, suggesting the applicability of vacuum processed melamine for gate dielectric layer in OFETs. The transistor fabrication and its transfer and output characteristics are presented along with observations that lead to the fabrication of stable and virtually hysteresis-free transistors. The extremely low price of precursor materials and the ease of fabrication recommend the evaporation processes as alternative methods for a large scale, R2R production of organic field effect transistors.     

Multilevel statistical inference from functional near-infrared spectroscopy data during stroop interference

Functional near-infrared spectroscopy (fNIRS) is an emerging technique for monitoring the concentration changes of oxy- and deoxy-hemoglobin (oxy-Hb and deoxy-Hb) in the brain. An important consideration in fNIRS-based neuroimaging modality is to conduct group-level analysis from a set of time series measured from a group of subjects. We investigate the feasibility of multilevel statistical inference for fNIRS. As a case study, we search for hemodynamic activations in the prefrontal cortex during Stroop interference. Hierarchical general linear model (GLM) is used for making this multilevel analysis. Activation patterns both at the subject and group level are investigated on a comparative basis using various classical and Bayesian inference methods. All methods showed consistent left lateral prefrontal cortex activation for oxy-Hb during interference condition, while the effects were much less pronounced for deoxy-Hb. Our analysis showed that mixed effects or Bayesian models are more convenient for faithful analysis of fNIRS data. We arrived at two important conclusions. First, fNIRS has the capability to identify activations at the group level, and second, the mixed effects or Bayesian model is the appropriate mechanism to pass from subject to group-level inference.     

BPC – A binary priority countdown protocol

In modern wireless ad hoc networks, with a high speed PHY, every collision means a significant loss of useful bandwidth. In the last few years different binary contention protocols have been introduced to address this problem. In this work we propose a novel binary contention protocol called binary priority countdown (BPC) protocol, whose goal is to reduce collisions as well as contention time. BPC uses a new priority countdown mechanism which exploits the efficiency of binary countdown, but the priority countdown process is not constrained to a single binary countdown round. This way, the priority space is not defined by the length of binary countdown round, like in other binary countdown protocols proposed in the literature, and arbitrary medium access priorities can be decremented through multiple binary countdown rounds if necessary. The ability of a new priority countdown mechanism to count down any priority number without changing the length of a binary countdown round, allows independent management of priority space. This “independence” of priority space introduces new optimization and adaptation possibilities. Collision memory effect is recognized and described. BPC protocol reveals connection between unary, binary and digit contention protocols. All three groups of protocols can now be seen as members of the same class of contention algorithms. Preliminary simulation results are shown.     

High output impedance current-mode lowpass,bandpass and highpass filters using current controlled conveyors

Three new current-mode second-order filter configurations which employ one or two current controlled conveyors (CCCIIs) and three passive elements are presented. Each proposed filter can realize one of the bandpass, lowpass or highpass responses all at high impedance outputs. The proposed filters offer current-control of pole angular frequency ω_o without disturbing the parameter ω_o /Q. No component matching is required and all the passive and active sensitivities are low. PSPICE simulation results are given to confirm the theoretical analysis.     

Electrically Active States of Charge Capture and Transfer Causing Slow Recombination in Thallium-Bromide Crystals at Low Temperatures

TlBr single crystals grown by the Bridgman–Stockbarger method are studied. It is established that frozen-conductivity effects manifest themselves under interband excitation by light at temperatures below 200 K. Herewith, clearly pronounced superlinear dependences of the induced photoconductivity on the strength of the applied electric field manifest themselves. The results of studying thermally stimulated conductivity evidence that these phenomena can be associated with the filling of trap states with thermal activation energies of 0.08–0.12 eV. This state can be removed due to thermal quenching at temperatures of ?180 K because of the emptying of energy states with an activation energy of 0.63–0.65 eV filled after optical generation.