Controllable electrode activities of nano-carbon films while maintaining surface flatness by electrochemical pretreatment

A carbon film consisting nanocrystallites with mixed sp² and sp³ bonds formed by using the electron cyclotron resonance (ECR) sputtering method was studied with respect to the changes in characteristics caused by electrochemical pretreatment (ECP). Unlike glassy carbon, our sputtered nanocrystalline carbon film deposited at an acceleration voltage of 75 V (ECR-75 nano-carbon film) largely retained its surface flatness after the ECP. This robust surface could be caused by an increase of 42% in the sp³ carbon realized by increasing the acceleration voltage during sputtering. The electrode activity of ECR-75 nano-carbon film was improved for surface sensitive species including Fe^3+/2+ unlike the boron doped diamond (BDD) electrode. This is because a sufficient quantity of surface sp² bonds remained and because the introduction of surface oxygen-containing groups is more efficient than with the BDD electrode. With pretreated ECR-75 nano-carbon film, the peak potential of glutathione was reduced solely due to the increase in the surface hydrophilicity with a sufficient quantity of surface sp² bonds, thus achieving the lowest detection limit (0.4 μM) ever obtained with carbon electrodes. We also achieved the stable measurement of 30 μM of serotonin (20 times) without the electrode surface fouling found with other electrodes.     

Forced vibration tests and simulation analyses of a nuclear reactor building

Forced vibration tests were carried out at the Hamaoka (BWR) Unit 4 R/B (reactor building) in Japan in April and May of 1992. Fundamental dynamic characteristics of the R/B were obtained, including its interaction with the adjacent T/B (turbine building) and the soil–structure interaction. Results for the preceding R/Bs are compared, and probable causes for fluctuations in the resonance curve around the 1st peak are discussed. Furthermore, simulation analyses of the fundamental dynamic characteristics of the soil–structure system were conducted, using a basic lumped-mass soil–structure model (lattice model), and strong correlation with the measured data was obtained. Other detailed simulation models were employed to investigate the effects of simultaneously induced vertical response and response of the adjacent turbine building on the lateral response of the reactor building.     

Decomposition of chlorofluorocarbons on TiO2ZrO2

The decomposition of chlorofluorocarbons (CFCs) in the presence of water was examined over a variety of solid acid catalysts. The TiO₂ZrO₂ catalyst was found to have the highest activity and longest life among the catalysts examined. The activity of the TiO₂ZrO₂ catalysts depended upon the content of TiO₂. At the contents of TiO₂ from 58 to 90 mole%, the TiO₂ZrO₂ catalysts exhibited high activity, and these catalysts were proven to contain TiZrO₄ crystal. From the study of the XRD peak intensity of the TiZrO₄ crystal, it was highest on the TZ-58 which contained 58 mole% of TiO₂, and decreased with increasing the content of TiO₂. Furthermore, the conversion of CFC113 measured at 673 K was highest at TZ-58, and decreased gradually with increasing TiO₂ content. Therefore, the TiZrO₄ crystal influences the activity of decomposition of CFC113. However, the TiO₂ZrO₂ catalyst was gradually deactivated during the reaction due to the elimination of titanium atoms. A good relationship was found between the activity on TiO₂ZrO₂ catalyst and bond energy of CCl in the compounds of chlorofluorocarbons and hydrochlorocarbons, suggesting that the rate controlling step was the cleavage of CCl bond.     

Field evaluation of UHF radio propagation for an ITS safety system in an urban environment

Roadside-to-vehicle and vehicle-to-vehicle communication systems have been proposed as part of ITS development to help achieve vehicle safety and realize more secure road traffic environments. In this article we first introduce several typical applications and their radio range requirements for vehicle safety communication systems to clarify the technical point of view. Then we show some field experiment results in an urban area in Tokyo to investigate and verify the radio propagation characteristics and the quality of communications by using a wireless radio prototype system. Finally, we conclude that the current prototype system has potential to fulfill the radio range requirements of vehicle safety communications, but there are still lots of issues that need to be addressed.     

BIO SKIN Urban Cooling Facade

Numbering 65, Nikken Sekkei's research group is the size of many substantial practices. Tomohiko Yamanashi, Tatsuya Hatori, Yoshito Ishihara and Norihisa Kawashima at Nikken Sekkei Ltd and Katsumi Niwa at the Nikken Sekkei Research Institute (NSRI) describe the unique collaborative processes that make the NSRI's contribution essential to any Nikken projects requiring the development of cutting-edge technology or urban planning proposals. Here, they detail the development of BIO SKIN, an innovative facade system developed for the Sony Research and Development Center in Tokyo, which addresses the urban heat island effect, one of the main environmental research areas of the NSRI. Copyright © 2011 John Wiley & Sons, Ltd.     

Influence of cardiac motion on diffusion-weighted magnetic resonance imaging of the liver

Purpose  

To assess cardiac motion-induced signal loss in diffusion-weighted magnetic resonance imaging (DWI) of the liver using dynamic DWI.     

Detection of moving object by mobile stereo omnidirectional system (SOS)

Moving object detection with a mobile image sensor is an important task in robotics and computer vision, when considering the practical use of robotics in human environments. In this paper, we propose a robust method that detects moving objects in the environment using the omnidirectional depth information obtained by a mobile Stereo Omnidirectional System (SOS). In order to detect only the moving objects within the depth image that are obtained by a sensor in motion, we first estimate the ego‐motion of the sensor, and generate a predicted depth image for the current time from the depth obtained at the previous time by only considering the ego‐motion of the sensor. Then the predicted depth image is compared with the actual one obtained at the current time, and the inconsistent regions are detected as moving objects. When the sensor moves, occlusions will occur in the scene and they will cause false detections. However, these false detections can be suppressed by estimating the occlusion regions using the ego‐motion parameters of the sensor and the jump edges in the depth image. The effectiveness of the method is shown with experimental results for a real environment. © 2005 Wiley Periodicals, Inc. Electr Eng Jpn, 152(3): 29–38, 2005; Published online in Wiley InterScience ( www.interscience. wiley.com ). DOI 10.1002/eej.20155     

Development of a colon delivery capsule and the pharmacological activity of recombinant human granulocyte colony-stimulating factor (rhG-CSF) in beagle dogs

A peroral dosage form was examined to deliver recombinant human granulocyte colony-stimulating factor (rhG-CSF) to the colon in beagle dogs. A new gelatin capsule with its inside surface coated with ethylcellulose was prepared for this purpose. RhG-CSF was dissolved with propylene glycol and was filled in the capsule. Several kinds of ethylcellulose-gelatin capsules with an ethylcellulose layer of thickness 46 to 221 mm were used. The capsule was filled with propylene glycol solution containing fluorescein as an absorption marker, castor oil derivative and citric acid. The hardness of the capsule was tested after the gelatin layer was dissolved using a hardness tester and was dependent on the thickness of the ethylcellulose layer of the capsule. The time, Tmax, at which plasma fluorescein level reaches its maximum following oral administration of ethylcellulose capsules was used as a parameter for the in-vivo disintegration time of the ethylcellulose capsule into the colon. Capsules of thickness 84 mm with a Tmax of 4-6 h were filled with rhG-CSF solution containing fluorescein and were administered to dogs. After administration, blood samples were collected for 96 h and the blood total leucocyte (BTL) counts were measured as a pharmacological index of rhG-CSF. The maximum BTL count appeared at 10 h then gradually decreased and returned to its normal level at 48 h. These results suggest the usefulness of ethylcellulose capsules for the delivery of rhG-CSF to the colon and the possibility of a new oral rhG-CSF dosage form has been elucidated.     

Synchronous Composite Packet Switching-A Switching Architecture for Broadband ISDN

A new switching architecture for broadband ISDN, "Synchronous Composite Packet Switching (SCPS)," is proposed and evaluated. It efficiently integrates circuit and packet switching functions on a single switching system and accommodates very high speed-up to several tens of Mbit/s-communication services, such as very high speed bursts of data, still picture, and motion video, as well as 64 kbit/s or less voice and data services. The SCPS system comprises plural switch modules and plural Very high speed synchronous loops. In the SCPS system, messages on plural circuit switched channels are assembled into quasi-packets, called "composite packets," and switched synchronously between switch modules, maintaining complete time transparency and short absolute delay time. A system parameter design to obtain high system efficiency and appropriate system modularity is explained, and an example for a very large capacity transit switch of 4 Gbit/s throughput is presented. System implementation problems to realize the SCPS principle, such as efficient implementation of the composite packet assembling and loop transmission functions, are investigated and an experimental system constructed for circuit switching part is presented. The most remarkable characteristic of the SCPS is that it efficiently integrates64 times nkbit/s circuit switching with packet switching. Moreover, the SCPS system retains compatibility with existing networks and the possibiliy of evolution toward a future broadband ISDN. On the basis of the above investigations and experimental system construction, the authors conclude that the SCPS is one of the most practical switching architectures for the coming broadband ISDN era.