The measurement of hydrogen activities in molten copper using an oxide protonic conductor

We have developed a hydrogen sensor for in situ measurements of hydrogen activities in molten copper. The sensor consists of a concentration cell utilizing a proton conductor, CaZr_0.9In_0.1O_3-δ, as the solid electrolyte. The electromotive force (emf) of the cell was generated by both hydrogen and oxygen activity gradients across the cell in a high-temperature region simulating the fire refining processes of copper. However, accurate hydrogen activity in molten copper could be evaluated from the emf if oxygen activity in molten copper was determined simultaneously by another concentration cell and if the hydrogen and the oxygen activities at the reference electrode were known. The performance of the sensor was studied under various conditions. The observed good response and reliability of the sensor show that it should be a powerful tool for improvement of the fire refining process of the molten copper. Theoretical treatment of the calculation of the emf of the concentration cells using a mixed ionic conductor, i.e., protonic and oxide ionic conductor, as solid electrolytes is also discussed briefly.     

The effect of excess gate current on input impedance of a JFET amplifier

When JFET is used as an amplifier, it should be regarded that the effect of excess gate current on the input impedance is changed by gain of the amplifier. The input impedance or conductance with gain of the JFET amplifier is experimentally analyzed applying small signal equivalent circuit.     

间歇吸附器内活性炭吸附水中微量三氯甲烷——孔扩散模型和表面扩散模型

<正> 近10多年来,各国对饮水氯化处理中的副作用研究甚多．现已发现氯化饮水中含有不同 性质的有机物约300种“’,其中三卤甲烷含量突出,而活性炭吸附是脱除其中不同性质有机物 的有效方法’‘－‘’．一般情况下,溶质在吸附剂内的扩散过程是整个吸附过程的控制步骤．但目 前文献仅限干研究活性炭吸附三卤甲烷的能力,很少涉及与吸附速率有关的有效扩散系数．     

New catalytic functions of Pd–Zn, Pd–Ga, Pd–In, Pt–Zn, Pt–Ga and Pt–In alloys in the conversions of methanol

Pd and Pt supported on ZnO, Ga₂O₃ and In₂O₃ exhibit high catalytic performance for the steam reforming of methanol, CH₃OH+H₂OCO₂+3HH₂, and the dehydrogenation of methanol to HCOOCH₃, 2CH₃OHHCOOCH₃+2HH₂. Combined results with temperature-programmed reduction (TPR) and XRD method revealed that Pd–Zn, Pd–Ga, Pd–In, Pt–Zn, Pt–Ga and Pt–In alloys were produced upon reduction. Over the catalysts having the alloy phase, the reactions proceeded selectively, whereas the catalysts having metallic phase exhibited poor selectivities.     

Optimization of groove dimensions in herringbone-grooved journal bearings for improved repeatable run-out characteristics

Optimization of groove dimensions in herringbone-grooved journal bearings is discussed in this paper with aims to design precision spindles with improved run-out characteristics. An evaluation index to represent the magnitude of the amplitude of repeatable run-out is firstly introduced and the groove design parameters are theoretically discussed to minimize the index value with taking the stable operation condition of the bearing into account. The comprehensive parameter research reveals a guideline for the design of the groove configuration for good run-out characteristics. Experiments with a shaft with grooves designed along the proposed guideline show that the amplitude of repeatable run-out reduces to about half of that of a bearing with currently designed groove configurations, thus confirming validity of the above guideline.     

Calculation of mechanical behaviors of shape memory alloy under multi-axial loading conditions

In this paper, for the calculation of the deformation behaviors of shape-memory alloy under multi-axial loading conditions with temperature changes, a two-dimensional mechanical model of polycrystalline shape memory alloy is constructed on the bases of the crystal plasticity and the deformation mechanism of shape memory alloy. In such a model, the orientation of crystal grain in the polycrystal and the loading direction can be considered. The deformation behaviors under some complex loading conditions are calculated with the model, and the results show that they are in good qualitative agreement with the experimental results.     

Eu-doped LiF-SrF2 eutectic scintillators for neutron detection

Eu²⁺ 0.05%, 0.1%, and 0.2% activated LiF-SrF₂ eutectic scintillators were prepared by the Bridgman method using ⁶Li enriched (95%) raw material. The α-ray-induced radio luminescence spectra showed intense emission peak at 430 nm due to an emission from Eu²⁺ 5d-4f transition in the Eu:SrF₂ layers. When excited by ²⁵²Cf neutrons, all the samples exhibited almost the same light yields of 5000-7000 ph/n with a typical decay times of several hundreds ns.     

Wind-flow measurement over the Subaru Telescope

Wind flows over the 8.2-m Subaru Telescope at Mauna Kea in Hawaii were analyzed with a correlation method. Three or four wind flows were detected from our measurements. Spatial and temporal resolution of the wind-flow analysis across the 8.2 m pupil were investigated experimentally. A three-dimensional spatiotemporal-frequency analysis was also applied to the wind-flow data.     

Simple and comprehensive two-dimensional reversed-phase HPLC using monolithic silica columns

Simple and comprehensive two-dimensional (2D)-HPLC was studied in a reversed-phase mode using monolithic silica columns for second-dimension (2nd-D) separation. Every fraction from the first column, 15 cm long (4.6-mm i.d.), packed with fluoroalkylsilyl-bonded (FR) silica particles, was subjected to the separation in the 2nd-D using one or two octadecylsilylated (C(18)) monolithic silica columns (4.6-mm i.d., 3 cm). Monolithic silica columns in the 2nd-D were eluted at a flow rate of up to 10 mL/min with separation time of 30 s that meets the fractionation every 15-30 s at the first dimension (1st-D) operated at a flow rate of 0.4-0.8 mL/min. Three cases were studied. (1) In the simplest scheme of 2D-HPLC, effluent of the 1st-D was directly loaded into an injector loop of 2nd-D HPLC for 28 s, and 2 s was allowed for injection. (2) Two six-port valves each having a sample loop were used to hold the effluent of the 1st-D alternately for 30 s for one 2nd-D column to effect comprehensive 2D-HPLC without the loss of 1st-D effluent. (3) Two monolithic silica columns were used for 2nd-D by using a switching valve and two sets of 2nd-D chromatographs separating each fraction of the 1st-D effluent with the two 2nd-D columns alternately. In this case, two columns of the same stationary phase (C(18)) or different phases, C(18) and (pentabromobenzyloxy)propylsilyl-bonded (PBB), could be employed at the 2nd-D, although the latter needed two complementary runs. The systems produced peak capacity of approximately 1000 in approximately 60 min in cases 1 and 2 and in approximately 30 min in case 3. The three stationary phases, FR, C(18), and PBB, showed widely different selectivity from each other, making 2D separations possible. The simple and comprehensive 2D-HPLC utilizes the stability and high efficiency at high linear velocities of monolithic silica columns.