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Li Xi Zuoyan Peng Wei Fan Kui Guo Gu Jianmin Muyu Zhao Wu Guoqiang 《Materials Science and Engineering: B》1996,40(2-3):147-152
SrMgxTi1 - xO3 nanocrystals (x = 0.1–0.6) were synthesized by the stearic acid gel method. Powder samples were characterized by X-ray diffraction and X-ray photoelectron (XP) spectroscopy. The results showed that the lattice parameter a and the O 1s XP spectrum changed not only with the Mg content x but also with the grain size d of the samples. The conductivity of a thick film specimen fabricated on an aluminium oxide wafer was investigated in a nitrogen—oxygen atmosphere. 相似文献
14.
Porous silica glass was prepared by sol-gel process from tetraethoxysilane (TEOS). The effects of solvents (water, ethanol), drying condition, heat treatment temperature on specific surface area and pore size distribution of porous silica were investigated. Gelation process accelerates with an increase of H2O content, while retards with the increase of ethanol amount. Structure changes during heat treatment were studied by means of DTA, XRD. TEM micrographs show that the gel particles shrink after heated at 500°C, thus the average pore size decreases. 相似文献
15.
We present a method that is useful in the estimate and assessment of heat capacity data. The approach is based on an analysis of the logarithmic average of the phonon frequencies. In this quantity, that may be easily derived from experimental data on the vibrational entropy, the influence of atomic masses can be exactly accounted for even in polyatomic solids. Our method is applied to Li2O, Na2O, K2O, Rb2O, and Cs2O. In particular, literature data for K2O are critically examined. 相似文献
16.
辐射制备缓释抗癌药阿糖胞苷的研究 总被引:1,自引:0,他引:1
报告了甲基丙烯酸酯类在室温下进行辐射聚合制备缓释抗癌药阿糖胞苷(Ara-C)的研究结果。结果表明,不仅亲水性单体,而且疏水性单体(包括MMA、EMA和BMA等)都可用于辐射固化。加入到亲水性基质中的疏水性单体可以延缓药物的离体释放,其顺序是MMA<EMA<BMA,央MMA-HEMA共聚物中,Ara-C释放率随着基质中的MMA含量增加而降低。药物的离体释放还受许多困素的控制,结果显示:药物释放量随着 相似文献
17.
In this paper, the CdxHg1-xTe (x=1-0.7) doped silica glass was prepared through two step sol-gel process and in-situ growth technique from tetraethoxysilane (TEOS), cadmium acetate, mercury acetate and telluric acid. The influence of various factors on the glass was studied. The structure of the microcrystals was investigated by XRD. The absorption and transmittance spectrum of the composite showed that the shift of absorption edge was in conformity with the quantum size effect. The third-order nonlinear optical susceptibility χ(3) was measured by the degenerate four wave mixing (DFWM). The values of χ(3) was in the range of 10-11-10-12 MO esu at wavelength of 1.06 μm. 相似文献
18.
A polymerizable photoredox system consisting of 4-methacryl oxbenzophenone (MABP) and N,N-dimethlaminoethyl methacrylate (DMAEMA) used for the photopolymerization of acrylonitrile (AN) was studied. It was found that the polymerization rate is proportional to the 0.93th power for the AN concentration, the 0.28th power for the MABP concentration, and the 0.25th power for the DMAEMA concentration. The overall activation energy of the polymerization obtained is 30.43 kJ/mol. The recorded ESR spectrum indicates that the excited-state MABP abstraets hydrogen mainly from the methyl group of the dimethylamino moiety. The comparison of the initiation ability of polymeric MABP or polymeric DMAEMA with their monomeric forms has also been done and the results indicate that in good solvents P (MABP) has a much higher initiation ability than that of monomeric MABP, but monomeric DMAEMA and P (DMAEMA) display almost the same initiation ability. In poor solvent, the initiation ability of P (MABP) is not so obviously higher than that in good solvents. The result of UV analysis of P (AN) initiated by the MABP–DMAEMA system indicates that both MABP and DMAEMA not only initiate the photopolymerization of AN, but also enter into P (AN) polymer chains. © 1994 John Wiley & Sons, Inc. 相似文献
19.
BaTiO3 multilayer capacitors with a nominal capacitance of 3.5nF have been carefully measured using the thermally stimulated current (TSC) technique. When a 300V polarization voltage is applied at room temperature, a new TSC peak appeared in defective sample A after it has been immersed in water. No new peak was found in good-quality sample B after a similar treatment. The accelerated life test shows that sample A hasa much shorter life than sample B in terms of insulation resistance. 相似文献
20.
With the aid of a double-tilt holder in a transmission electron microscope, a new method for a rapid and precise determination of the misorientations of a large number of subgrain or grain boundaries is given in this article. By use of the method, the continuous recrystallization can be rapidly and precisely evaluated when compared to the other conventional methods. 相似文献