Pt-Fe2O3复合纳米陶瓷的室温氢敏性能研究

以Fe2O3纳米粉与铂粉为原料,通过压片与烧结,制备出了Pt-Fe2O3复合纳米陶瓷。SEM等分析表明,该陶瓷中存在大量纳米尺寸的孔洞,其Fe2O3晶粒粒径仅为30nm。以该陶瓷材料制备的氢气传感器,在室温下对氢气具有显著的响应。对氮气中5%氢气,其电阻下降90余倍,响应时间和在空气中的恢复时间分别约为20s和30s。为了揭示其室温氢敏机理,将氮气中氢气的浓度由5%降低至0,发现该陶瓷的电阻不随氮气中氢气浓度的下降而发生变化。该结果表明,Pt-Fe2O3复合纳米陶瓷的室温氢敏现象是由于氢在Pt的催化作用下与吸附氧在室温下发生化学反应而引起的。与之前报道的TiO2基陶瓷材料的室温氢敏现象相比,Fe2O3基陶瓷材料的室温氢敏性能与机理均存在显著的差别,因此有必要对金属氧化物半导体基陶瓷材料的室温氢敏现象进行深入系统的研究。     

定-转子反应器制备LiFe1-xMxPO4 (M= Mn, Ni)粉体及其性能研究

采用具有高效传质和微观混合性能的定-转子反应器制备了LiFe_1-xMn_xPO₄ (x=0.0, 0.1, 0.2, 0.3)和LiFe_1-xNi_xPO₄ (x=0.00, 0.03, 0.05, 0.07)粉体,分别用作正极材料制成电池后,采用电池测试系统测定了电池的电化学性能随温度的变化规律。结果表明,粉体颗粒呈类球形,尺寸分布均匀,粒径范围为5~10 μm,Mn和Ni的掺杂没有改变粉体的晶体结构。以LiFe_0.8Mn_0.2PO₄和LiFe_0.95Ni_0.05PO₄两种组成的粉体性能最好,在倍率0.1 C下,所得电池的首次充放电比容量在室温和50 _oC时,分别为153.2和155.7 mAh/g,及156.4和160.4 mAh/g;100次充放电循环后电池的容量保持率分别为95.4和96.5%,及93.8和95.0%。借助具有过程强化作用的定-转子反应器制备的Mn和Ni掺杂LiFePO₄正极材料的电性能得到显著提高。原因是定-转子反应器一方面可以制备颗粒尺寸均匀的粉体,另一方面又可使掺杂的Mn和Ni在粉体颗粒中均匀分布,两者同时提高了电池中Li₊的扩散速率,进而提高了锂离子电池的电化学性能和高温电性能。     

单晶空心叶片榫头再结晶行为研究

为了更好的研究温度和载荷对镍基单晶空心叶片榫头位置的再结晶行为的影响,本实验首先对单晶试样施加不同载荷,然后在不同的温度下进行固溶处理,处理后的试样在光学显微镜和扫描电子显微镜进行组织分析。结果表明：不同载荷下的DD5单晶试样经1230℃/4h,ac热处理后,随着载荷增加,受载荷影响区域深度增加,该区域枝晶间空间增大,未溶解的共晶组织周围弥散分布大量与γ相共格的γ′相颗粒物,γ′相粒子以胞状形式重新析出,尺寸和深度随载荷的增大而增加;经1315℃/4h,ac.热处理后发生再结晶现象,随着载荷增加再结晶区域增大,受载荷影响区域的枝晶干发生钝化,枝晶干与枝晶间界限消失,再结晶晶粒间存在γ/γ′共晶组织。     

Thermodynamic Calculation of Phase Equilibria in the C-Mo-Zr System

The C-Mo-Zr system was assessed by means of the CALPHAD approach. All of the phase equilibria available from the literature were critically reviewed. The liquid was modeled as substitutional solution phase, while the carbides including fcc-(Mo,Zr)C_1?x, bcc-(Mo), bcc-(Zr), hcp-Mo₂C, hcp-(Zr) and η-MoC were described by using corresponding sublattice models. The laves-Mo₂Zr and shp-MoC phases were considered as binary compounds with no solubility for the third component. The existence of ternary phase was not reported in this system. The modeling of C-Mo-Zr ternary system covers the entire composition and temperature ranges, and a set of self-consistent thermodynamic parameters for the C-Mo-Zr system was systematically optimized. Comprehensive comparisons between the calculated and reported phase diagram data show that the reliable information is satisfactorily accounted for by the present modeling. The liquidus projection and reaction scheme of the C-Mo-Zr system were also generated based on the present thermodynamic assessment.     

Fatigue behaviour and life estimation of Mg/Al ultrasonic spot weld bonding welds

Mg/Al dissimilar joints with favourable static and dynamic mechanical properties were obtained utilising ultrasonic spot welding and ultrasonic spot weld bonding technology. The fatigue behaviour, fatigue failure mode, and typical fatigue fracture surface morphology of Mg/Al ultrasonic spot welding and ultrasonic spot weld bonding joints were compared and observed to get a better understanding of the fatigue failure mechanism. In general, the Mg/Al ultrasonic spot weld bonding joint exhibited better fatigue performance than the ultrasonic spot welding joint. The two kinds of joints presented different fatigue failure modes with decreasing applied load level. A fatigue life prediction model was established, and the fatigue life prediction results were in good agreement with the experimental fatigue results.     

Synergistic effect and drug‐resistance relief of paclitaxel and cisplatin caused by Co‐delivery using polymeric micelles

Combination therapy of paclitaxel (PTX) and cisplatin has been used to treat several cancers in clinic practice, but often causes serious systemic toxicity. Co‐delivery of PTX and cisplatin by means of polymeric micelles can reduce the systemic toxicity, but often needs two carrier polymers because of the solubility difference between them. Therefore, a strategy is developed to co‐deliver both PTX and cisplatin with only one carrier polymer by encapsulating PTX in the core of a polymeric micelle and cross‐linking the micelle with cisplatin. The PTX and Pt contents in the micellar formulation M(PTX/Pt) were 10 and 14 wt %, respectively. In vitro cytotoxicity of M(PTX/Pt) was evaluated via 3‐(4,5‐dimethylthiazol‐2‐yl)?2,5‐diphenyltetrazolium bromide assay in comparison with PTX and its micelle M(PTX), cisplatin and its micelle M(Pt), and PTX/cisplatin combination towards human hepatocarcinoma (SMMC‐7721) cells and chemoresistant SMMC‐7721(SMMC‐7721R) cells. The M(PTX/Pt) exhibited a high synergistic effect in the inhibition of cell growth and proliferation of both SMMC‐7721 and SMMC‐7721R cells and showed reasonable drug‐resistance relief. The synergistic effect and resistance relief were further supported or explained by intracellular uptake measurement of dye‐labeled micelles and by the confocal laser scanning microscopy observation of SMMC‐7721 and SMMC‐7721R cells treated with various formulations. Therefore, M(PTX/Pt) micelles were expected to find potential application in cancer chemotherapy. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41440.     

塑石假山三维钢筋网片数字化施工技术

以北京某在建主题乐园大型塑石假山为例,介绍了塑石假山三维钢筋网片数字化施工技术.通过3D扫描假山实体模型,获取数字信息模型,利用BIM技术进行塑石假山的结构设计及网片设计,自主编写钢筋自动弯曲机作业程序,完成钢筋的双向弯曲,实现网片钢筋生产数字化自动加工.解决了机械弯曲钢筋加工偏差大、钢筋组装定位不准确、网片造型还原度差等难题,实现了钢筋数字化生产、快速校正、精准焊接与组装,具有极大的推广应用价值.     

多元化课外实践教学项目促进知识的综合运用和创新

欲达到将所学知识和实际应用紧密结合这一目的,实践教学环节最为重要。本文首先分析了化学工程与工艺专业实践教学环节存在的不足,然后探讨了课外实践教学项目对人才培养的积极作用。多元化课外实践教学项目的实施,促进了学生知识综合运用能力的提高和创新活力的释放,取得了较好效果。     

离散涂层对TC4钛合金微动磨损性能影响

采用电火花强化技术和IBED技术复合处理TC4钛合金,生成了离散复合强化层。强化层主要由电极材料和基体材料反应生成的化合物组成。强化层微动磨损体积损失是未处理试样的1/40,磨损机制为片层剥落和局部颗粒剥落。     

磁场作用下AZ91镁合金焊接接头固溶时效后的组织与性能

在外加纵向交流磁场作用下,对AZ91镁合金板进行钨极氩弧焊(TIG),并对焊接接头固溶时效处理后的组织性能进行了分析。结果表明,固溶时效后,AZ91镁合金焊接接头组织由基体α-Mg和β-Al12Mg17两相组成,大量β-Mg17Al12相弥散析出。随磁场电流增加,焊接接头晶粒先细小后粗大;磁场电流为1.5 A时,晶粒最为细小,大量β-Mg17Al12相在晶界晶内弥散析出,接头显微硬度、抗拉强度和塑性最好,耐蚀性最差。