Impact Fracture of Thermally Tempered Glass Helicopter Windshields

In-service fracture of helicopter windshields was studied. Simulated catastrophic fracture tests were conducted by firing alumina and steel spheres onto stationary tempered and as-received glass panels. The results were studied by Hertzian analysis and modified Auerbach's relations. Thermally tempered glass shows much higher impact resistance than that estimated from superposition of residual stresses. Subcritical impact sites exhibit slow crack growth in tempered plates, eventually leading to fracture of the entire plate.     

Fractoemission from Lead Zirconate-Titanate

We present measurements of the electron, positive ion, and photon emission accompanying the fracture in vacuum of poly-crystalline 95/5 lead zirconate-titanate. The intensities of the charged-particle components of this fractoemission are shown to depend strongly on the direction (relative to the direction of fracture) and magnitude of polarization. The most intense emission is observed when the fracture surfaces are perpendicular to the polarization direction. The emission intensity increases monotonically with polarization. These results are interpreted in terms of a model involving charge separation on the fracture surfaces leading to a microdischarge during fracture. Implications to the interpretation of triboluminesence effects are discussed.     

Stress in Leached Phase-Separated Glass

When a phase-separated glass is leached, stresses develop because of release of thermal stresses, creation of surface area, ion exchange, and hydration. Analyses are presented for the thermal stresses, including the portion that develops on cooling from the heat-treatment temperature to the setting temperature of the less viscous phase. During leaching, the interfacial energy of the residual phase increases, so that phase tends to contract. A more important effect is the contraction caused by removal of alkali and B₂O₃ from the residual phase during leaching. The extent of removal of B₂O₂ decreases with heat-treatment time, t_H , because the scale of the microstructure increases as t^1/3_H. The change in residual B₂O₂ content with t_H is shown to be consistent with diffusion-controlled ion exchange. The dependence of stress on t_H in partially leached glasses, measured by Drexhage and Gupta, results principally from the change in extent of ion exchange; the reduction in surface area with increasing t_H also has a significant effect on the stresses.     

The function of bleaching earths in the processing of palm,palm kernel and coconut oils

The results presented in the literature, which attempt to elucidate the mechanisms by which triglyceride oils are bleached by earths, are reviewed. The impact of this work and how the mechanistic proposals affect changes in oil properties are considered, with particular emphasis on the needs of the palm oil processor. Important properties include color, metals and phosphorus content and oxidative stability of the oil. Investigations made in our own laboratories have been aimed at elucidating the effect of varying physical and chemical properties of the bleaching earth on the quality of bleached and deodorized oils. Techniques used in this work are pore-size distribution, surface area, scanning and transmission electron microscopy and a variety of chemical and X-ray analysis methods. The ability to vary such parameters in montmorillonite clays by alteration of process conditions to give materials with specific performance characteristics is demonstrated. Comparisons are made between acid-activated montmorillonites and other clay types.     

Identification of a class of nonlinear state-space models using RPEtechniques

The RPE (recursive prediction error) method in state-space form is developed in the nonlinear systems and extended to include the exact form of a nonlinearity, thus enabling structure preservation for certain classes of nonlinear systems. Both the discrete and the continuous-discrete versions of the algorithm in an innovations model are investigated, and a nonlinear simulation example shows a quite convincing performance of the filter as combined parameter and state estimator     

Optical networks for local loop applications

Some of the options for optical technology within the local loop environment are examined. In particular, passive shared access networks have been considered in some detail. These networks show great promise for delivering existing telephone services to small to medium business customers (4-30 lines) economically by the early 1990s. Extending fiber to the home will also be possible by virtue of a similar passive network infrastructure for customers requiring new broadband services beyond the single telephone line. For one-line plain old telephone service (POTS) customers, an intermediate approach of terminating the fiber network at the final network distribution point, with copper retained for the final leg, may be used prior to the provision of broadband services. A key feature of the passive optical network architecture is the use of wavelength-division multiplexing (WDM) as an upgrade strategy, allowing graceful upgrading from telephone services to multichannel high-definition television (HDTV) on gigabit/second bearers and full two-way switched broadband services employing wavelength routing across the network     

Long-term transients in a reactor under forced concentration cycling

In the approach to a cycle-invariant state in the forced feed concentration cycling of the CO oxidation over a NiO catalyst, a very long transient has been observed lasting 80 ks or more. This transient appears to be associated only with CO pretreatment of the catalyst and is not a general phenomenon. The slow convergence to the cycle-invariant state reported in certain modelling calculations in the literature appears to have a different cause.