Adsorptive studies of hazardous dye Tropaeoline 000 from an aqueous phase on to coconut-husk

This contribution presents result pertaining to the adsorptive removal of water-soluble hazardous dye Tropaeoline 000, on to a low cost adsorbent-coconut-husk and its efficiency in the dye colour sorption was compared with activated carbon (AC). The results obtained from the batch experiments revealed the ability of the coconut-husk to remove the Tropaeoline 000 dye. The adsorption of dye was carried out at different pH, temperatures, amount of adsorbent, contact time, concentration of adsorbate (initial dye concentration) and particle size. The adsorption studies revealed that the ongoing adsorption validates both Langmuir and Freundlich adsorption isotherm at temperatures 30, 40 and 50 degrees C. The adsorption isotherm data was also employed to calculate thermodynamic parameters like DeltaG degrees , DeltaH degrees and DeltaS degrees . The negative values of DeltaG degrees indicate that the dye adsorption process is a spontaneous in nature. The positive value of DeltaH degrees shows the endothermic nature of AC/coconut-husk system whereas negative value of DeltaH degrees indicates that the exothermic nature of AC/coconut-husk. The adsorption was found to undergo via a pseudo-second order adsorption kinetics and the results revealed that coconut-husk, an agricultural waste, proved to be an excellent low cost adsorbent.     

The importance of strong carbon-metal adhesion for catalytic nucleation of single-walled carbon nanotubes

Density functional theory is used to show that the adhesion between single-walled carbon nanotubes (SWNTs) and the catalyst particles from which they grow needs to be strong to support nanotube growth. It is found that Fe, Co, and Ni, commonly used to catalyze SWNT growth, have larger adhesion strengths to SWNTs than Cu, Pd, and Au and are therefore likely to be more efficient for supporting growth. The calculations also show that to maintain an open end of the SWNT it is necessary that the SWNT adhesion strength to the metal particle is comparable to the cap formation energy of the SWNT end. This implies that the difference between continued and discontinued SWNT growth to a large extent depends on the carbon-metal binding strength, which we demonstrate by molecular dynamics (MD) simulations. The results highlight that first principles computations are vital for the understanding of the binding strength's role in the SWNT growth mechanism and are needed to get accurate force field parameters for MD.     

Structural Performance of Hybrid GFRP/Steel Concrete Sandwich Panels

Precast/prestressed concrete sandwich panels consist of two concrete wythes separated by a rigid insulation foam layer and are generally used as walls or slabs in thermal insulation applications. Commonly used connectors between the two wythes, such as steel trusses or concrete stems, penetrate the insulation layer causing a thermal bridge effect, which reduces thermal efficiency. Glass fiber-reinforced polymer (GFRP) composite shell connectors between the two concrete wythes are used in this research as horizontal shear transfer reinforcement. The design criterion is to establish composite action, in which both wythes resist flexural loads as one unit, while maintaining insulation across the two concrete wythes of the panel. The experiments carried out in this research show that hybrid GFRP/steel reinforced sandwich panels can withstand out-of-plane loads while providing resistance to horizontal shear between the two concrete wythes. An analytical method is developed for modeling the horizontal shear transfer enhancement using a shear flow approach. In addition, a truss model is built, which predicts the panel deflections observed in the experiments with reasonable accuracy.     

Response of Multilayer Foundation System beneath Railway Track under Cyclic Loading

For an efficient and economical design of a railway track system, it is necessary to understand the behavior of each track component with special reference to ballast and subgrade, which play a pivotal role in distributing the large, cyclic wheel loads longitudinally, laterally, and vertically away from the wheel contact area on the rail surface to the underlying soil strata. This paper presents an analytical model of a track-ballast-subgrade system with different formation soils such as dense uniform sand, stiff clay, loose sand, and soft clay modeled by using a mass-spring dashpot system with two degrees of freedom. This represents the varying energy distribution through ballast and subgrade in the vertical direction. Results are presented in the form of time-displacement response profiles for both the ballast and subgrade layers. In addition, the magnification factors for displacements with variation in subgrade soils for cyclic loading frequencies are reported. It is observed that the results obtained from the present analysis follow the experimentally observed trends already available in the literature.     

Posttraumatic distress and physical functioning: A longitudinal study of injured survivors of community violence.

This study examines the cross-lagged relationships between posttraumatic distress symptoms and physical functioning, using a sample of 413 persons who were hospitalized for injuries resulting from community violence. Posttraumatic distress was assessed at 1 week, 3 months, and 12 months postinjury, and posttraumatic physical functioning was assessed at 3 months and 12 months. Structural equation modeling was used to assess the prospective relationship between posttraumatic distress symptoms and physical functioning while controlling for demographic characteristics and objective measures of injury severity. Results indicate that posttraumatic distress and physical functioning are reciprocally related. Individuals with high levels of psychological distress at 1 week posttrauma have worse physical functioning at 3 months. Psychological distress at 3 months was not significantly associated with subsequent change in physical functioning at 12 months. Individuals with poor physical functioning at 3 months had higher than expected levels of psychological distress at 12 months. These findings demonstrate a reciprocal relationship between physical and mental health following traumatic injury. Interventions targeting physical recovery may influence subsequent mental health, and therapies aimed at improving early mental health may also have long-term benefits for physical recovery. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Fluctuation induced conductivity of polycrystalline MgB<Subscript>2</Subscript> superconductor

We report fluctuation-induced conductivity (FIC) of the polycrystalline MgB₂ superconductor in the presence of magnetic field. The results are described in terms of the temperature derivative of the resistivity, dρ/dT. The dρ/dT peak temperature observed for H = 0 Tesla at 39 K remains very distinct under applied fields of 6 Tesla and 8 Tesla at 22 and 20 K respectively. Aslamazov and Larkin (AL) equations are used to explain the anisotropic nature of the polycrystalline MgB₂. The effective coherence length, ξ _p (0) determined experimentally is 55.17 Å, which roughly matches with previously reported experimental work.     

Stability enhancement of induction generator–based series compensated wind power plants by alleviating subsynchronous torsional oscillations using BFOA‐optimal controller tuned STATCOM

In this paper, a STATCOM (static synchronous compensator) is used to encounter the potential SSR (subsynchronous resonance) observed by IG (Induction Generator) based series compensated wind farms. The basic controller used for STATCOM control is identical to that of the literature. An idea of a unique meta‐heuristic swarm‐based optimization technique called BFOA (bacterial foraging optimization algorithm) based optimal‐controller is introduced for optimal parameter selection of the basic controller used in the control scheme of the STATCOM. The investigation is carried out with 500 MW IG‐based wind farm exposed to three‐phase LLL‐G fault close to the PCC (point of common coupling) and implemented with MATLAB in both steady and transient states for the three different cases, namely, without STATCOM, with the basic STATCOM controller, and in the presence of the proposed BFOA‐optimal controller‐based STATCOM. In both the states, the observed eigenvalues of the test system, together with the time domain results of the generator rotor dynamics for three distinct cases, reveals the effectiveness of the suggested BFOA‐optimal controller tuned STATCOM in mitigating the potential SSR.     

New composites based on short melamine fiber reinforced epdm rubber

Melamine fibre is a new category of advanced synthetic fiber having superior heat and flame resistance with decomposition temperature above 350°C. It suitability as a reinforcing fiber for ethylene propylene diene terpolymer, abbreviated as EPDM rubber, where ‘M’ stands for polymethylene chain, was investigated. It has been observed that tensile strength and stress at 100% strain of EPDM‐melamine fiber composites increase with the addition of a three‐component dry bonding system, comprising hexamethylene tetramine (hexa), resorcinol, and hydrate silica, abbreviated HRH system. Moreover, the fiber‐filled composites anisotropy in stress‐strain properties due to preferential of the short fibers along the milling direction (longitudinal), which is substantiated by the results of swelling and fractography studies. Aging causes an increase in the modulus, tensile strength and hardness of the composites. The fractographs show an increase in interfacial adhesion between the fibers and the matrix during aging, which is further confirmed by the reduction in tan δ peak height of the aged composites during dynamic mechanical studies. Atomic Force Microscopy (AFM) studies reveal the formation of an interphase with the addition of bonding agents and a better fiber‐matrix adhesion due to aging. AFM images also confirm the role of dry bonding systems in improving the fiber‐matrix adhesion of the aged vulcanizates. The composite modulus has been theoretically calculated using the well‐known Halpin‐Tsai equation. It is found that in the transverse direction, observed modulus values are greater than the calculated values, while in the longitudinal direction, the experimental modulus values are found to be lower than the calculated values for both unaged and aged composites owing to some degree of anisotropy in fiber orientation.     

Study of Corrosion Behavior and In Vitro Bioactivity of Single NbSi2 and Duplex NbSi2/Nb5Si3 Coatings on Nb Substrates for Biomedical Applications

Protection of Metals and Physical Chemistry of Surfaces - Single NbSi2 and duplex NbSi2/Nb5Si3 coatings were successfully applied on Nb substrates using halide activated pack cementation (HAPC)...