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241.
Xiaojing Huang Yunxin Li 《Communications, IEEE Transactions on》2005,53(7):1166-1177
The optimal linear modulation approximation of any M-ary continuous-phase modulated (CPM) signal under the minimum mean-square error (MMSE) criterion is presented in this paper. With the introduction of the MMSE signal component, an M-ary CPM signal is exactly represented as the superposition of a finite number of MMSE incremental pulses, resulting in the novel switched linear modulation CPM signal models. Then, the MMSE incremental pulse is further decomposed into a finite number of MMSE pulse-amplitude modulated (PAM) pulses, so that an M-ary CPM signal is alternatively expressed as the superposition of a finite number of MMSE PAM components, similar to the Laurent representation. Advantageously, these MMSE PAM components are mutually independent for any modulation index. The optimal CPM signal approximation using lower order MMSE incremental pulses, or alternatively, using a small number of MMSE PAM pulses, is also made possible, since the approximation error is minimized in the MMSE sense. Finally, examples of the MMSE-optimal CPM signal approximation and its comparison with the Laurent approximation approach are given using raised-cosine frequency-pulse CPM schemes. 相似文献
242.
243.
Porous SiO2 low-dielectric-constant films containing different porosities and sizes of uniformly distributed pores were prepared in this study. Their nanomechanical properties including true flow stress and fracture toughness were analyzed by a nanoindentation test. The hardness and elastic modulus of the films prepared with an ethanol molar ratio of 3 and an aging time of 16 h reached maximum values of 2.4 and 40 GPa, respectively. With increasing ethanol molar ratio, the porosity increased, and the mechanical properties consequently decreased. With increasing aging time, the mechanical properties increased and then dropped due to enlarged pore sizes. From converted true flow stress, the porous SiO2 films were found to yield at an ultimate stress of 3.1 GPa, and the maximum fracture energy release rate was calculated as 3.4 J/m2. The plastic deformation and fracture behavior of the porous films was observed through crack initiation and propagation along the large amount of pores. 相似文献
244.
Solid solutions of the GdFeO3–GdInO3 system were prepared at 1550 °C by ceramic powder processing. The formulated composition was Gd(Fe1−xInx)O3 (GFI) with the indium contents at x = 0, 0.25, 0.5, 0.75, and 1.0. A stable phase of Gd(Fe1/3In2/3)O3 in our system was identified by X-ray diffraction and phase composition analysis. Multi-phase morphologies were observed for GFI bulks with x = 0.5 and 0.75. Dielectric and electrical properties of the GFI bulks were investigated. The addition of 25% In3+ in GdFeO3 had an obvious enhancement in polarization and led to an elevated resonance frequency. Dielectric properties of GFI bulks except GdInO3 were strongly dependent upon the test frequency, which corresponded to the response of polarization mechanism. GdInO3 displayed as a stable dielectric, which was frequency- and temperature-insensitive. GdInO3 was thermally activated and became leaky until above 600 °C. 相似文献
245.
Guanghui Wang Lei Huang Rong Yu Nansheng Deng 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(5):601-608
BACKGROUND: Endocrine disruptors in the aquatic environment and their potential adverse effects are currently issues of concern. One of these endocrine disruptors is 2,2‐bis(4‐hydroxy‐3‐methylphenyl)propane (BPP). In this work the molecular recognition interaction of BPP with β‐cyclodextrin (β‐CD) was studied using IR spectroscopy and steady state fluorescence spectroscopy, and the photocatalytic degradation behaviour of BPP based on molecular recognition interaction was investigated in a TiO2/UV–visible (λmax = 365 nm) system. This might provide a new method for the treatment of some organic pollutants in wastewater. RESULTS: β‐CD reacts with BPP to form a 1:1 inclusion complex, the formation constant of which is 4.94 × 103 L mol?1. The photodegradation rate constant of BPP after molecular recognition by β‐CD showed a 1.42‐fold increase in the TiO2/UV–visible (λmax = 365 nm) system. The photodegradation of BPP depended on the concentration of β‐CD, the pH value, the gaseous medium and the initial concentration of BPP. The photodegradation efficiency of BPP with molecular recognition was higher than that without molecular recognition. After 100 min of irradiation the mineralisation efficiency of BPP after molecular recognition by β‐CD reached 94.8%, whereas the mineralisation efficiency of BPP before molecular recognition by β‐CD was only 40.6%. CONCLUSION: The photocatalytic degradation of BPP after molecular recognition by β‐CD can be enhanced in the TiO2/UV‐visible (λmax = 365 nm) system. This enhancement is dependent on the enhancement of the adsorption of BPP, the moderate inclusion depth of BPP in the β‐CD cavity and the increase in the frontier electron density of BPP after molecular recognition. Copyright © 2008 Society of Chemical Industry 相似文献
246.
Shaokai Huang Wei Qin Youyuan Dai 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(5):683-687
BACKGROUND: Carboxylic acids are among the most important substances that can be manufactured from biomass. However, the recovery of carboxylic acids from fermentation broths presents a challenging separation problem. To avoid the production of waste salts and net consumption of chemicals in the calcium carboxylate salt process, the use of reversible chemical complexation with polymeric sorbents and extractants is attractive for carboxylic acid recovery. Pyruvic acid is widely used in the manufacture of medicines, pesticides and foodstuffs and can be produced by fermentation. Since the acidity of pyruvic acid (pKa = 2.49) is stronger than that of normal carboxylic acids, and as few reports on the recovery of pyruvic acid are available, the sorption of pyruvic acid from aqueous solution on two types of weakly basic polymeric sorbent, tertiary amine D301R and primary amine D392, was investigated over a wide pH range and at various salt (MgSO4) concentrations. RESULTS: Overloading adsorption of pyruvic acid on both weakly basic polymeric sorbents occurred, with the overloading of D392 being greater than that of D301R. The adsorption of pyruvic acid on both sorbents was greatly affected by the solution pH and the salt concentration in the aqueous phase. An overloading model was able to predict the experimental uptake data very well. CONCLUSION: Solution pH is one of the most important operating conditions, and both polymeric sorbents D392 and D301R can be used to recover pyruvic acid from dilute aqueous solution with high efficiency at a solution pH around 2. The uptake by D392 is greater than that by D301R owing to steric hindrance of the tertiary amine. Copyright © 2008 Society of Chemical Industry 相似文献
247.
保山盆地为滇西的一个具西断东超箕状断陷结构的新近系小型盆地。为搞清区内保山气田的沉积特征,指导该区油气勘探工作,结合沉积岩(物)与沉积环境之间的辩证关系,通过对沉积岩的岩性特征(颜色、岩石类型、岩石结构、黏土矿物、岩相组合)的分析研究,借助于沉积相在测井和地震剖面上的显著特征,研究并划分了保山气田新近系上新统羊邑组二-三段的沉积微相类型。结果表明,在该研究区主要发育了扇三角洲前缘亚相中的水下分流河道、分流河道间、前缘席状砂、河口坝等沉积微相类型,以及浅湖亚相中的浅湖泥和浅湖漫流席状砂沉积微相。剖析各类骨架微相的沉积特征后指出:水下分流河道、河口坝和前缘席状砂为该区最有利的储集砂体。 相似文献
248.
249.
阐述了硅铁生产中焦碳生产输送系统的工作原理和工艺要求,介绍了PLC在原料输送系统中的应用,给出了PLC的I/O接线图及程序框图,提出了工业原料生产输送控制系统的设计特点。 相似文献
250.
The growth of Li1+xMn2O4 via detonation reaction was investigated with respect to the presence of an energetic precursor, such as the metallic nitrate and the degree of confinement of the explosive charge. The detonation products were characterized by scanning electron microscopy. Powder X-ray diffraction and transmission electron microscopy were used to characterize the products. Li1+xMn2O4 with 1-2 μm spherical morphology and more uniform secondary particles, but with smaller primary particles of diameters from 20 to 60 nm and a variety of morphologies were found. The oxides produced by this cheap method affirmed the validity of detonation synthesis of nano-size powders. 相似文献