Ultrathin Highly Luminescent Two‐Monolayer Colloidal CdSe Nanoplatelets

Surface effects in atomically flat colloidal CdSe nanoplatelets (NLPs) are significantly and increasingly important with their thickness being reduced to subnanometer level, generating strong surface related deep trap photoluminescence emission alongside the bandedge emission. Herein, colloidal synthesis of highly luminescent two‐monolayer (2ML) CdSe NPLs and a systematic investigation of carrier dynamics in these NPLs exhibiting broad photoluminescence emission covering the visible region with quantum yields reaching 90% in solution and 85% in a polymer matrix is shown. The astonishingly efficient Stokes‐shifted broadband photoluminescence (PL) emission with a lifetime of ≈100 ns and the extremely short PL lifetime of around 0.16 ns at the bandedge signify the participation of radiative midgap surface centers in the recombination process associated with the underpassivated Se sites. Also, a proof‐of‐concept hybrid LED employing 2ML CdSe NPLs is developed as color converters, which exhibits luminous efficacy reaching 300 lm W_opt^?1. The intrinsic absorption of the 2ML CdSe NPLs (≈2.15 × 10⁶ cm^?1) reported in this study is significantly larger than that of CdSe quantum dots (≈2.8 × 10⁵ cm^?1) at their first exciton signifying the presence of giant oscillator strength and hence making them favorable candidates for next‐generation light‐emitting and light‐harvesting applications.     

Adaptive Multiuser Channel Estimation using Reduced Kalman/LMS Algorithm

This paper presents an adaptive multiuser channel estimator using the reduced-Kalman least-mean-square (RK-LMS) algorithm. The frequency-selective fading channel is modeled as a tapped-delay-line filter with smoothly time-varying Rayleigh distributed tap coefficients. The multiuser channel estimator based on minimum-mean-square-error (MMSE) criterion is used to predict the filter coefficients. We also present its convergence characteristics and tracking performance using the RK-LMS algorithm. Unlike the previously available Kalman filtering algorithm based approach (Chen, Chen IEEE Trans Signal Process 49(7): 1523–1532, 2001) the incorporation of RK-LMS algorithm reduces the computational complexity of multiuser channel estimator used in the code division multiple access wireless systems. The computer simulation results are presented to demonstrate the substantial improvement in its tracking performance under the smoothly time-varying environment.

High-performance fully depleted silicon nanowire (diameter /spl les/ 5 nm) gate-all-around CMOS devices

This paper demonstrates gate-all-around (GAA) n- and p-FETs on a silicon-on-insulator with /spl les/ 5-nm-diameter laterally formed Si nanowire channel. Alternating phase shift mask lithography and self-limiting oxidation techniques were utilized to form 140- to 1000-nm-long nanowires, followed by FET fabrication. The devices exhibit excellent electrostatic control, e.g., near ideal subthreshold slope (/spl sim/ 63 mV/dec), low drain-induced barrier lowering (/spl sim/ 10 mV/V), and with I/sub ON//I/sub OFF/ ratio of /spl sim/10/sup 6/. High drive currents of /spl sim/ 1.5 and /spl sim/1.0 mA//spl mu/m were achieved for 180-nm-long nand p-FETs, respectively. It is verified that the threshold voltage of GAA FETs is independent of substrate bias due to the complete electrostatic shielding of the channel body.     

Stochastic behaviour of a two-unit cold standby redundant electronic equipment under human failure

This paper presents a mathematical model to evaluate availability and M.T.T.F. of a two-unit cold standby system with three possible states of each unit; viz. good, partially failed and failed, incorporating the concept of human failure. The model has been developed for exponential failures and general repairs. Single service facility is available in each state during the operational stage of the electronic equipment. Laplace transforms of the various state probabilities have been obtained. Steady-state probabilities, steady-state availability and mean time to failure have been derived.     

Orthorhombic Ti2O3: A Polymorph‐Dependent Narrow‐Bandgap Ferromagnetic Oxide

Magnetic semiconductors are highly sought in spintronics, which allow not only the control of charge carriers like in traditional electronics, but also the control of spin states. However, almost all known magnetic semiconductors are featured with bandgaps larger than 1 eV, which limits their applications in long‐wavelength regimes. In this work, the discovery of orthorhombic‐structured Ti₂O₃ films is reported as a unique narrow‐bandgap (≈0.1 eV) ferromagnetic oxide semiconductor. In contrast, the well‐known corundum‐structured Ti₂O₃ polymorph has an antiferromagnetic ground state. This comprehensive study on epitaxial Ti₂O₃ thin films reveals strong correlations between structure, electrical, and magnetic properties. The new orthorhombic Ti₂O₃ polymorph is found to be n‐type with a very high electron concentration, while the bulk‐type trigonal‐structured Ti₂O₃ is p‐type. More interestingly, in contrast to the antiferromagnetic ground state of trigonal bulk Ti₂O₃, unexpected ferromagnetism with a transition temperature well above room temperature is observed in the orthorhombic Ti₂O₃, which is confirmed by X‐ray magnetic circular dichroism measurements. Using first‐principles calculations, the ferromagnetism is attributed to a particular type of oxygen vacancies in the orthorhombic Ti₂O₃. The room‐temperature ferromagnetism observed in orthorhombic‐structured Ti₂O₃, demonstrates a new route toward controlling magnetism in epitaxial oxide films through selective stabilization of polymorph phases.     

Mie‐Resonant Membrane Huygens' Metasurfaces

All‐dielectric metasurfaces have become a new paradigm for flat optics as they allow flexible engineering of the electromagnetic space of propagating waves. Such metasurfaces are usually composed of individual subwavelength elements embedded into a host medium or placed on a substrate, which often diminishes the quality of the resonances. The substrate imposes limitations on the metasurface functionalities, especially for infrared and terahertz frequencies. Here a novel concept of membrane Huygens' metasurfaces is introduced. The metasurfaces feature an inverted design, and they consist of arrays of holes made in a thin membrane of high‐index dielectric material, with the response governed by the electric and magnetic Mie resonances excited within dielectric domains of the membrane. Highly efficient transmission combined with the 2π phase coverage in the freestanding membranes is demonstrated. Several functional metadevices for wavefront control are designed, including beam deflector, a lens, and an axicon. Such membrane metasurfaces provide novel opportunities for efficient large‐area metadevices, whose advanced functionality is defined by structuring rather than by chemical composition.     

Error Detecting Dual Basis Bit Parallel Systolic Multiplication Architecture over GF（2^m）

An error tolerant hardware efficient verylarge scale integration （VLSI） architecture for bitparallel systolic multiplication over dual base, which canbe pipelined, is presented. Since this architecture has thefeatures of regularity, modularity and unidirectionaldata flow, this structure is well suited to VLSIimplementations. The length of the largest delay pathand area of this architecture are less compared to the bitparallel systolic multiplication architectures reportedearlier. The architecture is implemented using Austria Micro System＇s 0.35 μm CMOS （complementary metaloxide semiconductor） technology. This architecture canalso operate over both the dual-base and polynomialbase.     

Time-domain analysis of cross correlation for time delay estimationwith an autocorrelated signal

The estimation accuracy of the time difference of arrival (TDOA) of an exponentially autocorrelated signal at two sensors in white noise is analyzed. The estimate is obtained by cross correlating samples taken as short-term integrals of the noisy signals from the two sensors. This technique avoids ambiguities in the cross correlation, and it is shown that the best sampling rate is double the Nyquist rate, for which the Cramer-Rao lower bound (CRLB) is met in practice     

Enhancement of room temperature ferromagnetism in Cd1−xNixSe nanoparticles

Cd_1?xNi_xSe (x = 0.0, 0.02, 0.05 and 0.1) nanoparticles have been synthesized by chemical route. X-ray diffraction analysis shows crystalline nature of synthesized nanoparticles possessing wurtzite phase having hexagonal structure. Transmission electron microscopy depicts spherical morphology and uniform particle size distribution of pure and Ni-doped CdSe nanoparticles. The blue-shift in band gap has been observed with Ni-doping concentration. Photoluminescence study shows the presence of intrinsic defects (V_Cd–V_Se) in the synthesized nanoparticles. Electron spin resonance (ESR) analysis reveals the long range ferromagnetic ordering in pure and doped nanoparticles. ESR study also indicates that Ni ions exist in +2 oxidation state in host nanoparticles. The magnetic hysteresis (M-H) loops display ferromagnetism at room temperature in pure and Ni-doped CdSe nanoparticles. The increase of ferromagnetic behavior has been observed with Ni-doping concentration. M-H analyses indicate that defects and carrier mediated exchange interactions are responsible for ferromagnetic ordering, in the present study.