Phase behavior for blends of styrene containing triblock copolymers with poly(2,6-dimethyl-1,4-phenylene oxide)

The extent to which the styrene end-blocks of three commercially available triblock copolymers can mix with a particular poly(2,6-dimethyl-1,4-phenylene oxide) (M_n = 22,600 and M_w = 34,000) or PPO has been examined by investigation of the glass transition behavior of the PPO and polystyrene (PS) portions of the blends using differential scanning calorimetry. Each block copolymer has a butadiene-based mid-block which was hydrogenated for two of these materials, but not the third. The three copolymers differ substantially in overall molecular weight and in molecula weight of the blocks. However, in analogy with the literature on blends of homopolymer polystyrene with styrene-based block copolymers, the molecular weight of the PS block should be the principal factor affecting the phase behavior in the present blends. Mixtures of the PPO with the block copolymers having PS blocks with M = 14,500 (nonhydrogenated midblock) and with M = 29,000 (hydrogenated mid-block) exhibited single composition-dependent T_gs for the hard phase, indicating complete mixing of PS segments with the PPO, for all proportions. On the other hand, the block copolymer having a PS block with M = 7,500 and a hydrogenated mid-block exhibited two separate hard phase T_gs corresponding to an essentially pure PPO phase and a PS-rich phase. For blends of homopolymer PS with styrene-based block copolymers, the similar two-phase behavior of the glassy portion can be readily explained by entropic considerations. For the present case, the favorable enthalpic contribution for mixing PPO and PS is an additional factor which seems to influence the restrictions on molecular weight for complete mixing; however, additional work is needed to develop a more quantitative assessment of this new issue.     

Oxidation and Fracture Strength of High-Purity Reaction-Bonded Silicon Nitride

Reaction-bonded Si₃N₄ (RBSN) made from high-purity Si powder is unusually resistant to degradation caused by exposures to air for up to 50 h at temperatures up to 1400°C. The weight gain during oxidation of this SiH₄-originating RBSN is approximately 10 times less than conventional RBSN. Contrary to normally observed strength degradations, room-temperature strengths of this high-purity, oxidized RBSN (avg = 435 MPa, max. = 668 MPa) remained at their unusually high, as-processed levels after 1000° and 1400°C oxidizing exposures. Fracture toughness values were unaffected by oxidation ( K _IC= 2.3 to 2.4 MPa · m^1/2). This superior oxidation resistance results from the high purity and the small diameter pore channels (0.01 to 0.06 μm) achieved in this SiH₄-originating RBSN.     

Simultaneous spectrophotometric determination of copper(II), lead(II) and cadrnium(II)

The full spectrum technique in the fourier domain was studied for simultaneous determination of Cu(II), Pb(II) and Cd(II) with 4-(2-pyridylazo) resorcinol (PAR). A program called SPGRFSQ. was designed to perform the calculations. Seven error functions were calculated for deducing the number of factors. Data reduction was performed using principal component analysis (PCA) algorithm. Experimental results showed the method to be successful even where there was severe overlap of spectra.     

Issues in the replacement of lead-bearing solders

The use of soft solders, particularly those containing lead, dates back nearly 5,000 years. Solders similar to the materials used to seal the aqueducts of ancient Rome are now an important building block in the manufacture of high-speed computer assemblies. This history attests to the technological versatility of soft solders and, in particular, the solder alloys that contain lead. However, the health effects of prolonged exposure to lead have also been documented; measures to limit human exposure—at the work place and indirectly through the environment—are being considered. The successful introduction of lead-free solders into future electronic products will rely heavily upon their solderability, which can be evaluated by test procedures such as the meniscometer/wetting balance technique and the capillary flow test.     

TEM IMAGING TECHNIQUE

This imaging technique is used for approximate interpretation of TEM data including ungrounded loopsource and grounded line source soundings.Loop source data can be collected as central-loop soundings or asout-of-loop soundings with a short or long offset configuration.The imaging method is based on the same princi-ple as that employed by Fullager(1989),with apparent resistivities computed directly from time-derivative data,db/d,and then associated with depths according to image theory.     

安钢SAP预留系统的开发与应用

本文简述了安钢信息化建设概况,介绍了安钢信息化建设中开发SAP预留系统的设计流程,阐述了预留系统实现的功能.     

Computational simulation of Belousov–Zhabotinskii oscillating chemical reaction

The suitability of computational simulation of the Belousov–Zhabotinskii oscillating chemical reaction by differential kinetic methodology for resolving nonlinear multi-component system is demonstrated in this work. According to the Field–KÖrÖs–Noyes mechanism and the Oregonator model, the change of the concentrations of HBrO₂, bromide ion and cerium ion are simulated. The results of computational simulation are consistent with experimental results very well. At the same time, the effect of variables and parameters, especially the rate constant on the oscillation curve, are investigated deeply. A simple method of estimating rate constants is obtained through simulation the concentrations of key components of the system, and then comparison the simulation results with the experimental ones. The reasonable rate constant is also proposed.