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971.
Practical aspects of implementing surfactant mass balance computation in finite elements models, where the model geometry
shape change is captured by utilizing the arbitrary Lagrange–Eulerian method are discussed briefly. The discussion and the
reported simulations are carried out in two-dimensional Cartesian coordinates. Two alternative approaches to formulating the
governing equation of surfactant mass balance for solving it computationally are presented and discussed. One of the approaches
is based on computing the boundary curvature and boundary tangential velocity, as well as their differentials on the boundary,
directly. The other approach is based on reformulating the governing equation in order to track the proportional rate of change
of local surface area. As a conclusion, it is found that though both of the presented approaches can be configured to perform
adequately in terms of surfactant mass conservation, surface differentials that are necessary to compute the surface curvature
and surface tangential velocity in the first one of the methods evoke numerical oscillations near those points of the boundary
where it is not smooth. The text is accompanied by example simulations and figures. 相似文献
972.
Vincent Lemiale Yuri Estrin Hyoung Seop Kim Robert O’Donnell 《Metallurgical and Materials Transactions A》2011,42(10):3006-3012
Grain refinement by plastic deformation is becoming increasingly popular as a way of producing metals with improved properties,
such as higher mechanical strength. Surface treatment techniques in which a metallic substrate is bombarded with metallic
particles can generate nanocrystalline layers in the impact zone. Understanding the physical mechanisms underlying this grain
refinement is crucial for achieving an improvement of existing experimental processes. In this article, we propose a numerical
framework combining finite element (FE) simulations with a dislocation-based material model to predict the evolution of the
microstructure under particle impact. A single particle normally impacting on a metallic substrate was simulated at different
initial velocities. The simulations were compared with previously reported numerical and experimental data. The results indicate
that our model accurately captures the grain refinement in the impact zone for a broad range of velocities. This approach
provides valuable information on the formation of nanocrystalline layers in both the substrate and the impacting particle.
Its potential applications include processes involving surface treatment by high velocity particles, such as shot peening,
surface mechanical attrition treatment, kinetic metallization, cold spray, etc. 相似文献
973.
Synthesis and properties of cross‐linked polymers from epoxidized rubber seed oil and triethylenetetramine 下载免费PDF全文
Muhammad Yusuf Abduh Muhammad Iqbal Francesco Picchioni Robert Manurung Hero J. Heeres 《应用聚合物科学杂志》2015,132(40)
A series of epoxidized oils were prepared from rubber seed, soybean, jatropha, palm, and coconut oils. The epoxy content varied from 0.03 to 7.4 wt %, in accordance with the degree of unsaturation of the oils (lowest for coconut, highest for rubber seed oil). Bulk polymerization/curing of the epoxidized oils with triethylenetetramine (in the absence of a catalyst) was carried out in a batch setup (1 : 1 molar ratio of epoxide to primary amine groups, 100°C, 100 rpm, 30 min) followed by casting of the mixture in a steel mold (180°C, 200 bar, 21 h) and this resulted in cross‐linked resins. The effect of relevant pressing conditions such as time, temperature, pressure, and molar ratio of the epoxide and primary amine groups was investigated and modeled using multivariable nonlinear regression. Good agreement between experimental data and model were obtained. The rubber seed oil‐derived polymer has a Tg of 11.1°C, a tensile strength of 1.72 MPa, and strain at break of 182%. These values are slightly higher than for commercial epoxidized soybean oil (Tg of 6.9°C, tensile strength of 1.11 MPa, and strain at break of 145.7%). However, the comparison highlights the potential for these novel resins to be used at industrial/commercial level. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42591. 相似文献
974.
Investment optimization model for freshwater acquisition and wastewater handling in shale gas production 下载免费PDF全文
Linlin Yang Ignacio E. Grossmann Meagan S. Mauter Robert M. Dilmore 《American Institute of Chemical Engineers》2015,61(6):1770-1782
Major challenges of water use in the drilling and fracturing process in shale gas production are large volumes required in a short‐period of time and the nonsteady nature of wastewater treatment. A new mixed‐integer linear programming (MILP) model for optimizing capital investment decisions for water use for shale gas production through a discrete‐time representation of the State‐Task Network is presented. The objective is to minimize the capital cost of impoundment, piping, and treatment facility, and operating cost including freshwater, pumping, and treatment. The goal is to determine the location and capacity of impoundment, the type of piping, treatment facility locations and removal capability, freshwater sources, as well as the frac schedule. In addition, the impact of several factors such as limiting truck hauling and increasing flowback volume on the solution is examined. A case study is optimized to illustrate the application of the proposed formulation. © 2015 American Institute of Chemical Engineers AIChE J, 61: 1770–1782, 2015 相似文献
975.
976.
Christine M. Wickens Evelyn Vingilis Robert E. Mann Patricia Erickson Maggie E. Toplak Nathan J. Kolla Jane Seeley Anca R. Ialomiteanu Gina Stoduto Gabriela Ilie 《Accident; analysis and prevention》2015
Background
Despite limited empirical investigation, existing scientific literature suggests that individuals with a history or current diagnosis of conduct disorder (CD) may be more likely to demonstrate reckless and aggressive driving. Much of the limited research in this field examines the impact of childhood CD on driver behaviour and collision risk in young adults. Few if any, studies assess the impact of this disorder on driver behaviour beyond age 21 years. The current research is a population-based study of the impact of CD symptoms during childhood on the risk of engaging in driver aggression during adulthood.Methods
Data are based on telephone interviews with 5230 respondents who reported having driven in the past year. Data are derived from the 2011–2013 cycles of the CAMH Monitor, an ongoing cross-sectional survey of adults in Ontario, Canada aged 18 years and older. A binary logistic regression analysis of self-reported driver aggression in the previous 12 months was conducted, consisting of measures of demographic characteristics, driving exposure, problem substance use, alcohol- and drug-impaired driving, symptoms of attention deficit hyperactivity disorder, and childhood (before age 15) symptoms of CD.Results
When entered with demographic characteristics, driving exposure, and other potential confounders, childhood symptoms of CD increased the odds of reporting driver aggression more than two-fold (adjusted OR = 2.12). Exploratory analyses of the interaction between childhood symptoms of CD and age was not a significant predictor of driver aggression.Conclusions
Results suggest that symptoms of CD during childhood are associated with significantly increased odds of self-reported driver aggression during adulthood. Limitations and future directions of the research are discussed. 相似文献977.
978.
Jeffrey G. Tait Tamara Merckx Wenqi Li Cindy Wong Robert Gehlhaar David Cheyns Mathieu Turbiez Paul Heremans 《Advanced functional materials》2015,25(22):3393-3398
With lab‐scale solution‐processed thin film photovoltaic (TFPV) devices attaining market relevant efficiencies, the demand for environmentally friendly and scalable deposition techniques is increasing. Replacing toxic halogenated solvents is a priority for the industrialization of solution‐processed TFPV. In this work, a generalized five‐step process is presented for fabricating high‐performance devices from nonhalogenated inks. Resulting from this process, several new solvent systems are introduced based on thiophene, tetralin, 1,2,4‐trimethylbenzene, o‐xylene, and anisole for blade coating of three different diketopyrrolopyrrole‐based (pDPP5T‐2, pPDPP5T‐2S, and P390) bulk heterojunctions applied in organic photovoltaic devices. Devices based on pDPP5T‐2S and P390 attain 5.6% and 6.1% efficiency, respectively, greater than the efficiency either material reached when processed from the halogenated solvent system commonly used. These processes are implemented without post‐deposition annealing treatments or additives. The Hansen solubility parameters of the pDPP5T‐2 material are obtained, and are used, along with wettability data on a variety of substrates, to determine optimum solvent combinations and ratios for deposition. This generalized five‐step process results in new nonhalogenated solvent pathways for the scalable deposition of thin film photovoltaic materials. 相似文献
979.
Modular and Versatile Spatial Functionalization of Tissue Engineering Scaffolds through Fiber‐Initiated Controlled Radical Polymerization 下载免费PDF全文
Rachael H. Harrison Joseph A. M. Steele Robert Chapman Adam J. Gormley Lesley W. Chow Muzamir M. Mahat Lucia Podhorska Robert G. Palgrave David J. Payne Shehan P. Hettiaratchy Iain E. Dunlop Molly M. Stevens 《Advanced functional materials》2015,25(36):5748-5757
Native tissues are typically heterogeneous and hierarchically organized, and generating scaffolds that can mimic these properties is critical for tissue engineering applications. By uniquely combining controlled radical polymerization (CRP), end‐functionalization of polymers, and advanced electrospinning techniques, a modular and versatile approach is introduced to generate scaffolds with spatially organized functionality. Poly‐ε‐caprolactone is end functionalized with either a polymerization‐initiating group or a cell‐binding peptide motif cyclic Arg‐Gly‐Asp‐Ser (cRGDS), and are each sequentially electrospun to produce zonally discrete bilayers within a continuous fiber scaffold. The polymerization‐initiating group is then used to graft an antifouling polymer bottlebrush based on poly(ethylene glycol) from the fiber surface using CRP exclusively within one bilayer of the scaffold. The ability to include additional multifunctionality during CRP is showcased by integrating a biotinylated monomer unit into the polymerization step allowing postmodification of the scaffold with streptavidin‐coupled moieties. These combined processing techniques result in an effective bilayered and dual‐functionality scaffold with a cell‐adhesive surface and an opposing antifouling non‐cell‐adhesive surface in zonally specific regions across the thickness of the scaffold, demonstrated through fluorescent labelling and cell adhesion studies. This modular and versatile approach combines strategies to produce scaffolds with tailorable properties for many applications in tissue engineering and regenerative medicine. 相似文献
980.
Robert Bevan 《Architectural Design》2015,85(3):16-25
Author and architecture critic for the London Evening Standard, Robert Bevan reflects on the enduring appeal of the temporary structure, speaking ‘to a latent desire for freedom and movement’ as a hangover of our nomadic past in a sedentary ‘civilised’ society. He highlights the type's historical apex in Henry VIII's palatial pop-up on the Field of the Cloth of Gold, questioning the purpose and purposelessness of more recent examples. 相似文献